A post curing strategy toward the feasible covalent adaptable networks in polyacrylate latex films

The implementation of covalent adaptable networks (CANs) in general resin system is becoming attractive. In this work, we propose a simple post-curing strategy based on the core-shell structured acrylate latex for the achievement on both the improved general performance and the CANs characteristics in latex films. The building to the CANs was relied on the introduction of 4,4′-diaminophenyl disulfide as the curing agent, which cured the acetoacetoxy decorated shell polymer through the ketoamine reaction. The metathesis reaction of aromatic disulfides in the crosslinking segments enabled the thermally induced dynamic behavior of the network as revealed in the stress relaxation tests by comparison with other diamine crosslinking agents without the incorporation of disulfide. The synergism of the dynamic crosslinking of the shell polymer and static crosslinking in the core polymer contributed to the improved mechanical strength (15 MPa, strain% = 250%) and the suppressed water adsorption (~1% in 24 h of soaking) of the latex film, which exhibited above 90% of recovery in both strength and strain from a cut-off film damage within 1 h at 80°C. Moreover, the cured latex film could be recycled, and 75% of the mechanical performance was regained after three fragmentation-hot-pressing cycles. These, in addition with the feasible and environmental friendly characteristics, suggest a sustainable paradigm toward the smart thermosetting latex polymers.     

Precise Synthesis and Thin Film Self-Assembly of PLLA-b-PS Bottlebrush Block Copolymers

The ability of bottlebrush block copolymers (BBCPs) to self-assemble into ordered large periodic structures could greatly expand the scope of photonic and membrane technologies. In this paper, we describe a two-step synthesis of poly(l-lactide)-b-polystyrene (PLLA-b-PS) BBCPs and their rapid thin-film self-assembly. PLLA chains were grown from exo-5-norbornene-2-methanol via ring-opening polymerization (ROP) of l-lactide to produce norbornene-terminated PLLA. Norbonene-terminated PS was prepared using anionic polymerization followed by a termination reaction with exo-5-norbornene-2-carbonyl chloride. PLLA-b-PS BBCPs were prepared from these two norbornenyl macromonomers by a one-pot sequential ring opening metathesis polymerization (ROMP). PLLA-b-PS BBCPs thin-films exhibited cylindrical and lamellar morphologies depending on the relative block volume fractions, with domain sizes of 46–58 nm and periodicities of 70–102 nm. Additionally, nanoporous templates were produced by the selective etching of PLLA blocks from ordered structures. The findings described in this work provide further insight into the controlled synthesis of BBCPs leading to various possible morphologies for applications requiring large periodicities. Moreover, the rapid thin film patterning strategy demonstrated (>5 min) highlights the advantages of using PLLA-b-PS BBCP materials beyond their linear BCP analogues in terms of both dimensions achievable and reduced processing time.     

红树林保护与修复标准发展现状及对策

回顾近20年来中国对红树林的保护以及通过人工造林进行恢复的情况, 梳理我国红树林保护与修复的相关标准, 厘清现行标准存在的问题, 提出如下相应的建议与对策。1) 应结合国家碳中和战略及红树林保护与恢复规划目标, 制定完善的红树林保护与生态修复技术标准体系规划, 加快相关国家标准的出台; 2) 在编制红树林保护与修复相关标准的同时, 应注重红树林固碳能力和增汇效应的提高; 3) 建议制定退塘还林相关标准, 填补国内空白; 4) 应充分落实“自然恢复为主、人工修复为辅”的生态修复原则, 重视并加强红树林保护与修复标准的技术细节制定; 5) 标准的制定和实施应由红树林研究专业机构及专家深度参与, 提高造林成活率。     

La$_{{1-x}}$Sr$_{x}$TiO$_{3}$ 薄膜的高通量 X 射线衍射

高通量材料合成方法和高通量材料表征手段区别于传统低效率的 "试错法"材料发展方法, 极大地加速了材料科学的变革和发展. 通过设计程序进行了高通量 X 射线衍射实验, 在保证数据分辨率条件下, 高效地表征了 La$_{1-x}$Sr$_{x}$TiO$_{3}$ 薄膜上多个数据位点的晶体结构, 验证了其成分的连续变化性质, 为后续开展更多类型的高通量 X 射线衍射实验提供了指导.     

Strain effects on multiferroic BiFeO3 films

The field of multiferroics has experienced a rapid progress resulting in the discovery of many new physical phenomena. BiFeO₃ (BFO) compound, which is one of the few room-temperature single-phase multiferroics, has contributed subsequently to this progress. As a result, significant review articles have been devoted specifically to this famous system. This chapter is dedicated to the strain effects on the structure stability and property changes of BFO thin films. It is a short and non-exhaustive topical overview that may be seen as an invitation for interested readers to go beyond. There is a very active and prolific research in this field and we apologize to the authors whose relevant work is not cited here. After a short introduction, we will thus review the effect of strain on BFO films by describing the consequences on the structure and the phase transitions as well as on polar, magnetic and magnetoelectric properties.     

动物试验方法的专利申请

 为判断动物试验方法是否具备实用性，分析了中国关于实用性的相关规定，通过4个典型案例对动物试验方法是否属于非治疗目的的外科手术方法、是否具备实用性进行了分析，总结判断标准并给出了撰写权利要求的建议。在撰写动物试验方法的专利申请时，应当注意该方法的目的及该方法是否包含外科手术步骤，并针对该方法的不同情况采用不同的撰写策略。     

基于DIS数字信息化系统对透光物质透光性能的研究

采用DIS数字信息化系统,对不同浓度的蓝墨水溶液在激光光源照射下的透射平均照度及照度分布图像进行实验研究,得到了平均照度值随溶液浓度变化的规律。对不同颜色塑料膜片对白炽灯光源透过照度值及照度分布图像进行实验研究得到及其相关之规律。     

网络时代隐私权的法律保护

对隐私权的概念进行了界定，提出了网络时代隐私权的侵权方式呈现出传统侵权方式与网络侵权方式并存的特点，并在分析我国隐私权法律保护现状的基础上，对网络时代隐私权法律保护的前景作了探讨，即赋予隐私权以独立性、在未来民法典中对隐私权的法律保护做一般性规定、在某些特别领域对隐私权的法律保护做具体性规定以及从国际私法的角度对隐私权加以保护．     

关于高速公路施工中的环保监理

根据高速公路施工合同协议规定的环保监理的义务 ,结合施工实践 ,从路基施工、桥梁施工及取土场、弃土场等规范施工的要求 ,阐述环保监理的控制方法     

"经营城市"与北京历史文化名城的保护、利用

高水平“经营城市”是中共北京市第九次党代会就北京城市发展建设提出的明确要求，而且是在北京要率先实现现代化这一背景下提出的要求。同时，做好北京历史文化名城的保护、利用也是党中央、图书馆对北京城市发展建设提出的具体要求。这两者有着内在的联系，是同一体的两个方面，而不是对立的两个方面。北京提出“经营城市”理念包含着历史文化名城的保护、利用，北京历史文化名城的保护、利用也可以引入“经营城市”理念。为此，北京应进一步全面普查历史文化遗存，深入发掘这些有形资源和无形资源的历史文化价值，进行合理保护和充分利用。