纳米颗粒团聚物流化特性的数值研究

基于气固两相流体动力学理论,建立气体纳米颗粒团聚物两相流动双流体模型.模型中采用了Jung ＆ Gidaspow (2002)测量的固相应力模量和王垚等(2001)提出的聚团曳力系数计算模型.对纳米颗粒团聚物的流化过程进行了数值模拟,得到纳米颗粒团聚物的流化特性.模拟得出的床层膨胀比与文献中实验的结果较为接近.     

Influence of Particle Morphology and Flow Conditions on the Dispersion Behavior of Fumed Silica in Silicone Polymers

The dispersion behavior of agglomerates of several grades of fumed silica in poly(dimethyl siloxane) liquids has been studied as a function of particle morphology and applied flow conditions. The effects of primary particle size and aggregate density and structure on cohesivity were probed through tensile and shear strength tests on particle compacts. These cohesivity tests indicated that the shear strength of particle compacts was two orders of magnitude higher than the tensile strength at the same overall packing density. Experiments carried out in both steady and time‐varying simple‐shear flows indicate that dispersion occurs through tensile failure. In the steady‐shear experiments,enhanced dispersion was obtained at higher levels of applied stress and, at comparable levels of applied stress, dispersion was found to proceed faster at higher shear rates. Experiments conducted in time‐varying flows further corroborated the results obtained in tensile cohesivity tests. Experiments in which the mean and maximum stresses in the time‐varying flows were matched to the stresses produced in steady shear flows highlight the influence of flow dynamics on dispersion behavior.     

超声场中湿法制备氧化铝纳米粉

将超声波应用于湿法制备氧化铝纳米粉工艺过程，探讨了超声作用机理，研究了超声辐射对颗粒的形成和团聚以及干燥过程的影响，研究表明，超声能量能加速前驱体的形核，超声分散可控制晶核的长大和团聚；超声振动还能影响陈化过程中的沉淀向凝胶的转变，易得到疏松三维网络状结构，这样的凝胶结构有利于最后得到疏松、少（无）团聚的纳米粉体。     

Physical boundaries within aggregates – differences between amorphous,para‐crystalline,and crystalline Structures

The structural properties of finely divided inorganic materials such as metal and metalloid oxides, silicates or carbonates of both synthetic and natural origin are compared by means of electron microscopy and tomography. The structure of the outer surfaces of various compact or compacted agglomerates may suggest some striking similarities between various amorphous silica on the one hand and crystalline titania and alumina on the other however the details of the interior fine structure are completely different. Inside of the crystalline aggregates of, for example, alumina and titania distinct grain boundaries between the inter‐grown primary crystallites exist. Also physical boundaries between different solid phases and crystalline/amorphous transitions in core/shell structures can occur. No physical grain or phase boundaries were found inside of synthetic amorphous silica or para‐crystalline carbon black thus, the aggregate is the constituent particle. Synthetic amorphous silica from different production technologies (fumed/pyrogenic, precipitated, aerogel, gel) may exhibit different macro‐morphology but distinct similarities of the amorphous silica networks. Computational studies on silica and titania underline the stability of constituent particles and aggregates as observed by means of TEM after dispersing the original materials by ultra‐sonication.     

B2O3—MgO—SiO2—CaO—Fe3O4系固结块的抗压强度和还原性

用五因子回归正交设计法对Ｂ２Ｏ３－ＭｇＯ－ＳｉＯ２－ＣａＯ－Ｆｅ３Ｏ４五元系的抗压强度、还原性同组分、温度的关系做了系统的研究，建立了抗压强度、还原率两指标同Ｂ２Ｏ３，ＭｇＯ，ＳｉＯ２，ＣａＯ／ＳｉＯ２，ｔ因素的二次回归数学模型，Ｂ２Ｏ３对还原性影响不大，而对抗压强度影响显著，当Ｂ２Ｏ３含量为４－６％时，抗压强度最大，ＭｇＯ增加还原性降低，但对抗压强度影响不大，随着温度上升，抗压强度和还原性均降低     

影响烧结矿强度的因素及对策

分析了影响烧结矿强度的主要原因，提出了提高烧结矿强度的几条措施。     

一种基于网络的入侵检测模型及其实现

在入侵检测CIDF体系结构基础上,提出了基于网络的二层式多数据包分析入侵检测模型.这一模型中,事件分析器对当前事件分两层进行处理:先将当前事件结合历史事件进行关联分类,找出与当前事件关联紧密的历史事件;然后对包含当前事件的这一类关联事件进行回归分析,最终发现潜在的协同攻击和分布式入侵行为.仿真试验说明该算法模型能够检测出传统入侵检测系统难以发现的分布式入侵行为.     

Silica surface modification using different aliphatic chain length silane coupling agents and their effects on silica agglomerate size and processability

Silica surface was treated with various aliphatic chain length silane coupling agents and compounded in EPDM using an internal mixer, and their agglomerate sizes, viscosity, and extrudate swell were investigated. The treated silica compounds showed smaller agglomerate size, lower viscosity, and lower swell reduction compared to untreated silica compound after equivalent mixing times. Short chain silane treated silica compound exhibited smallest agglomerate size. Silane acted as dispersing agents and processing aids in silica/EPDM compounds.     

高速公路团雾驾驶员视错觉特性与行车安全研究综述

高速公路团雾路段行车安全问题一直是中国交通行业面临的难题。为提高团雾环境下的行车安全,明确团雾环境行车安全研究中的关键问题。本文综述了国内外团雾环境行车安全影响因素及研究进展。首先,阐述了驾驶人的视觉特性,论述团雾感知下降会造成视错觉的原因,分析了团雾出现前的“象鼻形”曲线,阐明了团雾环境下人车路与交通安全之间的关系,最后归纳了现阶段确保团雾路段行车安全采取的管控措施。研究结论表明：团雾环境下能见度的急剧下降,会严重影响驾驶人的感知,干扰驾驶员的视觉,并造成距离和速度错觉。为了提高团雾环境下的驾驶安全性,通过监控和预警系统提前使驾驶员提高警惕,并开发各种诱导设施,以加强视觉诱导。未来需从减少视错觉影响的角度研究复杂因素影响下的驾驶视觉需求。     

山区微尺度环境探测参数拟合“瘴气”曲线

无线探测网络(wireless sensor network,WSN)可以方便采集复杂微环境物理参数,通过对多参数曲线拟合,形成描述微环境的拟合参数集与拟合参数曲线。研究通过具有单向对流通道的山地微环境的WSN多参数连续探测,揭示了微环境的微颗粒搬移过程。山区微环境不同空间存在的植被残屑、花粉等有害粉末与山地团雾混合后,通过对流与山风等微环境气象形成的物质搬迁。当搬迁物质在低地空间产生物质沉积,成为山区瘴气等灾害动因。实验通过沿通道部署多参数WSN,通过对团雾的识别与颗粒密度(搬迁物质)峰值曲线拟合,证实了这种上团雾的迁移规律,部分证实了历史上瘴气存在与影响。