A simple,rapid and sensitive method based on modified multiwalled carbon nanotube for preconcentration and determination of lead ions in aqueous media in natural pHs

In this study, multiwalled carbon nanotube (MWCNT) was modified by the pyridine group using a silane agent and characterized by infrared spectroscopy (IR), thermal analysis (TG/DTA), and elemental analysis (CHN) and scanning electron microscopy (SEM). The application of this sorbent was investigated in determination of lead ions in aqueous samples, using flame atomic absorption spectrometry (FAAS). Through this study, different parameters such as pH and sample flow rate on adsorption process and eluent concentration, volume and flow rate were optimized. The limit of detection (LOD), the relative standard deviation and the recovery of the method were 2 ng mL^?1, 1.3% and 99.7%, respectively. Two standard reference materials (NIST 1571 and NIST 1572) were used to verify accuracy of this method. Finally, the sorbent was successfully applied for extraction and determination of low levels of Pb(II) ions in aqueous samples.     

A Variable Neighborhood Search for the Multi Depot Vehicle Routing Problem with Time Windows

The aim of this paper is to propose an algorithm based on the philosophy of the Variable Neighborhood Search (VNS) to solve Multi Depot Vehicle Routing Problems with Time Windows. The paper has two main contributions. First, from a technical point of view, it presents the first application of a VNS for this problem and several design issues of VNS algorithms are discussed. Second, from a problem oriented point of view the computational results show that the approach is competitive with an existing Tabu Search algorithm with respect to both solution quality and computation times.     

Complete systems, elementary submodels and the tightness of upper hyperspaces

We introduce and study some completeness properties for systems of open coverings of a given topological space. A Hausdorff space admitting a system of cardinality κ satisfying one of these properties is of type Gκ. Hence, we define several new variants of the ?ech number and use elementary submodels to determine further results. We introduce M-hulls and M-networks, for M elementary submodel. As an application, we give estimates for both the tightness and the Lindelöf number of a generic upper hyperspace. Two recent results of Costantini, Holá and Vitolo on the tightness of co-compact hyperspaces follow from ours as corollaries.     

基于Windows NT的HRPS-Ⅱ设备的控制系统设计

介绍了华中科技大学开发的HRPS-Ⅱ型选择性激光烧结设备的体系结构，根据选择性激光烧结的工作原理并结合该系统的硬件结构开发了基于NT操作系统下的控制软件．该控制软件是一种分层的结构，各个不同优先级的任务在不同的层面上运行，实时性强的部分运行在硬件中断级别上，对控制软件的关键性技术进行了描述．通过试验运行，该设备成功地加工出了复杂的原型件，证明控制系统开发是成功的．     

Counterpoise-corrected potential energy surfaces of simple H-bonded systems

Geometries and stabilization energies of various simple H-bonded complexes (water dimer, hydrogen fluoride dimer, formamide dimer, formic acid dimer) have been determined by a gradient optimization that eliminates the basis set superposition error (BSSE) by the counterpoise (CP) method in each gradient cycle as well as by the standard gradient optimization. Both optimization methods lead to different potential energy surfaces (PES). The difference depends on the theoretical level used and is larger if correlation energy is considered. Intermolecular distances from the CP-corrected PES are consistently longer, and this difference might be significant (∼0.1 ?); also angular characteristics determined from both surfaces differ significantly. Different geometries were obtained even when passing to larger basis sets (aug-cc-pVDZ). The standard optimization procedure can result in a completely wrong structure. For example, the “quasi-linear” structure of the (HF)₂ (global minimum) does not exist at the standard MP2/ 6-31G** PES (where only cyclic structure was detected) and is found only at the CP-corrected PES. Stabilization energies obtained from the CP-corrected PES are always larger than these from the standard PES where the BSSE is added only a posteriori for the final optimized structure; both energies converge only when passing to a larger basis set (aug-cc-pVDZ). Received: 11 March 1998 / Accepted: 19 June 1998 / Published online: 4 September 1998 RID=" ID=" <E6>Acknowledgements.</E6> The project was supported by the Grant Agency of the Czech Republic (Grant No. 203/98/1166). RID=" ID=" <E5>Correspondence to</E5>: P. Hobza     

Highly diastereoselective chemoenzymatic synthesis of (2′R)- and (2′S)-2′-deoxy[2′-H]guanosines

In an effort to develop an efficient synthetic method of highly diastereoselective (2′R)- and (2′S)-2′-deoxy[2′-²H]guanosines, chemoenzymatic conversion was investigated. The synthesis of (2′R > 98% de)-2′-deoxy[2′-²H]guanosine was achieved by biological transdeoxyribosylation using (2′R > 98% de)-2′-deoxy[2′-²H]uridine, 2,6-diaminopurine, and Enterobacter aerogenes AJ-11125, followed by treatment with adenosine deaminase. (2′S > 98% de)-2′-Deoxy[2′-²H]guanosine was synthesized from (2′S > 98% de)-2′-deoxy[2′-²H]uridine and 2,6-diaminopurine using thymidine phosphorylase and purine nucleoside phosphorylase instead of E. aerogenes AJ-11125.     

基于MSComm控件的串行通信方法及实现

串行接口由于其具有连接简单、使用方便、数据传递可靠等优点，在工业实时控制系统中得到了广泛应用。本文探讨了基于Windows98平台上利用Microsoft Communica-tions Control控件编写串行通信程序的方法，并结合开发实践，阐述了用C Builder5语言实现了基于ActiveX技术的串行通信编程的一般步骤。实践表明，该方法简单、可靠，从而大大缩短实时控制软件的开发周期，减少程序员的工作量。     

WIN95环境下的双机通信

简要介绍了双机通信、资源共享的几种方法，并详细给出了在WINDOWS95环境下双机通信的具体方法和过程．     

多媒体CAI课件创作软件分析

根据多媒体ＣＡＩ课件创作的需求，分析了媒体数据获取、编辑、合成及件成形创作所需要的一些基本软件的功能与特色。     

Windows应用程序结构剖析及运行控制技术

分析了Ｗｉｎｄｏｗｓ系统的运行机制，指出Ｗｉｎｄｏｗｓ编程与ＤＯＳ编程的本质区别．以ＢｏｒｌａｎｄＣ＋＋为工具，剖析了Ｗｉｎｄｏｗｓ应用程序结构，探讨了控制其运行的技术．以多媒体数据库中实时挂接视霸卡捕捉的图像数据为例，说明了运用该技术对不同工具开发的Ｗｉｎｄｏｗｓ应用程序的运行实施控制的方法