全文获取类型
收费全文 | 30492篇 |
免费 | 2354篇 |
国内免费 | 3223篇 |
专业分类
化学 | 9306篇 |
晶体学 | 157篇 |
力学 | 1234篇 |
综合类 | 241篇 |
数学 | 5972篇 |
物理学 | 4044篇 |
综合类 | 15115篇 |
出版年
2024年 | 106篇 |
2023年 | 335篇 |
2022年 | 701篇 |
2021年 | 815篇 |
2020年 | 1093篇 |
2019年 | 807篇 |
2018年 | 754篇 |
2017年 | 849篇 |
2016年 | 1005篇 |
2015年 | 983篇 |
2014年 | 1553篇 |
2013年 | 1969篇 |
2012年 | 1655篇 |
2011年 | 1824篇 |
2010年 | 1390篇 |
2009年 | 1670篇 |
2008年 | 1618篇 |
2007年 | 2023篇 |
2006年 | 1848篇 |
2005年 | 1593篇 |
2004年 | 1441篇 |
2003年 | 1427篇 |
2002年 | 1212篇 |
2001年 | 960篇 |
2000年 | 882篇 |
1999年 | 764篇 |
1998年 | 666篇 |
1997年 | 536篇 |
1996年 | 570篇 |
1995年 | 469篇 |
1994年 | 417篇 |
1993年 | 347篇 |
1992年 | 312篇 |
1991年 | 243篇 |
1990年 | 210篇 |
1989年 | 191篇 |
1988年 | 171篇 |
1987年 | 142篇 |
1986年 | 89篇 |
1985年 | 91篇 |
1984年 | 59篇 |
1983年 | 32篇 |
1982年 | 56篇 |
1981年 | 32篇 |
1980年 | 18篇 |
1979年 | 37篇 |
1978年 | 20篇 |
1977年 | 26篇 |
1976年 | 22篇 |
1973年 | 12篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
Qianqian Fan Zirui Liu Feng Qiu Prof. Yong Mao Prof. Qingju Liu Prof. Longzhou Zhang 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(63):e202202700
The artificially accurate design of nonmetal electrocatalysts’ active site has been a huge challenge because no pure active species with the specific structure could be strictly controlled by traditional synthetic methods. Species with a multiconfiguration in the catalyst hinder identification of the active site and the subsequent comprehension of the reaction mechanism. We have developed a novel electro-assisted molecular assembly strategy to obtain a pure pentagon ring on perfect graphene avoiding other reconstructed structures. More importantly, the active atom was confirmed by the subtle passivation process as the topmost carbon atom. Recognition of the carbon-defect electrocatalysis reaction mechanism was first downsized to the single-atom scale from the experimental perspective. It is expected that this innovative electro-assisted molecular assembly strategy could be extensively applied in the active structure-controlled synthesis of nonmetal electrocatalysts and verification of the exact active atom. 相似文献
2.
为提高煤与瓦斯突出矿井瓦斯抽放效果,建立了3个一级指标、14个二级指标的突出矿井瓦斯抽放限制影响因素评价指标体系,利用AHP和熵权法分别确定指标因子主、客观权重.通过实地调研分析和反馈验证了AHP-熵权法的可行性和正确性,利用加权平均法确定评价模型的综合权重.研究表明:封孔方式、钻孔半径、抽放时间、煤体裂隙发育程度和抽放负压是目前影响煤矿瓦斯抽放效果的主控因素. 相似文献
3.
Prediction of drag reduction effect caused by pulsating pipe flows is examined using machine learning. First, a large set of flow field data is obtained experimentally by measuring turbulent pipe flows with various pulsation patterns. Consequently, more than 7000 waveforms are applied, obtaining a maximum drag reduction rate and maximum energy saving rate of 38.6% and 31.4%, respectively. The results indicate that the pulsating flow effect can be characterized by the pulsation period and pressure gradient during acceleration and deceleration. Subsequently, two machine learning models are tested to predict the drag reduction rate. The results confirm that the machine learning model developed for predicting the time variation of the flow velocity and differential pressure with respect to the pump voltage can accurately predict the nonlinearity of pressure gradients. Therefore, using this model, the drag reduction effect can be estimated with high accuracy. 相似文献
4.
