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1.
Nuclear Magnetic Resonance (NMR) was used to investigate the extrusion behaviour of PTFE pastes in a ram extruder. By means
of 1H-NMR imaging (MRI) it is possible to determine the local proton density and therefore, the local fluid concentration. The
19F-MRI provides the local solid concentration. Thus the local saturation and the local porosity can be calculated with the
information of the local fluid and solid concentration. Furthermore displacement profiles can be derived from NMR images by
means of correlation techniques without any preparation or marking of the pastes.
Received: 8 May 2000 Accepted: 1 May 2001 相似文献
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The title reaction has been used as an example to test the importance of using a hindered rotor treatment instead of a harmonic oscillator model for calculating vibrational partition functions corresponding to low-frequency internal rotation modes. First, a normal-mode analysis according to the Ayala and Schlegel's algorithm has been used to identify the internal rotation modes of methanethiol and the transition state structure. Then, after calculation of the energy barrier for each internal rotation, the corresponding hindered rotor partition functions have been calculated following the CW scheme of Chuang and Truhlar. The results show that the anharmonic treatment produces a rather modest improvement of the rate constants at room temperature or below. 相似文献
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The conversion and residence time were investigated during the bulk polymerization of styrene in a twin screw extruder. It was found that polymerization mainly occurred in the zone between 400 and 1000 mm along the screw axis in the extruder, corresponding to the residence time of the reactants ranging from 1 to 4 min in the extruder. Furthermore, the processing conditions (feed rate, screw rotation rate) and average molecular weight of the polymer have a great effect on the residence time. Based on dimensionless analysis, a model of the residence time has been built‐up, which has been confirmed by the results of realistic measurements. A kinetic model of the polymerization has also been established under the assumption that the screw extruder can be regarded as an ideal plug flow reactor. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
7.
本文对对流方程ut=aux建立了中间层包含两个节点,带两个参变量m,k的一般三层显格式.当m,k满足一定关系时,上述格式变为二阶格式.稳定性分析表明,当参数k<1/2时,格式的稳定条件为网格比的绝对值不超过1,这一点区别于色散方程的类似情况. 相似文献
8.
C. Damas M. Adibnejad A. Benjelloun A. Brembilla M. C. Carré M. L. Viriot P. Lochon 《Colloid and polymer science》1997,275(4):364-371
Cationic amphiphilic polymers (e.g. polyvinylpyridinium bromides and polyvinylimidazo-lium bromides) adopt a compact coiled
form in aqueous solutions. In the case of former polymers, the resulting hydrophobic microdomains are evidenced only by fluorescence
spectroscopy if a molecular rotor (DMAC) is used as a fluorescent probe, while the behaviour of the latter can be studied
in aqueous solution by using both types of fluorescent probes, i.e., pyrene and the molecular rotor. The purpose of the present
investigation deals with a comparative study between the magnitude of the local viscosity and the polarity of the hydrophobic
microdomains generated by poly(3-hexadecyl-1-vinylimidazolium bromide) in an aqueous medium using pyrene and DMAC as fluorescent
probes. Moreover, the results are compared with the data obtained with micelles of conventional surfactants such as the homopolymer
repetitive unit model and CTAB.
Received: 3 June 1996 Accepted: 29 September 1996 相似文献
9.
针对钢筋混凝土桥墩压弯承载力的计算,提出了基于极限状态的截面应力-应变关系,并分别以等效矩形应力图和混凝土应力-应变公式处理受压区混凝土的抗力计算图式,将轴压-压弯-纯弯的计算方法统一起来,使计算更简捷,最后给出工程应用实例. 相似文献
10.
渐开线曲面因其特性和成熟的加工方法被广泛应用于机械工程中.罗茨泵中转子上的渐开线曲面,常用的加工方法有数控镗铣、仿形铣、仿形刨等.本文通过对渐开线曲面形成和特性的分析,给出了在牛头刨床上用展成法加工渐开线曲面的方法. 相似文献