基于WEB方式的电子政务初探

本提出了基于WEB方式的电子政务设计、开发、运营方法和技术平台的总体框架。描述了电子政务数据开发模型的雄度，电子政务系统工程的实施原则、实施步骤及应用系统集成的一整套的实践模型。     

Nonlinear Time Series Analysis Since 1990:Some Personal Reflections

Abstract I reflect upon the development of nonlinear time series analysis since 1990 by focusing on five majorareas of development. These areas include the interface between nonlinear time series analysis and chaos,thenonparametric/semiparametric approach,nonlinear state space modelling,financial time series and nonlinearmodelling of panels of time series.     

Protective Properties of Zinc-Rich Coatings: An Impedance Method Estimate

The impedance of zinc-rich polymer coatings on steel in a 3-% NaCl solution is studied. The electrochemical behavior of the electrode is satisfactorily described by an equivalent circuit that contains a constant-phase element, which reflects fractal properties of the zinc surface in the binder. From the results of calculations of the circuit elements for metal-rich electrodes with different zinc contents computed are fractions of the active area of the surface of the coating and its fractal dimensionality.     

Study of non-isothermal crystallization of amorphous Cu<Subscript>50</Subscript>Ti<Subscript>50</Subscript> alloy

The crystallization kinetics of amorphous Cu₅₀Ti₅₀ has been studied using differential scanning calorimetry (DSC) under non-isothermal conditions. The curves at different linear heating rates (2, 4, 8 and 16 K min^–1) show sharp crystallization peaks. The crystallization peak shifts to higher temperatures with increasing heating rate. The Kissingers method of analysis of the shift in the transformation peak is applied to evaluate the activation energy (E _c). The KJMA formalism, which is basically developed for isothermal experiments, is also used to obtain E _c and the Avrami parameter (n).The DSC data have been analysed in terms of kinetic parameters, viz. activation energy (E _c), Avrami exponent (n) and frequency factor K ₀ using three different theoretical models. It is observed that the activation energy values derived from KJMA approach and modified Kissinger equation agree fairly well with each other. The activation energy values obtained from normal Kissinger method, and Gao and Wang expression underestimate the activation energy.The financial support provided by All India Council for Technical Education (AICTE), New Delhi (Govt. of India) is gratefully acknowledged.     

Intermolecular hydrogen bonds: Comparison of associates in crystals and liquids

The density and sound velocity were measured within wide ranges of temperature for a number of liquids (water, formamide, diols, aliphatic alcohols, cellosolves, ketones), in which various types of H-associate can exist. The temperature dependences of the adiabatic and molar adiabatic compressibility, density, and molar volume are analyzed. The values of the molar adiabatic compressibility permit one to evaluate the dimensionality of H-associates existing in liquids; the values of adiabatic compressibility do not offer this possibility. The terms responsible for the similarity and difference between H-associates in crystals and liquids are discussed.     

Monte—Carlo model of the diffusion-limited reaction kinetics in microheterogeneous media. Comparison with the experimental plots of the forward and backward electron phototransfer kinetics on the pore diameter in silica gel

The kinetics of the diffusion-limited decay reaction A + B B was simulated by the Monte—Carlo method on a two-dimensional square lattice with defects presented by randomly distributed sites. The cases were considered where [B] [A] at the random initial distribution (quenching reaction) and [B] = [A] with the initial distribution of the A and B particles on neighboring sites (geminate recombination). The kinetic curves were approximated by the simplest analytical equation [A]/[A]₀ = (1 – )exp[–(kt)^1–h ] + (where k and are constants). The plots of the heterogeneity parameter (h) and time-averaged first-order rate constant vs. concentration of defects (p) or B particles (in the case of quenching) were obtained and compared with similar correlations obtained earlier by the experimental study of the kinetics of forward (quenching reaction) and backward (geminate recombination) electron phototransfer on the surface of different porous silica gels. The experimental plots of h vs. silica gel porosity are in satisfactory agreement with the plots of h vs. p in the model space, if the fraction of volume inaccessible for reactants, calculated from the free silica gel volume, is chosen as the p parameter for silica gel.Published in Russian in Izvestiya Akademii Nauk. Seriya Khimicheskaya, No. 8, pp. 1536–1541, August, 2004.     

一种新的彩色图像降维方法

基于内容的图像检索(CBIR)是图像检索的重要分支，而基于颜色的特征提取是CBIR的常用方法之一．如果对图像颜色的特征数提取过多、维数过大，则不利于对图像的快速匹配．本文将图像的色彩直方图作为输入向量，然后采用局部线性映射(LLE)算法对原始数据进行降维，并分别在4种色彩空间下对降维后的彩色图像进行分类．实验证明，在处理非线性数据降维时，LLE较主成分分析(PCA)具有明显的优势．     

基于属性降维的钓鱼网站检测方法

随着对钓鱼网站分析刻画的不断完善,使得钓鱼网站检测特征呈现高维化特点。属性维度的增加以及数据量的增长,会造成检测计算复杂度呈几何倍数扩大,导致检测时间复杂度高、占用资源大和检测效率低。针对多属性的钓鱼网站检测,设计了一种基于属性降维的钓鱼网站检测方法。该方法使用信息增益方法对原始数据进行特征选择,筛除可能存在的冗余和噪声数据信息;根据不同属性间的互信息计算属性相关性矩阵,利用属性相关性矩阵作为权值参与加权主成分分析;根据得到的降维后新特征数据通过监督学习算法构建钓鱼网站检测模型。实验表明,该方法可以有效降低原始数据中冗余和噪声属性的干扰,能够有效检测出复杂网络环境中的钓鱼网站,同时具有较高的稳定性。     

The Prospect of Dimensionality in Porous Semiconductors

With the advent of silicon-based semiconductors, a plethora of previously unknown technologies became possible. The development of lightweight low-dimensional organic semiconductors followed soon after. However, the efficient charge/electron transfers enabled by the non-porous 3D structure of silicon is rather challenging to be realized by their (metal-)organic counterparts. Nevertheless, the demand for lighter, more efficient semiconductors is steadily increasing resulting in a growing interest in (metal-)organic semiconductors. These novel materials are faced with a variety of challenges originating from their chemical design, their packing and crystallinity. Although the effect of molecular design is quite well understood, the influence of dimensionality and the associated change in properties (porosity, packing, conjugation) is still an uncharted area in (metal-)organic semiconductors, yet highly important for their practical utilization. In this Minireview, an overview on the design and synthesis of porous semiconductors, with a particular emphasis on organic semiconductors, is presented and the influence of dimensionality is discussed.