全文获取类型
收费全文 | 24448篇 |
免费 | 2936篇 |
国内免费 | 2829篇 |
专业分类
化学 | 10181篇 |
晶体学 | 291篇 |
力学 | 446篇 |
综合类 | 155篇 |
数学 | 1383篇 |
物理学 | 10981篇 |
综合类 | 6776篇 |
出版年
2024年 | 57篇 |
2023年 | 178篇 |
2022年 | 525篇 |
2021年 | 537篇 |
2020年 | 493篇 |
2019年 | 513篇 |
2018年 | 516篇 |
2017年 | 706篇 |
2016年 | 770篇 |
2015年 | 828篇 |
2014年 | 1143篇 |
2013年 | 1702篇 |
2012年 | 1522篇 |
2011年 | 1428篇 |
2010年 | 1213篇 |
2009年 | 1455篇 |
2008年 | 1501篇 |
2007年 | 1778篇 |
2006年 | 1550篇 |
2005年 | 1438篇 |
2004年 | 1208篇 |
2003年 | 1146篇 |
2002年 | 986篇 |
2001年 | 848篇 |
2000年 | 827篇 |
1999年 | 764篇 |
1998年 | 618篇 |
1997年 | 637篇 |
1996年 | 538篇 |
1995年 | 424篇 |
1994年 | 396篇 |
1993年 | 347篇 |
1992年 | 320篇 |
1991年 | 276篇 |
1990年 | 211篇 |
1989年 | 219篇 |
1988年 | 172篇 |
1987年 | 111篇 |
1986年 | 73篇 |
1985年 | 31篇 |
1984年 | 38篇 |
1983年 | 9篇 |
1982年 | 33篇 |
1981年 | 22篇 |
1980年 | 20篇 |
1979年 | 18篇 |
1978年 | 14篇 |
1977年 | 12篇 |
1974年 | 11篇 |
1973年 | 15篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
1.
Inside Cover: Photoinduced Formation of an Azobenzene‐Based CD‐Active Supramolecular Cyclic Dimer (Chem. Eur. J. 18/2015) 下载免费PDF全文
2.
根据GB 7475—87《水质铜、锌、铅、镉的测定火焰原子吸收分光光度法》建立地表水样测定的数学模型,并根据JJF 1059.1—2012《测量不确定度评定与表示》的要求,计算测量过程中的不确定度分量,最终得出扩展不确定度.经检测计算,该地表水样品中的铜含量为1.53 mg/L,其扩展不确定度为0.036 mg/L,包含因子k=2,地表水样品中铜含量的测量结果应报告为(1.53±0.036) mg/L, k=2.结果表明,火焰原子吸收分光光度法测定地表水样中铜含量的不确定度主要来源于标准曲线拟合、标准溶液配制和样品重复测量. 相似文献
3.
Leila Torkian Mostafa M. Amini Tayebeh Gorji Omid Sadeghi 《Arabian Journal of Chemistry》2019,12(7):1315-1321
In this study, multiwalled carbon nanotube (MWCNT) was modified by the pyridine group using a silane agent and characterized by infrared spectroscopy (IR), thermal analysis (TG/DTA), and elemental analysis (CHN) and scanning electron microscopy (SEM). The application of this sorbent was investigated in determination of lead ions in aqueous samples, using flame atomic absorption spectrometry (FAAS). Through this study, different parameters such as pH and sample flow rate on adsorption process and eluent concentration, volume and flow rate were optimized. The limit of detection (LOD), the relative standard deviation and the recovery of the method were 2 ng mL?1, 1.3% and 99.7%, respectively. Two standard reference materials (NIST 1571 and NIST 1572) were used to verify accuracy of this method. Finally, the sorbent was successfully applied for extraction and determination of low levels of Pb(II) ions in aqueous samples. 相似文献
4.
本文通过组合数学和矩阵论的方法获得了完全图的特征多项式和谱,指出完全图的特征多项式的系数与图的结构之间的关系,并证明了邻接谱、拉谱拉斯谱和无符号拉谱拉斯谱三者之间的关系. 相似文献
5.
