从电子设计竞赛看单片机实验教学的改革与创新

结合电子设计竞赛的内容及特点,从当前社会发展对高素质、创新人才的需求出发,为提高学生运用理论知识去解决实际问题的能力,对单片机原理及应用课程实验内容和方法的改革进行了探讨.     

暂态电路的试验设计

在电工电子技术暂态电路的试验设计中，因电路本身响应时间短，用常规仪器很难对其响应的过程进行直接测量。本文结合暂态电路的工作原理及常规仪器的特点，给出三种简单、实用的试验电路设计方法。     

二维模型风振特性强迫振动实验研究

从颤振的角度讨论了空气动力(包括升力和力矩)对振动的影响，该实验模型采用二维截断模型。为了完成模型的纯弯和扭转单自由度强迫振动实验，专门设计了一套强迫振动机构，并用计算机采集和处理数据。然后利用模型的纯弯和扭转单自由度强迫振动实验得出了颤振导数，绘出颤振导数随无量纲风速K变化的曲线图，较好地描述了其随无量纲风速K的变化规律。     

一种石油热采密封技术的研究

采用3级(导套、浮动密封环组、盘根)组合密封结构设计方法，实现石油热采密封系统的密封要求．利用层流间隙密封与轴向端面密封理论，确定出系统的密封间隙．采用接触与非接触结构混合密封方式并配合所选择的密封材料的自润滑性质，解决并实现系统的润滑要求．通过试验研究得到所希望的密封效果.     

A Simple Approach for Multi‐fidelity Experimentation Applied to Financial Engineering

In practical applications, information about the accuracy or ‘fidelity’ of alternative surrogate systems may be ambiguous and difficult to determine. To address this problem, we propose to treat surrogate system fidelity level as a categorical factor in optimal response surface design. To design the associated experiments, we apply the Expected Integrated Mean Squared Error optimal design criterion, which takes into account both variance and bias errors. The performance of the proposed design was compared using three test cases to four types of alternatives using the Empirical Integrated Squared Error. Because of its ability to foster relatively accurate predictions, the proposed design is recommended in fidelity experimental design, particularly when the experimenters lack sufficient information about the fidelity levels of surrogate systems. The method was applied to the case of intraday trading optimization in which data were collected from the Taiwan Futures Exchange. We also calculated the implied volatility from the Merton's Jump‐diffusion model via the fast Fourier transform algorithm with three different models of varying fidelity levels. Copyright © 2014 John Wiley & Sons, Ltd.     

Development and Molecular Understanding of a Pd-Catalyzed Cyanation of Aryl Boronic Acids Enabled by High-Throughput Experimentation and Data Analysis

A synthetic method for the palladium-catalyzed cyanation of aryl boronic acids using bench stable and non-toxic N-cyanosuccinimide has been developed. High-throughput experimentation facilitated the screen of 90 different ligands and the resultant statistical data analysis identified that ligand σ-donation, π-acidity and sterics are key drivers that govern yield. Categorization into three ligand groups – monophosphines, bisphosphines and miscellaneous – was performed before the analysis. For the monophosphines, the yield of the reaction increases for strong σ-donating, weak π-accepting ligands, with flexible pendant substituents. For the bisphosphines, the yield predominantly correlates with ligand lability. The applicability of the designed reaction to a wider substrate scope was investigated, showing good functional group tolerance in particular with boronic acids bearing electron-withdrawing substituents. This work outlines the development of a novel reaction, coupled with a fast and efficient workflow to gain understanding of the optimal ligand properties for the design of improved palladium cross-coupling catalysts.     

松香改性酚醛环氧树脂的合成与表征

以松香,环氧氯丙烷,甲醛及苯酚等为主要原料,合成了一种新型的环氧树脂。通过正交实验法确定了环氧化反应的最佳实验条件,即环氧化温度90℃,碱用量13 g,催化剂为cat 1,其最佳用量为0.018 mol,环氧氯丙烷的用量为50 g,碱浓度为30%(以上数值均以松香用量为70 g时计)。在最佳实验条件下合成得到了松香改性酚醛环氧树脂(简称RAPE),并用HPLC、FT-IR、NMR对其进行结构表征。结果表明,得到的RAPE其环氧值为0.28 mol/100g,平均聚合度约为3.4,酚羟基和树脂酸上的羧基基本反应完全,得到一种新型的缩水甘油醚型和缩水甘油酯型的环氧树脂。     

数学实验课的研究与认识

对数学实验这门课程的起源、目的、意义和作用做了明确的阐述。并对课程的内容和教法做了深入的讨论研究,建议数学实验课应该建设成为一门大学数学的技术基础课。     

高师化学专业实验教学内容和课程体系改革的研究

面对世纪之交社会发展趋势和21 世纪的时代特点,我国高师化学专业实验教学内容和课程体系难以适应培养21 世纪所需高师化学人才的要求.改革教学内容和课程体系是整个教学改革的重点和难点.面对21 世纪的挑战,分析了高师化学专业实验教学的现状和问题,提出了“一体化、多层次”实验教学模式.     

根据神经类型测定综合心理运动能力的实验分析

大脑神经细胞的结构和功能是影响综合心理运动能力的重要因素.掌握按照神经类型测定综合心理运动能力的方法,对运动选材、教学训练、运动竞赛等方面有着重要意义.