Controlled synthesis of ZnO nanoparticles from a Zn(II) coordination polymer: Structural characterization,optical properties and photocatalytic activity

A zinc coordination polymer derived from pyridine-2,6-dicarboxylate (PDC), {[Zn₂(PDC)₂]}_n, was successfully prepared via conventional, sonication and microwave-irradiation methods. The composition and characteristics of the obtained coordination polymers (CPs) were investigated by elemental analysis, TGA/DTA, X-ray diffraction and spectroscopic techniques. The so obtained CPs were heat-treated in the air at 600 °C for 2 h to produce ZnO of nanosized particles (NPs). It is of interest to note that the synthesis approach of the precursor greatly affects both the nanoparticle size and the structure of the resulting ZnO NPs. Moreover, the smallest particle size was associated with the sample derived from the ultrasonically prepared precursor. TEM analysis revealed that all samples have sphere-like morphologies. Structural analysis of the prepared ZnO samples was conducted and compared using Rietveld analysis of their PXRD patterns. Optical band gap calculations based on analysis of the UV–vis spectra of ZnO samples using Tauc's power law were achieved. The highest band gap of 3.63 eV was observed for ZnO sample obtained from the ultrasonically prepared precursor. Furthermore, the photocatalytic activity of ZnO NPs for the removal of Eosin Y color was monitored. The highest removal efficiency was recorded for ZnO originated from the ultrasonically synthesized precursor. Enhancement of removal efficiency that reached 98% was attained in only a period of 8 min. Its recycling test showed that it can be reused without structural changes over four cycling experiments.     

含氟废水处理研究与应用

本文就近年来国内对含氟废水处理研究及应用概况作了简要综述，可看出含氟废水处理的研究有了较大进展。     

新型纳米纤维膜对地下水中重金属的过滤去除研究

采用扫描电镜表征了氯化聚氯乙烯静电纺丝纳米纤维膜的微观结构特征,并进行了去除地下水中铜、铅、镉等重金属阳离子的过滤试验,包括直接过滤、加土壤过滤、加硅藻土过滤和胶束强化过滤。结果表明,最佳的过滤工艺是胶束强化过滤,其最佳试验条件是10层膜过滤和5mmol/L的SDBS浓度,对铜、铅、镉的去除率分别超过73%,82%和91%。     

山东潍坊某办公大楼整体平移技术

采用钢筋混凝土包柱夹墙式托换结构和高性能工程塑料滚轴，对某办公大楼整体平移，监测结果表明，房屋平移6m后整体性提高。平移的成功以及由此取得的明显经济与社会效益，表明本工程设计方案与施工技术先进合理，可为类似整体平移工程提供参考。     

着生刚毛藻处理富营养化湖泊水

分别研究了室内和露天条件下在鹅卵石上着生的刚毛藻Cladophora oligoclona对富营养化湖水中氮(N)和磷(P)的净化效果及其对水华藻类生长的抑制能力,同时对处理后湖水的藻类生长潜力进行了测试.结果显示,刚毛藻在原始浓度总氮(TN)10.512 mg/L和总磷(TP)0.856 mg/L的富营养化湖水中能维持正常的生长代谢,并能有效去除水体中的N、P养分.在室内12 d培养期间,刚毛藻对TN、氨氮(NH4-N)、TP和无机磷(PO4-P)的平均去除率分别达53.13%,44.40%,35.71%和30.53%.在室外6 d培养期间,刚毛藻对TN、NH4-N、TP和PO4-P的日均减少量分别为1.643 5±0.413 9,1.350 3±0.352 4,0.113 7±0.041 1,0.074 2±0.033 0 mg/L,总去除率分别高达93.81%,94.62%,79.67%和77.66%.刚毛藻对水华微囊藻生长的抑制率达99.63%,处理后湖水的藻类生长潜力较原湖水下降了40.17%.据此认为,刚毛藻在净化污染水体、修复受损湖泊及防治水体富营养化等方面具有潜在的应用前景.     

炼钢厂引风机叶轮粘灰控制

对目前广泛采用的炼钢厂一次烟气引风机叶轮冲水清灰效果不佳的原因进行了分析，提出采用压缩气体清灰的思路，并计算了供气压力。现场实际运行效果表明，风机运行周期超过1个月。     

冶炼工业废气中SO_2的脱除研究

研究用软锰矿的水悬浮液脱除冶炼工业废气中SO_2的工艺可行性,提出抑制副产物MnS_2O_6生成的途径。     

有分离调整和移走时间的两机器流水作业最大延误问题

在工件的调整时间和移走时间独立于加工时间的两机器流水作业问题中，同一工件的“调整”步及“移走”步在两台机器上可重叠进行，但“加工”步不能重叠，本以最大延误为目标函数讨论问题的解中工件排列应满足的条件，根据这些条件我们构作了两个近似算法。     

一个检测超流的早期淘汰算法

超流是网络中具有大量不同宿IP/源IP链接的源IP/宿IP.实时检测出高速网络（OC48、OC192等）中的超流对网络安全具有非常重要的意义.近年来已经有论文提出了不同超流检测算法,但是这些算法都没有考虑控制测量过程中超流缓存空间的大小.论文在超流检测过程中增加了早期淘汰功能,将超流缓存中链接数较少的记录提前淘汰,以便腾出空间用于存储新检测到的IP记录,实现对超流缓存资源的控制.论文最后还使用实际网络日志数据对算法进行验证,实验表明：早期淘汰算法可以使系统以更少的内存空间和测量资源检测超流信息.     

NCO-新型干洗剂的研究

本文论述了以近代物理方法和化学分析手段剖析美国“三羊牌”去污精结构组成,结合干洗剂基础理论研究,立足国情进行合成、配方、筛选,研制出新型干洗剂NCO—O1、NCO—06,其性能相当于进口样品,应用面广。