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1.
玻璃陶瓷材料中Tm3+离子红外到蓝色上转换发光 总被引:4,自引:0,他引:4
系统研究了PbF2+GeO2+WO3ⅩⅣTmF3玻璃陶瓷材料中,在近红外光(1.06μm)激发下,Tm3+离子的发光特性.实验中观测到Tm3+离子的两组峰值位置分别在20920cm-1和22173cm-1的蓝色上转换发光,并证实这两组上转换发光分别与吸收三个和四个光子有关,同时建立了上转换发光的模型.为了选择最佳掺杂浓度,详细地测量了Tm3+离子峰值为20920cm-1的蓝色上转换发光强度与TmF3浓度的关系. 相似文献
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Pulsed laser deposition with a Nd:YAG laser was used to grow thin films from a pre-synthesized Ti3SiC2 MAX-phase formulated ablation target on oxidized Si(1 0 0) and MgO(1 0 0) substrates. The depositions were carried out in a substrate temperature range from 300 to 900 K, and the pressure in the deposition chamber ranged from vacuum (10−5 Pa) to 0.05 Pa Argon background pressure. The properties of the films have been investigated by Rutherford backscattering spectrometry for film thickness and stoichiometric composition and X-ray diffraction for the crystallinity of the films. The silicon content of the films varied with the energy density of the laser beam. To suppress especially the silicon re-sputtering from the substrate, the energy of the incoming particles must be below a threshold of 20 eV. Therefore, the energy density of the laser beam must not be too high. At constant deposition energy density the film thickness depends strongly on the background pressure. The X-ray diffraction measurements show patterns that are typical of amorphous films, i.e. no Ti3SiC2 related reflections were found. Only a very weak TiC(2 0 0) reflection was seen, indicating the presence of a small amount of crystalline TiC. 相似文献
4.
Total-reflection X-ray fluorescence spectrometry has been compared with Instrumental Neutron Activation Analysis in order to test its potential application to the study of archaeological ceramics in the archaeometric field. Two direct solid non-chemical sample preparation procedures have been checked: solid sedimentation and solid chemical homogenization. For sedimentation procedure, total-reflection X-ray fluorescence allows the analysis of the elemental composition with respect to the size fraction but not the average evaluation of the composition. For solid chemical homogenization procedure, total-reflection X-ray fluorescence provides precise (from 0.8% to 27% of coefficient of variation) and accurate results (from 91% to 110% of recovery) for 15 elements (Cr, Hf, Ni, Rb, Al, Ba, Ca, K, Mn, Ti, V, Cu, Ga, Y and Fe) with an easy sample preparation process of the solid clay and without previous chemical treatment. The influence of the particle sizes has been checked by total-reflection X-ray fluorescence sample angle scans and anomalous behaviors have been found for three additional detected elements: As, Sr and Zn, which can be attributed to interference effects of the mineral grain sizes of their associated chemical phases in the total-reflection X-ray fluorescence interference region. The solid chemical homogenization procedure produces data useful for archaeological interpretation, which is briefly illustrated by a case-study. Finally, the decantation procedure data can be also useful for size chemical speciation and, consequently, for alternative environmental total-reflection X-ray fluorescence applications. 相似文献
5.
朱开佩 《浙江万里学院学报》2005,18(1):92-94
陶瓷艺术已由传统的艺术程式进入了现代艺术表现阶段.在陶瓷艺术中,材质既是一种物质材料,又是重要的艺术表现手段.文章从传统陶瓷材质的单一性到现代陶瓷材质的丰富性为前导,探索综合材质与现代陶艺结合表现的诸多可能性,为现代陶艺表现形式的多样性起到一定的促进作用. 相似文献
6.
在国内氧化铝生产过程中采用板式蒸发器浓缩铝酸钠溶液是一种新的尝试。但国内几家氧化铝生产厂家在使用中相继发生了板片开裂现象。文章对板式蒸发器的设计、制造及使用中如何消除这一现象作了一些有益的探讨。 相似文献
7.
Ozao R. Yoshida H. Inada T. Ochiai M. 《Journal of Thermal Analysis and Calorimetry》2003,72(1):113-118
Nanoporous alumina membrane prepared by anodic oxidation using sulfuric acid electrolyte was subjected to TG-DTA and X-ray
Photoelectron Spectroscopy (XPS or ESCA) to further study the distribution of sulfur. In XPS study, Ar+ ion bombardment was performed on the sample to etch the surface at a rate of 3 nm min-1. As a result, sulfur was found to be concentrated within a depth of 3nm from the surface. The S content of the surface was
found to be 2.7±0.5 wt%, and that at a depth of ca. 3 nm and ca. 10 nm was found to be as low as about 0.6±0.11 wt% (5.37±1.0
wt%→ 1.26±0.2wt% SO2). In TG-DTA, the mass loss of 7.3% was in fair agreement with that calculated on XPS results (7.1±1.2%).
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
8.
Chunlin Li Yilu Fu Guozhu Bian Tiandou Hu Yaning Xie Jing ZhanDepartment of Chemical Physics University of Science and Technology of China Hefei China Institute of High Energy Physics Chinese Academy of Sciences Beijing China 《天然气化学杂志》2003,12(3)
The Ni/CeO2-ZrO2-Al2O3 catalyst with different Al2O3 and NiO contents were prepared by hydrothermal synthesis method. The catalytic performance for CO2 reforming of CH4 reaction, the interaction among components and the relation between Ni content and catalyst surface basicity were investigated. Results show that the interaction between NiO and Al2O3 is stronger than that between NiO and CeO2-ZrO2.The addition of Al2O3 can prevent the formation of large metallic Ni ensembles, increase the dispersion of Ni, and improve catalytic activity, but excess Al2O3 causes the catalyst to deactivate easily. The interaction between NiO and CeO2 results in more facile reduction of surface CeO2. The existence of a small amount of metallic Ni can increase the number of basic sites. As metallic Ni may preferentially reside on the strong basic sites, increasing Ni content can weaken the catalyst basicity. 相似文献
9.
本文把扩展电阻法应用于陶瓷微区电导性能研究.建立了微区的定位标识系统,可精确、方便地对选定的微区进行电导性能及组分的重复测定.该方法在研究Ba(Sn_(1-x)Sb_x)O_3、ZnO及BaTiO_3半导体瓷应用中得到有意义的结果. 相似文献
10.
氟氧化物陶瓷的多谱线上转换发光 总被引:1,自引:0,他引:1
以氧化硅、氟化铅为基质制备了Er3 :Yb3 共掺杂氟氧化物陶瓷 ,X 射线分析表明陶瓷中存在着 β PbF2 晶相 ,沉积在其中的稀土离子由于具有很低的无辐射跃迁几率而显示出良好的上转换性能。Er3 ,Yb3 离子之间存在的多种能量传递通道 ,导致稀土离子十分丰富的上转换谱线的出现。 相似文献