Caesium carbonate supported on hydroxyapatite‐encapsulated Ni0.5Zn0.5Fe2O4 nanocrystallites as a novel magnetically basic catalyst for the one‐pot synthesis of pyrazolo[1,2‐b]phthalazine‐5,10‐diones

A novel nanomagnetic basic catalyst of caesium carbonate supported on hydroxyapatite‐coated Ni_0.5Zn_0.5Fe₂O₄ magnetic nanoparticles (Ni_0.5Zn_0.5Fe₂O₄@HAP‐Cs₂CO₃) was prepared. This new catalyst was fully characterized using Fourier transform infrared spectroscopy, transmission and scanning electron microscopy, X‐ray diffraction and vibrating sample magnetometry techniques, and then the catalytic activity of this catalyst was investigated in the synthesis of 1H‐pyrazolo[1,2‐b]phthalazine‐5,10‐dione derivatives. Also, Ni_0.5Zn_0.5Fe₂O₄@HAP‐Cs₂CO₃ could be reused at least five times without significant loss of activity and could be recovered easily by applying an external magnet. Thus, the developed nanomagnetic catalyst is potentially useful for the green and economic production of organic compounds. Copyright © 2015 John Wiley & Sons, Ltd.     

Recyclable and reusable Pd(OAc)2/PPh3/PEG‐2000 system for homocoupling reaction of arylboronic acids under air without base

A stable and efficient Pd(OAc)₂/PPh₃/PEG‐2000 catalytic system for homocoupling of arylboronic acids has been developed. In the presence of Pd(OAc)₂ and PPh₃, the homocoupling reaction of arylboronic acids was carried out smoothly in PEG‐2000 at 70 °C under air without base to afford a variety of symmetric biaryls in good to excellent yields. The isolation of the products was readily performed by extraction with diethyl ether, and the Pd(OAc)₂/PPh₃/PEG‐2000 system could be easily recycled and reused six times without significant loss of catalytic activity. Copyright © 2014 John Wiley & Sons, Ltd.     

上海黄浦江两支流河流甲烷含量研究

甲烷是一种重要的温室气体,虽然目前大气中含量远小于二氧化碳,但排放增长率却大于后者.研究区域为上海市黄浦江支流苏州河和淀浦河,通过实验数据对比城郊春夏的甲烷排放的差异,探讨甲烷产生的机制及其与环境因子的关系,这将有助于研究河流甲烷排放对于环境变化的影响.研究结果认为河流甲烷主要来源于水中沉积物,其产生与水质、温度等因素相关;同时甲烷摩尔浓度与硝酸根离子质量体积比存在负相关性,与铵根离子质量体积比和有机碳质量分数存在正相关性.     

Vertex-disjoint rainbow triangles in edge-colored graphs

Let $G$ be an edge-colored graph of order $n$. The minimum color degree of $G$, denoted by ${\delta }^c\left(G\right)$, is the largest integer $k$ such that for every vertex $v$, there are at least $k$ distinct colors on edges incident to $v$. We say that an edge-colored graph is rainbow if all its edges have different colors. In this paper, we consider vertex-disjoint rainbow triangles in edge-colored graphs. Li (2013) showed that if ${\delta }^c\left(G\right)\ge (n+1)∕2$, then $G$ contains a rainbow triangle and the lower bound is tight. Motivated by this result, we prove that if $n\ge 20$ and ${\delta }^c\left(G\right)\ge (n+2)∕2$, then $G$ contains two vertex-disjoint rainbow triangles. In particular, we conjecture that if ${\delta }^c\left(G\right)\ge (n+k)∕2$, then $G$ contains $k$ vertex-disjoint rainbow triangles. For any integer $k\ge 2$, we show that if $n\ge 16k-12$ and ${\delta }^c\left(G\right)\ge n∕2+k-1$, then $G$ contains $k$ vertex-disjoint rainbow triangles. Moreover, we provide sufficient conditions for the existence of $k$ edge-disjoint rainbow triangles.     

Lipase‐Supported Metal–Organic Framework Bioreactor Catalyzes Warfarin Synthesis

A green and sustainable strategy synthesizes clinical medicine warfarin anticoagulant by using lipase‐supported metal–organic framework (MOF) bioreactors (see scheme). These findings may be beneficial for future studies in the industrial production of chemical, pharmaceutical, and agrochemical precursors.     

Ⅰ级洁净手术室中无影灯直径的确定

采用高雷诺数K-ε二方程模型，从控制污染物的扩散范围和保证工作区乱流度这两个指标出发，对I级洁净手术室内无影灯直径进行了研究，为无影灯直径的选型提供了依据。     

蕴含W5可图序列的最小度和

Gould,Jacobson和Lehel考虑了下述经典Tur偄n型极值问题的变形:对于给定的图H,确定最小的正偶数σ(H,n),使得对于每一个n项可图序列π=(d1,d2,…,dn),当σ(π)=d1+d2+…+dn≥σ(H,n)时,π有一个实现G包含H作为可图的.本文确定了当n≥11时,σ(W5,n)之值,其中Wr是r个顶点的轮图.     

The Chang-Łoś-Suszko theorem in a topological setting

The Chang-Łoś-Suszko theorem of first-order model theory characterizes universal-existential classes of models as just those elementary classes that are closed under unions of chains. This theorem can then be used to equate two model-theoretic closure conditions for elementary classes; namely unions of chains and existential substructures. In the present paper we prove a topological analogue and indicate some applications.     

设计教育中的环境教育研究

现代人类社会面临的环境问题日益严重,而解决环境问题的有效途径是环境教育。设计活动在创造人类生存的物质环境和生活方式方面起着关键作用,因而在解决环境问题方面具有重要地位。本文论述了环境教育的发展以及在设计教育中开展环境教育的作用,并就其中的问题进行了讨论。