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1.
景毅 《科技情报开发与经济》2004,14(5):132-133
对处于交变磁场作用下的磁性磨料颗粒的受力和运动规律进行了分析和描述,为交变磁场作用下的磁粒研磨光整加工技术提供了新的思路和工艺选择。 相似文献
2.
This paper presents the importance and usage of natural zeolites, which was recently recognized in the industry. Therefore, the grinding properties of natural zeolite were studied with the emphasis on a kinetic study in a ball mill. The experimental mill employed was laboratory sized, 200 mm diameter, 191 mm length, providing a total mill volume of 6000 cm3, with a total mass of 5.62 kg of steel balls of 25 mm diameter with a charge of 20% of the mill volume and with a rotation speed of 76 rpm. The breakage parameters were determined by using single sized feed fractions of ?850+600 μm, ?600+425 μm, and ?425+300 μm for the zeolite samples. The Si (specific rate of breakage) and Bi, j (primary breakage distribution) values were obtained for those feed size fractions in order to predict the product size distributions by simulation for comparison to the experimental data. From the experimental results, Si values increased as the feed sizes became coarser, i.e., the highest Si value was 0.85 min?1 for ?850+600 μm, while the lowest Si value was 0.65 min?1 for ?425+300 μm feed ground in the mill. The Bi, j values obtained for the zeolite sample were γ=0.84, ?=0.61, and β=4.25. The breakage parameters obtained showed that the zeolite is broken faster than quartz and slower than calcite and barite in terms of the aT values reported previously at the same experimental conditions. The simulations of the product size distributions of zeolite were in good agreement with the experimental data using a standard ball mill simulation program. The slowing‐down effect was also seen in the mill after 4 min. of grinding. 相似文献
3.
Grindstone Chemistry--a greatly evolved version of Toda’s method of grinding solids together for solvent-free chemical reactions--has been described and its usefulness illustrated by the successful application of this technique to a simplified process for conducting the multi-component Biginelli reaction for the synthesis of physiologically active tetrahydropyrimidinones. 相似文献
4.
室温或近室温固相反应要求绿色化、清洁化[1,2]。我们以KMnO4和MnCl2·4H2O为原料,用室温固相氧化还原反应制备氧化锰粉体时,得到了一种对H2O2分解具有较高催化活性的纳米KMn8O16粉体,用XRD、SEM、IR等技术对其进行了表征,发现研磨时间对粉体性能有显著影响。1 实验部分1 1 粉体的制备按摩尔比(2∶3)准确称取一定量的分析纯KMnO4和MnCl2·4H2O,分别置于玛瑙研钵中充分研细,再混合研磨,固相反应立即发生,体系颜色逐渐加深,并有刺激性气体产生,充分研磨后70℃恒温12h,固相产物依次经水洗至中性、醇洗、抽滤,真空干燥得黑色粉… 相似文献
5.
N- aryl substituted benzenesulfamides are often used as heating-sensitive recording material1, thermal printing material2, sensitizer3 and developer4. Moreover, some of the benzenesulfamides have antifungal activities5. Many methods have been described for preparation of sulfamides. They are used to carry out in solvent8 or in solid phase condition9. These methods required solvent or solid support and even required heating or cooling. At the same time, the process of these methods is complex. Now we have developed a new method to prepare N-aryl substituted toluenesulfamides under solvent-free conditions.In recent years, solvent-free technology has gained popularity in organic synthesis. For instance,solidstate reaction and microwave reaction have received considerable attention. Solvent-free synthesis of amides has been reported10-11. This technology has many advantages such as high efficiency and selectivity, easy separation and environmental acceptability. All these merits are in accord with green chemistry's requirements of energy-saving, high efficiency and environmental benefits.In our paper, we used a simple and efficient method for preparing N-aryl substituted toluenesulfamides under solvent-free conditions, as a replacement for classic solvent, which gives many environmental benefits.All reactions were completed at room temperature by co-grinding in an agate mortar for 3-20min and the results are shown in Table 1.In conclusion, we have developed an efficient and convenient method of preparation N-aryl substituted toluenesulfamides in high yields. It symbols an improvement for synthesis of benzenesulfamides. 相似文献
6.
研究铲磨机各种运动和控制要求,设计出继电控制与PC控制相结合的电气控制系统。此系统在电路设计、电气柜安装、调试维修和操作等方面满足了设计要求。铲磨加工过程的PC控制解决了转轮流道三维表面成形运动的控制难题。PC控制程序基本满足了铲磨工艺要求。 相似文献
7.
The synthesis of unsaturated unnatural amino acids according to the Heck-Jeffery protocol using a ball-milling procedure is presented. NOE data recorded on the products confirm that the Z-isomer is formed. This type of mechano-chemistry provides an efficient, “solvent free” and reliable method for the synthesis of substituted dehydroalanines. These conditions provide patterns of reactivity complementary to conventional procedures. 相似文献
8.
麻花钻内锥面刃磨试验 总被引:3,自引:3,他引:0
戴俊平 《陕西理工学院学报(自然科学版)》2003,19(1):7-9
阐述了内锥面法刃磨麻花钻的原理以及在工具磨床上进行磨削工艺试验的方法。通过试验刃磨出了合格的麻花钻,验证了内锥面法刃磨麻花钻理论,并对内锥面刃磨试验中存在的问题进行了分析讨论。 相似文献
9.
SHIMIZU Jun EDA Hiroshi 《厦门大学学报(自然科学版)》2002,(Z1)
This study aims to reduce the work-affected layer of the machined surface by carrying out the grinding at the speed over static pr o pagation speed of plastic wave of ductile materials and also aims to clarify suc h super high-speed machining mechanism.This paper reports on the result obtain ed through the molecular dynamics simulations and experiments on the super-spee d grinding below and beyond static propagation speed of aluminum.From the simul ation results,it is verified that the plastic deformation ... 相似文献
10.
Wieczorek-Ciurowa K. Gamrat K. Paryło M. Shirokov Ju. G. 《Journal of Thermal Analysis and Calorimetry》2002,70(1):165-172
The physical mixtures of hydroxocarbonates of Cu and Ni with aluminium were activated using a laboratory planetary mill. The
chemical reactions and alloy formations as the effects of grinding were followed by the phase analysis of solid products based
on the thermogravimetry and X-ray diffractometry. Experimental evidence indicates that the nature of reactions and products
of mechanical activation was dependent on the amount of aluminium and time of grinding.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献