全文获取类型
收费全文 | 2588篇 |
免费 | 293篇 |
国内免费 | 103篇 |
专业分类
化学 | 583篇 |
晶体学 | 7篇 |
力学 | 195篇 |
综合类 | 5篇 |
数学 | 223篇 |
物理学 | 1261篇 |
综合类 | 710篇 |
出版年
2024年 | 14篇 |
2023年 | 65篇 |
2022年 | 87篇 |
2021年 | 108篇 |
2020年 | 96篇 |
2019年 | 24篇 |
2018年 | 71篇 |
2017年 | 122篇 |
2016年 | 131篇 |
2015年 | 70篇 |
2014年 | 192篇 |
2013年 | 110篇 |
2012年 | 154篇 |
2011年 | 129篇 |
2010年 | 109篇 |
2009年 | 131篇 |
2008年 | 102篇 |
2007年 | 141篇 |
2006年 | 133篇 |
2005年 | 97篇 |
2004年 | 81篇 |
2003年 | 83篇 |
2002年 | 78篇 |
2001年 | 46篇 |
2000年 | 55篇 |
1999年 | 49篇 |
1998年 | 65篇 |
1997年 | 48篇 |
1996年 | 51篇 |
1995年 | 48篇 |
1994年 | 45篇 |
1993年 | 45篇 |
1992年 | 35篇 |
1991年 | 23篇 |
1990年 | 26篇 |
1989年 | 21篇 |
1988年 | 14篇 |
1987年 | 11篇 |
1986年 | 12篇 |
1985年 | 7篇 |
1984年 | 16篇 |
1983年 | 5篇 |
1982年 | 3篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1977年 | 5篇 |
1976年 | 2篇 |
1974年 | 3篇 |
排序方式: 共有2984条查询结果,搜索用时 31 毫秒
1.
In this study, parenchyma cellulose, which was extracted from maize stalk pith as an abundant source of agricultural residues, was applied for preparing cellulose nanoparticles (CNPs) via an ultrasound-assisted etherification and a subsequent sonication process. The ultrasonic-assisted treatment greatly improved the modification of the pith cellulose with glycidyltrimethylammonium chloride, leading to a partial increase in the dissolubility of the as-obtained product and thus disintegration of sheet-like cellulose into nanoparticles. While the formation of CNPs by ultrasonication was largely dependent on the cellulose consistency in the cationic-modified system. Under the condition of 25% cellulose consistency, the longer sono-treated duration yielded a more stable and dispersible suspension of CNP due to its higher zeta potential. Degree of substitution and FT-IR analyses indicated that quaternary ammonium salts were grafted onto hydroxyl groups of cellulose chain. SEM and TEM images exhibited the CNP to have spherical morphology with an average dimeter from 15 to 55 nm. XRD investigation revealed that CNPs consisted mainly of a crystalline cellulose Ι structure, and they had a lower crystallinity than the starting cellulose. Moreover, thermogravimetric results illustrated the thermal resistance of the CNPs was lower than the pith cellulose. The optimal CNP with highly cationic charges, good stability and acceptable thermostability might be considered as one of the alternatively renewable reinforcement additives for nanocomposite production. 相似文献
2.
马蹄寺石窟群地处河西走廊中部,气候条件十分恶劣。由于常年受到温度、湿度、酸碱盐等作用的影响,石窟岩体性能出现了不同程度的劣化现象。通过开展室内模拟试验,研究以上多种恶劣环境的循环作用对于岩体抗压强度、波速、质量的影响规律,同时使用X射线衍射仪(X-ray diffraction,XRD)、X射线荧光光谱(X-ray fluorescence,XRF)和扫描电子显微镜(scanning electron microscope,SEM)对循环作用过程中样品的矿物组分、元素含量和微观形貌进行分析研究。研究结果表明,循环作用使样品中的长石类矿物和方解石含量降低,黏土类矿物含量增加,胶结程度下降,孔隙逐渐发展成为横向微裂隙,导致样品的性能出现不同程度的劣化现象。循环作用对岩体性能的影响程度从大到小依次为冻融循环、耐盐循环、耐碱循环、耐酸循环和温湿循环。 相似文献
3.
