全文获取类型
收费全文 | 15183篇 |
免费 | 813篇 |
国内免费 | 1377篇 |
专业分类
化学 | 7183篇 |
晶体学 | 26篇 |
力学 | 234篇 |
综合类 | 84篇 |
数学 | 311篇 |
物理学 | 2022篇 |
综合类 | 7513篇 |
出版年
2024年 | 57篇 |
2023年 | 269篇 |
2022年 | 324篇 |
2021年 | 386篇 |
2020年 | 389篇 |
2019年 | 321篇 |
2018年 | 293篇 |
2017年 | 346篇 |
2016年 | 464篇 |
2015年 | 540篇 |
2014年 | 889篇 |
2013年 | 858篇 |
2012年 | 859篇 |
2011年 | 1051篇 |
2010年 | 864篇 |
2009年 | 1018篇 |
2008年 | 953篇 |
2007年 | 1063篇 |
2006年 | 904篇 |
2005年 | 873篇 |
2004年 | 736篇 |
2003年 | 586篇 |
2002年 | 477篇 |
2001年 | 375篇 |
2000年 | 337篇 |
1999年 | 266篇 |
1998年 | 291篇 |
1997年 | 293篇 |
1996年 | 250篇 |
1995年 | 170篇 |
1994年 | 168篇 |
1993年 | 145篇 |
1992年 | 89篇 |
1991年 | 89篇 |
1990年 | 89篇 |
1989年 | 69篇 |
1988年 | 64篇 |
1987年 | 43篇 |
1986年 | 23篇 |
1985年 | 24篇 |
1984年 | 14篇 |
1983年 | 5篇 |
1982年 | 15篇 |
1981年 | 7篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1977年 | 3篇 |
1975年 | 2篇 |
1974年 | 4篇 |
1973年 | 3篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
1.
2.
Edward G. Sheetz Zhao Zhang Alyssa Marogil Minwei Che Dr. Maren Pink Dr. Veronica Carta Prof. Dr. Krishnan Raghavachari Prof. Dr. Amar H. Flood 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(60):e202201584
The recognition of boron compounds is well developed as boronic acids but untapped as organotrifluoroborate anions (R−BF3−). We are exploring the development of these and other designer anions as anion-recognition motifs by considering them as substituted versions of the parent inorganic ion. To this end, we demonstrate strong and reliable binding of organic trifluoroborates, R−BF3−, by cyanostar macrocycles that are size-complementary to the inorganic BF4− progenitors. We find that recognition is modulated by the substituent's sterics and that the affinities are retained using the common K+ salts of R−BF3− anions. 相似文献
3.
Ajit Kumar Singh Seulgi Ji Baghendra Singh Chittaranjan Das Heechae Choi Prashanth W. Menezes Arindam Indra 《Materials Today Chemistry》2022
Herein, we report a Mott-Schottky catalyst by entrapping cobalt nanoparticles inside the N-doped graphene shell (Co@NC). The Co@NC delivered excellent oxygen evolution activity with an overpotential of merely 248 mV at a current density of 10 mA cm–2 with promising long-term stability. The importance of Co encapsulated in NC has further been demonstrated by synthesizing Co nanoparticles without NC shell. The synergy between the hexagonal close-packed (hcp) and face-centered cubic (fcc) Co plays a major role to improve the OER activity, whereas the NC shell optimizes the electronic structure, improves the electron conductivity, and offers a large number of active sites in Co@NC. The density functional theory calculations have revealed that the hcp Co has a dominant role in the surface reaction of electrocatalytic oxygen evolution, whereas the fcc phase induces the built-in electric field at the interfaces with N-doped graphene to accelerate the H+ ion transport. 相似文献
4.
5.
《云南民族大学学报(自然科学版)》2015,(6):510-513
普米语是一种无文字的少数民族语言,目前已处于濒危状态,建立语音语料库及开展语音识别研究是保护和传承普米语的重要手段.基于HTK的语音识别中,参数的选取对不同语言的识别率有很大的影响.针对MFCC维数、HMM状态数及GMM个数这3个参数对普米语的识别率进行研究,结果表明:普米语语音识别的最佳MFCC维数为13维,最佳HMM状态数为8个,最佳GMM个数为3个. 相似文献
6.
