A Shell-by-Shell Approach for Synthesis of Mesoporous Multi-Shelled Hollow MOFs for Catalytic Applications

Over the past two decades, advanced materials with hollow interiors have received significant attention in materials research owing to their great application potential across a vast number of technological fields. Though with great difficulty, multi-shelled hollow metal–organic frameworks (MSHMs) have also been successfully synthesized in recent years. Herein, a rational shell-by-shell soft-templating protocol has been devised to fabricate highly uniform multi-shelled hollow cobalt-imidazole-based MOF (ZIF-67). For the first time, it has become possible to endow mesoporosity to this new type of functional material (i.e., mesoporous MOFs). When used as carrier materials in catalytic reactions, in principle, these mesoporous MSHMs with high surface area not only improve the dispersity of metal nanoparticles (NPs), but also efficiently facilitate the mass diffusion of the reactions, resulting in enhanced catalyst activity. Moreover, the obtained MSHMs/M nanocomposites serve as base-metal bifunctional catalysts for one-pot oxidation-Knoevenagel condensation cascade reaction, in which the MSHMs itself serves as a pristine active catalyst in addition to its role of catalyst support. The results demonstrate that excellent multifunctional catalysts can be achieved via preparing intrinsically microporous bulk MOFs into extrinsically mesoporous MSHMs which possess many structural merits that conventional bulk MOFs do not have.     

二项式光场与级联三能级原子的量子纠缠

利用量子熵理论，研究了二项式光场与级联三能级原子的量子纠缠，讨论了光场与原子的初始参量对其量子纠缠性质的影响.结果表明，利用二项式光场的特性，可以揭示从相干态到数态之间的所有态光场与三能级原子相互作用时的量子纠缠性质.选择适当的系统参数可以制备稳定的光场-原子qutrit纠缠态. 关键词： 二项式光场 级联三能级原子 光场熵 量子纠缠     

Highly strained InxGa(1−x)As−InyAl(1−y)As (x>0.8,y<0.3) layers for short wavelength QWIP and QCL structures grown by MBE

Highly strained quantum cascade laser (QCL) and quantum well infrared photodetector (QWIPs) structures based on In_xGa_(1−x)As−In_yAl_(1−y)As (x>0.8,y<0.3) layers have been grown by molecular beam epitaxy. Conditions of exact stoichiometric growth were used at a temperature of 420°C to produce structures that are suitable for both emission and detection in the 2–5 μm mid-infrared regime. High structural integrity, as assessed by double crystal X-ray diffraction, room temperature photoluminescence and electrical characteristics were observed. Strong room temperature intersubband absorption in highly tensile strained and strain-compensated In_0.84Ga_0.16As/AlAs/In_0.52Al_0.48As double barrier quantum wells grown on InP substrates is demonstrated. Γ–Γ intersubband transitions have been observed across a wide range of the mid-infrared spectrum (2–7 μm) in three structures of differing In_0.84Ga_0.16As well width (30, 45, and 80 Å). We demonstrate short-wavelength IR, intersubband operation in both detection and emission for application in QC and QWIP structures. By pushing the InGaAs–InAlAs system to its ultimate limit, we have obtained the highest band offsets that are theoretically possible in this system both for the Γ–Γ bands and the Γ–X bands, thereby opening up the way for both high power and high efficiency coupled with short-wavelength operation at room temperature. The versatility of this material system and technique in covering a wide range of the infrared spectrum is thus demonstrated.     

级联三能级原子与单模场相互作用下的腔场谱

研究了高Q腔内级联三能级原子与单模光场相互作用模型的腔场谱.结果表明,原子初态处于上能级时，随R=g2/g1的增大,真空场的拉比峰个数按2→6→4→2→4的规律变化，在R1时，所有的拉比峰都消失.在初始场较弱时,腔场谱可出现3峰、5峰或7峰.在初始场很强时,腔场谱中只有单一的经典共振峰.如果原子初态处在中能级且R=1,腔场谱为简单的对称双峰结构，与标准J-C模型的谱相似. 关键词： 级联三能级原子 单模光场 腔场谱     

数字式八脉冲触发器

本文介绍了自行研制的数字式八脉冲触发器．该触发器运行可靠，抗干扰能力强，性能、价格比高，在电力电子技术的应用中有一定的推广价值     

1.5μm波段基于级联二阶非线性的铌酸锂光波导全光波长变换的理论分析

研究了基于级联二阶非线性的铌酸锂波导全光波长变换器的特性.首先从耦合模方程出发,比较了数值分析结果与小信号近似分析的结果.其次在数值分析基础上,分析了铌酸锂晶体的温度变化导致相应基频光波波长与极化反转光栅周期的变化关系.最后分析了在不同相互作用长度下,转换的光波功率与有效基频光波波长带宽、温度调谐带宽、极化反转光栅周期带宽等关系,以对全光波长变换器件进行优化设计 关键词： 级联二阶非线性 波长变换 准位相匹配 铌酸锂光波导     

进口畸变条件下改善压气机性能的数值研究

依据"非定常两代流型"理论,验证了二维叶栅在均匀进气条件下,施加激励对其性能所起的改善作用,尔后重点研究了进口具有总压的周向畸变时,施加激励对其气动性能的影响。计算结果表明,在有无进口畸变时,施加一定的激励都会改善流场结构,气动参数有积极变化,压升和效率增加,特别是在流量比较小时,变化尤为明显.对于进口畸变和施加激励影响压气机性能的内在原因,从流场结构的变化方面进行了初步分析。     

大型电站锅炉主蒸汽温度的模块化阶梯式动态矩阵控制

针对淮南平圩电厂#1锅炉主蒸汽温度难以自动调节的问题,在充分了解系统特性、综合考虑各个扰动因素后,作者引入10个影响因素,提出了采用模块化、阶梯式动态矩阵控制方案,成功地解决了该厂2008t/h锅炉主蒸汽温度难以自动调节的问题,使其控制指标达到540±3℃之内,优于国家标准540±4℃.这一实施方案能解决大惯性、大时延及多扰动系统控制问题,具有在线辨识、滚动优化和实时反馈等优点.     

Solutions in Sobolev spaces of vector refinement equations with a general dilation matrix

In this paper, we present a necessary and sufficient condition for the existence of solutions in a Sobolev space W_p^k(ℝ^s) (1≤p≤∞) to a vector refinement equation with a general dilation matrix. The criterion is constructive and can be implemented. Rate of convergence of vector cascade algorithms in a Sobolev space W_p^k(ℝ^s) will be investigated. When the dilation matrix is isotropic, a characterization will be given for the L_p (1≤p≤∞) critical smoothness exponent of a refinable function vector without the assumption of stability on the refinable function vector. As a consequence, we show that if a compactly supported function vector φ∈L_p(ℝ^s) (φ∈C(ℝ^s) when p=∞) satisfies a refinement equation with a finitely supported matrix mask, then all the components of φ must belong to a Lipschitz space Lip(ν,L_p(ℝ^s)) for some ν>0. This paper generalizes the results in R.Q. Jia, K.S. Lau and D.X. Zhou (J. Fourier Anal. Appl. 7 (2001) 143–167) in the univariate setting to the multivariate setting. Dedicated to Professor Charles A. Micchelli on the occasion of his 60th birthday Mathematics subject classifications (2000) 42C20, 41A25, 39B12. Research was supported in part by the Natural Sciences and Engineering Research Council of Canada (NSERC Canada) under Grant G121210654.