电负性及其在无机化学上的应用

从用电负性来衡量元素在化合物分子中吸引电子的能力的必要性出发，阐述电负性的概念以及阿莱－罗周（Ａｌｌｒｅｄ－Ｒｏｃｈｏｗ）计算电负性标的方法，重点论述了电负性在无机化学上的某些应用．     

Electrically insulated molecular wires

This paper is an up-to-date mini-review based on literature data and own results regarding synthesis and properties of conducting (pseudo)rotaxane supramolecular structures. Conjugated polymers, such as polyarylene, polyheteroarylene, polyaniline, polyarylenevinylene or polyaryleneimine, were used as axle, while the macrocyclic components were cyclodextrins, cucurbiturils, cyclophanes or crown ethers. Properties of the supramolecular structure such as solubility, thermal or chemical stability, conductivity, etc. can be drastically modified by the inclusion of hydrophobic conjugated polymers inside the macrocycle, without any chemical modification. For instance, the photophysical properties (i.e. quantum yield of fluorescence and electroluminescence) of the supramolecular structures were enhanced when compared with uninsulated conjugated polymers. The doping process is also affected, because the access of a dopant to the conjugated chain is limited only to the uncovered domains of the conjugated chain.     

Electro-disclinic effect in tilted smectic phases of banana-shaped liquid crystal materials

We give the first evidence that the director tilt angle can be reduced by electric fields in the tilted smectic phase of banana-shaped molecules. In these phases the value of polarization is determined by the molecular packing and no electro-clinic effect is expected. Our studies show that high electric fields eventually induce a meta-stable phase with zero director tilt. The tilted phase slowly recovers at low fields. We propose that the field-induced quenching of the layer fluctuations is responsible for the observed effects.     

深亚微米工艺EEPROM单元加固设计及辐照性能

当普通EEPROM单元在太空中应用时,会受到辐照效应的影响,导致单元可靠性降低,寿命缩短,为此,基于0.18 μm工艺,设计出一种新型抗辐照EEPROM单元.新单元采用环形栅和场区隔离管加固结构.加固后,单元面积为9.56 μm2,抗总剂量效应能力大于1 500 Gy,抗辐照能力明显优于普通结构.为明确失效机制,基于新...     

电大尺寸载体天线间宽带干扰耦合快速分析

为求解电大尺寸载体天线间的宽带干扰耦合度,建立了天线间干扰耦合分析模型,提出了自适应多层快速多极子算法作为求解该耦合分析模型的核心算法.该算法将阻抗积分表达式中的基函数和权函数分别用不同空间位置上的Dirac函数展开,使阻抗积分的计算得到大大简化,所有转移过程可由快速傅里叶变换计算完成,应用波形渐进估计技术计算载体表面及天线上的宽带电流值,最后结合微波二端口网络理论求得天线间的宽带耦合度.数值实验和实测结果证明,在精度相等的前提下,所提出的快速分析方法比传统快速分析方法的计算效率和存储效率均提高了30%左右.     

PE算法伪微分算子的多种近似处理对电磁散射计算的影响研究

文章对抛物线方程(Parabolic Equation,简称PE)算法的伪微分算子的多种逼近形式进行了深入的分析研究,探讨了多种经过近似处理的抛物线方程算法的特点,并将多种PE算法应用于电大尺寸目标的电磁散射特性的分析中。关于理想导体柱电磁散射的算例表明,各种经过近似处理的抛物线方程算法具有各自的特点和适用范围。     

Carbon‐based sorbents in chromatography. New achievements

The newest results in the employment of carbon‐based composites in various chromatographic techniques such as gas–liquid chromatography, high‐performance liquid chromatography and electrically driven separation techniques for the separation, quantitative determination and identification of a wide variety of compounds in complicated matrices are compiled. The results are concisely described and critically evaluated. The future trends in the application of carbon‐based compounds in the chromatographic separation methods are briefly discussed. Copyright © 2008 John Wiley & Sons, Ltd.     

Electrochemiluminescence Behavior of Ru(bpy)32+/Carbofuran System on an Electrically Heated Microelectrode Chip

An electrically heated microelectrode chip (HMEC) was designed and the Ru(bpy)₃²⁺/carbofuran electrochemiluminescence (ECL) systems were applied to characterize the performance of the HMEC. The ECL intensities increase at elevated electrode temperature, and the detection limit at 60°C (electrode surface temperature) was about 10 times lower than that at 30°C. The results indicate that new heated electrode can be handled easily and can be mass produced, the difference between the electrodes was little. The stability of the HMEC was good since the electrode surface can hardly be destroyed during detection and storage.     

Cu_xS法导电PAN纤维的导电耐久性研究

本文对CU_xS法导电PAN纤维的导电耐久性不理想的表现和原因进行了分析。提出一系列提高导电耐久性的措施,指出活化预处理和多硫化物后处理对提高导电耐久性具有明显的效果,并对其作用机理进行了探讨。在此基础上制得了导电耐久性优良的导电PAN纤维。     

低频电磁脉冲对复杂电大目标耦合效应

针对复杂电大目标电磁脉冲耦合效应缺乏定量研究的问题,基于时域有限差分方法(FDTD)建立了一套电磁脉冲耦合效应建模与评估分析流程,开展了低频电磁脉冲激励下的仿真试验,获取和分析了特性数据,进而提出了一种表面加载透明导电材料的低频电磁脉冲激励防护方法。试验结果表明:基于功率密度的易损性分析具有良好的工程适用性,而且防护方法对低频电磁脉冲激励具有较好的屏蔽效能。