《自然科学进展(英文版)》2020,30(2):185-191
Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts. 相似文献
7.
通过对电子阅览室读者满意度的问卷调查和对调查数据的分析,对电子阅览室服务质量进行了综合评价,旨在进一步完善电子阅览室的各项工作,从而提升读者对图书馆的满意度. 相似文献
8.
Field-effect transistors (FETs) are one of the most widely-used electronic sensors for continuous monitoring and detection of contaminants such as pharmaceuticals and endocrine-disrupting compounds at low concentrations. FETs have been successfully utilized for the rapid analysis of these environmental pollutants due to their advantageous material properties like the disposability, rapid responses and simplicity. This paper presented an up-to-date overview of applied strategies with different bio-based materials in order to enhance the analytical performances of the designed sensors. Comparison and discussion were made between characteristics of recently engineered FET bio-sensors used for the detection of famous and selected pharmaceutical compounds in the literature. The recent progress in environmental research applications, comments on interesting trends, current challenge for future research in endocrine-disrupting chemicals’ (EDCs) detection using FETs biosensors were highlighted. 相似文献
9.
Multi-sensor data fusion is an evolving technology whereby data from multiple sensor inputs are processed and combined. The data derived from multiple sensors can, however, be uncertain, imperfect, and conflicting. The present study is undertaken to help contribute to the continuous search for viable approaches to overcome the problems associated with data conflict and imperfection. Sensor readings, represented by belief functions, have to be fused according to their corresponding weights. Previous studies have often estimated the weights of sensor readings based on a single criterion. Mono-criteria approaches for the assessment of sensor reading weights are, however, often unreliable and inadequate for the reflection of reality. Accordingly, this work opts for the use of a multi-criteria decision aid. A modified Analytical Hierarchy Process (AHP) that incorporates several criteria is proposed to determine the weights of a sensor reading set. The approach relies on the automation of pairwise comparisons to eliminate subjectivity and reduce inconsistency. It assesses the weight of each sensor reading, and fuses the weighed readings obtained using a modified average combination rule. The efficiency of this approach is evaluated in a target recognition context. Several tests, sensitivity analysis, and comparisons with other approaches available in the literature are described. 相似文献
10.
近年来深度卷积神经网络在可见光船舶检测方面取得了显著的进展,然而,大多数相关研究是通过改进大型的网络结构来提高检测性能,因此加大了对更高计算机性能的需求。此外,可见光图像难以在云、雾、海杂波、黑夜等复杂场景检测到船舶。针对以上问题,提出了一种融合红(red, R)、绿(green, G)、蓝(blue, B)和近红外(NIR)4个波段光谱信息的由粗到精细的轻量型船舶检测算法。与现有的方法中根据光谱特性利用水体检测算法提取水体区域不同之处是该算法是利用改进的水体检测算法来提取船舶候选区域。为获取更准确的候选区域,对船舶、厚云、薄云、平静海面、杂波海面5种场景中4个波段的像素值进行了统计分析,选取近红外大于阈值作为辅助判断,并以其中心点获取候选区域32×32大小的切片,并对切片进行非极大值抑制,由此获得了船舶粗检测结果。随后构建了轻量级LSGFNet网络对船舶候选区域切片进行精细识别。构建的网络融合了1×1卷积提取的波谱特征与3×3的提取几何特征,为防止光谱特征与几何特征的信息在融合时“信息不流通”,在LSGFNet网络中引入了ShuffleNet中的通道打乱机制,并减小了模型结构,与典型的轻量级网络相比具有更好的效果且模型较小。最后,利用Sentinel-2卫星多光谱10 m分辨率数据构建了512×512大小的1 120组数据进行粗检测,以及32×32大小的6 014组数据进行精细网络训练,其中候选区域粗提取的查全率为98.99%,精细识别网络精确度为96.04%,不同场景下的平均精确度为92.98%。实验表明该算法在抑制云层、海浪杂波等干扰的复杂背景下具有较高的检测效率,且训练时间短、计算机性能需求低。 相似文献