建筑与寻常景观——华南理工大学建筑设计院创作室环境设计

从设计定位、空间布局、技术细节三方面入手,详细介绍了华南理工大学建筑设计院创作室环境设计的理念和手法。论述了作为建筑设计事务所周边环境的设计,如何做到如寻常景观一般与原有环境相融合的协调,并从中总结经验和教训。     

Synthesis and characterisation of bis(pentafluorophenyl)antimony(V) cations, [(C6F5)2SbL3]

Pentacoordinate complex cations of the general formula [(C₆F₅)₂SbL₃]³⁺ stabilized as solid salts in combination with tetraphenylborate (BPh₄), tetrafluorobroate (BF₄) anions, where L=DMSO, Ph₃AsO, PyO, DMF, α-, β- and γ-picoline have been isolated. The newly formed complexes were characterized by elemental analysis, molar conductance measurements, solid-state IR and View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022113903000940-si3.gif"> and View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022113903000940-si4.gif"> NMR. From these results, a five-fold coordination around antimony was required.     

The regioselectivity of the formation of 2-pyrazolylthiazoles and their precursors from the reaction of 2-hydrazinothiazoles with 4,4,4-trifluoro-1-hetaryl-1,3-butanediones

Reaction of 2-hydrazinothiazoles 1 with 1-thienyl- and 1-furyl-1,3-butanediones 2a,b in methanol in the presence of hydrochloric acid mainly leads to a mixture of pyrazoles 3 and pyrazolines 4 or pyrazoles 3 and 5 in strong acidic conditions. Isomeric hydrazones 6 and pyrazolines 4 were formed and isolated in these reactions in the absence of hydrochloric acid. It has been shown that the regioselectivity in the reaction of diketones 2 with hydrazine 1 is governed by both the concentration of acid and the nature of substituents in the 1,3-diketones 2. Cyclization of hydrazones 6 is shown to occur under milder conditions than dehydration for pyrazolines 4. The new heterocyclic compounds were prepared and fully characterized by NMR spectra and by X-ray analysis for 3c.     

Molecular structure and spectral properties of thionaphthalimides

The molecular structure and absorption spectra of monothio- and dithio-naphthalimides were compared to their naphthalimide analogues using AM1, PM3 and ZINDO/S semiempirical quantum chemical methods. The substitution of the 4R-naphthalimide oxygen atoms by sulphur atoms resulted in a red-shift of the absorption spectra by Δλ_max60-65 and 100-140 nm, respectively. The thionated naphthalimide derivatives do not show observable fluorescence due to intersystem crossing to the triplet View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022286003003181-si8.gif">-states localised at the CS groups. The View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022286003003181-si9.gif">-absorption bands of monothioimides are located at 525-580 nm (ε=60-80) and those for dithioimides at 535-560 nm (ε=140-390) and 628-686 nm (ε=34-68). None of these transitions are solvent sensitive. The View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022286003003181-si10.gif">-transitions of N-phenylthioimides have also a small contribution from View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022286003003181-si11.gif">-states due to a partial conjugation between CS group and π-electronic system of the N-phenyl ring. As a result, the View the MathML source" title="View the MathML source" src="http://ars.els-cdn.com/content/image/1-s2.0-S0022286003003181-si12.gif"> bands of aromatic substituted N-phenylthioimides are red-shifted as compared to those of the aliphatic N-methyl-thioimides.     

关于高职课程观的探讨

课程观是课程开发、课程实施和课程评价的基本出发点,当前高职课程观从总体上可分为学科课程观和活动课程观两大类,二者均忽视作为课程存在基本条件的学生。要以学生的发展为视角,关注学生个体差异、关注学生认知、情感、态度的形成,树立开放的课程观。     

船用航迹仪的研究

用ＣＰＵ、ＣＲＴＣ及监示器组成电子海图，与ＧＰＳ接收机连接而构成航迹仪．其电子海图具有与纸质海图一样的直观效果．海图图象能移动、按比例放大或缩小，并具有描绘计划航线，记录并存储航迹等功能．其体积小，操作方便，易于推广应用．     

论学报编辑的参与意识

本文讨论的“参与意识”是指学报编辑人员在编辑稿件的过程中，在进入学科的前提下针对作者和稿件的具体情况，就选题、试验数据及处理、撰写角度、篇章结构等方面提出自己的建议并为作者所接受采纳，从而达到提高稿件质量的目的。高校学报编辑较一般刊物编辑的差异在于对作者和其科研工作通常比较了解，因此其参与意识具有独特优势和丰富的内涵     

稳定土厂拌站监控系统的设计与实现

针对稳定土厂拌站采用的电子计量微机控制的方式,研究了基于“组态王”工控组态软件的监控系统的设计和实现,分析了稳定土厂拌站配料系统的特点,进而确定了系统的硬件架构;接着介绍了用“组态王”设计监控软件各主要功能模块的基本思想及涉及到的几个技术难点;最后研究了系统实现稳定配比控制的算法,该算法主要采用增量式控制和输出限幅的思想.现场测试实验证明,本系统真实再现了稳定土厂拌站的生产工艺流程,实现了配方/生产报表管理、故障报警等功能,并能对配料过程进行实时控制,保证产品达到一定的配比要求.