α-Al2O3微粉对镁质浇注料性能的影响

研究α-Al2O3微粉加入量对钢包渣线用镁铝质浇注料线变化率、显气孔率、耐压强度和抗渣性能的影响,借助EDAX分析,探讨了浇注料的渣蚀机理。结果表明,随着α-Al2O3质量分数的增加,经1000℃×3h热处理后,浇注料的线变化率逐渐增大,显气孔率增加,耐压强度提高;经1600℃×3h热处理后,浇注料的线变化率逐渐增加,显气孔率稍有减小,耐压强度逐渐降低,但当α-Al2O3质量分数大于10%后,浇注料的耐压强度增加;随着α-Al2O3质量分数的增加,浇注料渗透指数逐渐减小,但侵蚀指数明显增大。镁铝质浇注料的性能变化主要与材料的组成和显微结构相关。     

铝灰合成Sialon复合粉对铁沟浇注料性能的影响

用以铝灰为原料所制得的4种Sialon复合粉分别替换铁沟料原配方中的部分细粉,研究Sialon复合粉对铁沟浇注料性能的影响.结果表明,将合成的Sialon复合粉体用于A12O3-SiC-C质铁沟浇注料,可以显著提高其110 ℃×24 h和1 450 ℃×3 h处理后的常温物理性能,使其1 450 ℃×0.5 h氧化后的常温抗折强度升高,但会使试样的高温抗折强度有所降低.     

基质组成对MgO-Al2O3质浇注料性能的影响

研究基质组成对MgO-Al2O3质浇注料热震稳定性和抗渣性能的影响.结果表明,随着α-Al2O3含量的增加,MgO-Al2O3质浇注料1600℃×3 h抗折强度逐渐降低,α-Al2O3质量分数大于15%后抗折强度明显增大;α-Al2O3加入量为10%～15%时浇注料具有最佳的热震稳定性;随着α-Al2O3含量的增加,浇注料渗透指数明显减小,侵蚀指数逐渐增大.MgO-Al2O3质浇注料的性能主要与基质的组成和显微结构相关.     

硅微粉对提高中间包浇注料使用性能的研究

根据中间包浇注料的使用条件和损毁原因，探讨了硅微粉的加入对中间包浇注料的热震稳定性、抗渣侵蚀性和热膨胀性的影响．结果表明，硅微粉的加入量为4a％时，中间包浇注料的上述性能良好．     

Research on application of different particle sizes of cordierite on castable refractory

Effect of different particle sizes of cordierite on properties of castable refractory by different heat treatment temperatures were investigated respectively with mullite and bauxite as raw materials,calcium aluminate cement as binders.After 24 h curing in mould and another 24 h curing at 110 ℃ after demoulding,the specimens were heat treated at 1 000 ℃,1 300 ℃ and 1 500 ℃ for 3 h,respectively.The bulk density(BD),permanent linear change(PLC),modulus of rupture(MOR)and clod crushing strength(CCS),thermal expansion coefficient and thermal shock resistance were examined.The results show that there is no obvious effect on adjusting permanent linear change and bulk density of castables by adding different particle sizes of cordierite at low temperature and intermediate temperature.Modulus of rupture of castable increase with the decreasing of the particle sizes of cordierite after heat treated by 1 000 ℃ and 1 300 ℃.In this experiment,thermal shock resistance of the castable with cordierite whose particle size is 0~1 mm is the best.     

回转窑窑口新型浇注料的研制

利用均化矾土和电熔莫来石为主要原料,添加少量碳化硅,以铝酸钙水泥为结合剂,制备了一种新型窑口浇注料。通过其与现场刚玉-莫来石质浇注料进行对比,得出以下结论:4.8%的加水量以及粒度分布系数为0.34的新型浇注料具有较高的体积密度和常温强度;新型浇注料1 400℃在基质中原位形成了大量的莫来石相使其高温抗折强度提高了10倍,高温下在基质部分生成的原位莫来石与原料中引入的柱状莫来石呈网络交叉结构,使其4%荷重软化温度提高了200℃以上;在新型浇注料配方中的电熔莫来石及碳化硅细粉,均起到了提高材料的热震稳定性及高温耐磨性的作用。     

循环流化床锅炉用高性能刚玉质耐火浇注料的研制

以刚玉为原料，通过加入添加剂和使用复合结合剂来改善浇注料机质，制备出了具有优良理化性能和使用性能的高性能刚玉质浇注料。     

高炉非金属冷却壁用耐火浇注料合理配置的研究

针对高炉各部位使用条件的差异，对高炉非金属冷却壁用耐火浇注料的合理配置进行了研究．结果表明，在炉身工作温度低于800℃的上部选用矾土水泥结合的高铝质浇注料；在800-1000℃的炉身下部选用纯铝酸钙水泥结合的高铝质浇注料；在工作温度高，渣侵蚀比较严重的妒腰部位用抗侵蚀性好，冷却强度大的纯铝酸钙水泥结合高铝-碳化硅质浇注料．     

中间包永久衬浇注料用结合剂

以B级高铝矾土熟料为骨料，A级矾土熟料为基质料，同时加入蓝晶石、硅线石为膨胀荆，紫木节粘土为烧结剂、塑化剂，研究了分别采用硅灰、高铝水泥、水玻璃、复合结合剂等为结^合剂的不同配方组成的浇注料。通过浇注料试样性能检测比较，探讨了不同种类结合剂对浇注料性能的影响，实验证明复合结合剂更有利于浇注料性能的提高。     

Nitroxy/Azido‐Functionalized Triazoles as Potential Energetic Plasticizers

The synthesis of a series of nitroxy‐ and azido‐functionalized compounds, based on 4‐amino‐3,5‐di(hydroxymethyl)‐1,2,4‐triazole, for possible use as an energetic plasticizers is described. All compounds were fully characterized. Two of them were further confirmed by X‐ray single crystal diffraction. Energetic performance was calculated by using EXPLO5 v6.01 based on calculated heats of formation (Gaussian 03) and experimentally determined densities at 25 °C. The results show that the nitration product 1‐nitro‐3,5‐di(nitroxymethyl)‐1,2,4‐triazole, containing a nitro group and two nitroxy groups, exhibits good detonation properties (D=8574 m s^?1, P=32.7 GPa). In addition, its low melting point makes it very attractive as an energetic plasticizer in solid propellants.