以应用ProCAST和MAGMAsoft 2款软件为例,针对铸造工艺仿真设计前处理和过程处理每个环节的主要内容与使用方法进行了较为详细地归纳、分析和总结。提出了处理过程的技术路线,并系统地介绍了每项应用内容的操作平台与使用步骤,从而为高效地应用铸造工艺仿真设计提供理论和技术支持。 相似文献
5.
Dekun Wu Dr. Qing Xu Dr. Jing Qian Prof. Xiaopeng Li Prof. Yuhan Sun 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(12):3105-3111
Covalent organic frameworks (COFs) are a new class of crystalline porous polymers comprised mainly of carbon atoms, and are versatile for the integration of heteroatoms such as B, O, and N into the skeletons. The designable structure and abundant composition render COFs useful as precursors for heteroatom-doped porous carbons for energy storage and conversion. Herein, we describe a multifunctional electrochemical catalyst obtained through pyrolysis of a bimetallic COF. The catalyst possesses hierarchical pores and abundant iron and cobalt nanoparticles embedded with standing carbon layers. By integrating these features, the catalyst exhibits excellent electrochemical catalytic activity in the oxygen reduction reaction (ORR), with a 50 mV positive half-wave potential, a higher limited diffusion current density, and a much smaller Tafel slope than a Pt-C catalyst. Moreover, the catalyst displays superior electrochemical performance toward the hydrogen evolution reaction (HER), with overpotentials of −0.26 V and −0.33 V in acidic and alkaline aqueous solution, respectively, at a current density of 10 mA cm−2. The overpotential in the catalysis of the oxygen evolution reaction (OER) was 1.59 V at the same current density. 相似文献
6.
《Stochastic Processes and their Applications》2020,130(5):2596-2638
In this paper we introduce a new generalisation of the relative Fisher Information for Markov jump processes on a finite or countable state space, and prove an inequality which connects this object with the relative entropy and a large deviation rate functional. In addition to possessing various favourable properties, we show that this generalised Fisher Information converges to the classical Fisher Information in an appropriate limit. We then use this generalised Fisher Information and the aforementioned inequality to qualitatively study coarse-graining problems for jump processes on discrete spaces. 相似文献
7.
基于汤姆路透公司的ESI和InCites数据库,分析了中国地质大学各学科的特征,探讨了高被引论文、热门论文、顶尖论文与学科发展的关系,并预测后续最有可能入围ESI世界前1%的学科。 相似文献
8.
Kai Xu Zhenchang Tang Yan Zhang Wanshu Li Haiou Li Lihui Wang Liming Liu Honghang Wang Feng Chi Xiaowen Zhang 《Current Applied Physics》2019,19(10):1076-1081
Germanium dioxide (GeO2) aqueous solutions are facilely prepared and the corresponding anode buffer layers (ABLs) with solution process are demonstrated. Atomic force microscopy, X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy measurements show that solution-processed GeO2 behaves superior film morphology and enhanced work function. Using GeO2 as ABL of organic light-emitting diodes (OLEDs), the visible device with tris(8-hydroxy-quinolinato)aluminium as emitter gives maximum luminous efficiency of 6.5 cd/A and power efficiency of 3.5 lm/W, the ultraviolet device with 3-(4-biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole as emitter exhibits short-wavelength emission with peak of 376 nm, full-width at half-maximum of 42 nm, maximum radiance of 3.36 mW/cm2 and external quantum efficiency of 1.5%. The performances are almost comparable to the counterparts with poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) as ABL. The current, impedance, phase and capacitance as a function of voltage characteristics elucidate that the GeO2 ABL formed from appropriate concentration of GeO2 aqueous solution favors hole injection enhancement and accordingly promoting device performance. 相似文献
9.
探讨在Linux操作系统中基于代理的进程迁移方法,包括代理的组织、代理的通讯方式、迁移进程信息的获取及进程迁移后未完成报文和打开文件的处理等. 相似文献
10.
杨忠辉 《浙江万里学院学报》2003,16(3):142-144
培养具有创新精神和实践能力的高级专门人才是时代赋予高等教育的历史重任,而教学过程是实现这一目标的重要途径,文章就优化教学过程,在良好的教学过程中培养学生的创新意识作了一些探索。提出了相关的观点。 相似文献