系统研究了Nd0.5Ca0.5Mn1-xAlxO3(x=0,0.03)单相多晶样品在低温下的电磁性质和超声特性.电阻和磁化率测量表明,Nd0.5Ca0.5O3体系在TCO-257 K处发生了电荷有序相变.超声声速从室温开始随着温度的降低逐渐减小,并在TCO附近达到最小,之后,随着温度的进一步降低,声速急刷增加,同时伴随着一个尖锐的超声衰减峰出现.TCO附近的超声异常表明体系中存在着强烈的电-声子相互作用,该电-声子耦合来源于Mn3 的Jahn-Teller效应.在低温下,出现了另一个超声衰减峰,它的出现归结为反铁磁相与顺磁相之间的相分离现象.随着Al在Mn位的掺入,超声声速的最低点和衰减峰向低温移动,表明体系中的电荷有序态和反铁磁相均被部分抑制, 相似文献
4.
Hongwei Hao Minsheng Wu Yifang Chen Jiaowen Tang Qingyu Wu 《Colloids and surfaces. B, Biointerfaces》2004,33(3-4):151-156
To prevent cyanobacterial bloom in eutrophic water by ultrasonic method, ultrasonic irradiations with different parameters were tested to inhibit Spirulina platensis from growth. The experimental result based on cyanobacterial growth, chlorophyll a and photosynthetic activity showed that, the ultrasonic irradiation inhibited cyanobacterial proliferation effectively, furthermore the inhibition effectiveness increased in the order: 200 kHz>1.7 MHz>20 kHz and became saturated with the increased power. The inhibition mechanism can be mainly attributed to the mechanical damage to the cell structures caused by ultrasonic cavitation, which was confirmed by light microscopy and differential interference microscopy. The optimal frequency of 200 kHz in cavition and sonochemistry was also most effective in cyanobacterial growth inhibition. The higher frequency of 1.7 MHz is weaker than 20 kHz in cavitation, but has more effective inhibition because it is nearer to the resonance frequency of gas vesicle. The inhibition saturation with ultrasonic power was due to the ultrasonic attenuation induced by the acoustic shielding of bubbles enclosing the radiate surface of transducer. 相似文献
5.
6.
本文阐述了一种新的研究成果——用模型优适度寻找含水层主进水口位置的原理、方法和应用。模型优适度作为衡量地下水模型场势与原型(矿区)场势相似拟合程度的量度,它凭借含水层地下水场势对源点的响应差异,判别模型源点位置与原型源点位置是否一致、接近或偏离。本文给出了模型优适度的计算公式和用统计分析方法对动态矩阵施行标准化的公式推演过程。通过多次模拟试验,绘出优适度的等值线图,为华北某矿圈定含水层补给范围,进行注浆堵水,大大地降低了矿井涌水量,在实践应用中获得初步成功。 相似文献
7.
W. Hufenbach R. Böhm A. Langkamp L. Kroll T. Ritschel 《Mechanics of Composite Materials》2006,42(2):151-162
The basic damage and failure models of multiaxially reinforced composites with a thermoplastic matrix are presented and verified.
Within the framework of continuum damage mechanics, a phenomenological model is introduced, where the damage is defined as
a change in the elasticity tensor. For damage identification, a specific ultrasonic device was developed. A combination of
an immersion set-up and a contact coupling device formed a system for an efficient determination of stiffness-tensor components
from convenient sets of velocity measurements. Linked to a tensile machine, it allowed us to measure the anisotropic damage
of the new materials group caused by tensile loading.
Russian translation published in Mekhanika Kompozitnykh Materialov, Vol. 42, No. 2, pp. 221–234, March–April, 2006. 相似文献
8.
Two tests for multivariate conditional heteroscedastic models are proposed. One is based on the cross-correlations of standardized squared residuals and the other is a score (Lagrange multiplier) test. The cross-correlations test can be used to detect the presence of multivariate conditional heteroscedasticity whereas the other test can be used for diagnostic checking. Simulation studies on the size and power of the test statistics are reported. The application of the tests is illustrated by an example using the S & P 500 and Sydney All Ordinary Indexes. 相似文献
9.
筒型基础系缆平台沉/拔过程侧摩阻力原型测试 总被引:7,自引:1,他引:6
介绍了1999年首次安装在渤海锦州9-3地区多筒基础平台安装施工过程中的侧摩阻力原型测试研究,描述了简型基础上沉和上拔过程中筒壁侧摩阻力的测试系统和测试方法,给出了主要测试结果并与现行规范进行了对比分析,这项成果对筒型基础平台的设计和施工具有直接的参考意义。 相似文献
10.
Summary We discuss a null experiment to search for the fifth force at ranges around 10 km. It is proposed to use a three-axis gravity
gradiometer to measure the trace of the Earth gravity tensor from a freely falling elevator dropped by a balloon. The main
error sources are considered to some extent.
Paper presented at the V Cosmic Physics National Conference, S. Miniato, November 27–30, 1990. 相似文献