Rational Molecular Design towards Vis/NIR Absorption and Fluorescence by using Pyrrolopyrrole aza‐BODIPY and its Highly Conjugated Structures for Organic Photovoltaics 下载免费PDF全文
Prof. Dr. Soji Shimizu Taku Iino Prof. Dr. Akinori Saeki Prof. Dr. Shu Seki Prof. Dr. Nagao Kobayashi 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(7):2893-2904
Pyrrolopyrrole aza‐BODIPY (PPAB) developed in our recent study from diketopyrrolopyrrole by titanium tetrachloride‐mediated Schiff‐base formation reaction with heteroaromatic amines is a highly potential chromophore due to its intense absorption and fluorescence in the visible region and high fluorescence quantum yield, which is greater than 0.8. To control the absorption and fluorescence of PPAB, particularly in the near‐infrared (NIR) region, further molecular design was performed using DFT calculations. This results in the postulation that the HOMO–LUMO gap of PPAB is perturbed by the heteroaromatic moieties and the aryl‐substituents. Based on this molecular design, a series of new PPAB molecules was synthesized, in which the largest redshifts of the absorption and fluorescence maxima up to 803 and 850 nm, respectively, were achieved for a PPAB consisting of benzothiazole rings and terthienyl substituents. In contrast to the sharp absorption of PPAB, a PPAB dimer, which was prepared by a cross‐coupling reaction of PPAB monomers, exhibited panchromatic absorption across the UV/Vis/NIR regions. With this series of PPAB chromophores in hand, a potential application of PPAB as an optoelectronic material was investigated. After identifying a suitable PPAB molecule for application in organic photovoltaic cells based on evaluation using time‐resolved microwave conductivity measurements, a maximized power conversion efficiency of 1.27 % was achieved. 相似文献
6.
Elsye Agustina Jeungchoon Goak Suntae Lee Youngho Seo Jun-Young Park Naesung Lee 《ChemistryOpen》2015,4(5):613-619
Iron catalysts have been used widely for the mass production of carbon nanotubes (CNTs) with high yield. In this study, UV/visible spectroscopy was used to determine the Fe catalyst content in CNTs using a colorimetric technique. Fe ions in solution form red–orange complexes with 1,10-phenanthroline, producing an absorption peak at λ=510 nm, the intensity of which is proportional to the solution Fe concentration. A series of standard Fe solutions were formulated to establish the relationship between optical absorbance and Fe concentration. Many Fe catalysts were microscopically observed to be encased by graphitic layers, thus preventing their extraction. Fe catalyst dissolution from CNTs was investigated with various single and mixed acids, and Fe concentration was found to be highest with CNTs being held at reflux in HClO4/HNO3 and H2SO4/HNO3 mixtures. This novel colorimetric method to measure Fe concentrations by UV/Vis spectroscopy was validated by inductively coupled plasma optical emission spectroscopy, indicating its reliability and applicability to asses Fe content in CNTs. 相似文献
7.
分析了不同的填充强化剂(后处理A液)、不同的后处理B液基料、后处理B液中水性环氧乳液的掺量及后处理液浸泡时间对石膏基打印器件耐水性、抗压强度、尺寸偏差、表面微观结构的影响.结果表明:经纳米硅超硬固化剂处理后的打印器件抗压强度大幅提高,纳米硅超硬固化剂最适宜作为后处理A液;水性聚氨酯乳液PU-202B最适宜作为后处理B液的基料;后处理B液中加入水性环氧乳液,处理后打印器件的抗压强度增加、吸水率降低,但水性环氧乳液含量增加到一定程度后会出现尺寸偏差;后处理A、B液最佳浸泡时间分别为130 s和35 s;先浸泡后处理A液、后浸泡后处理B液的打印器件具有抗压强度高、吸水率小、表面较光滑、不脱粉等优良性能. 相似文献
8.
设计了一种基于炉灶热量回收的吸热装置。该装置通过将导热性能及焊接性能优良的无氧紫铜管与炉灶支架焊接成一个整体,近距离吸收炉灶火焰四周散失的热量,利用火焰散失的热量给生活用水加热,将生成的热水供日常生活使用;对出水装置进行改良,使其与加热装置形成循环结构,达到对整个系统进行保护的目的。本装置提高了对能源的利用率,减少了能源消耗,达到节能的目的。 相似文献
9.
基于多变量希尔伯特频域模型的癫痫发作预测 总被引:1,自引:0,他引:1
癫痫发作具有突发性和反复性,对患者生命安全构成巨大威胁.为了对癫痫发作进行有效地预测,提出了多变量希尔伯特频域模型的癫痫发作预测方法.将希尔伯特边际谱、希尔伯特边际谱的变化方向和希尔伯特加权频率组成一个三维特征向量作为多变量希尔伯特频域模型,输入到支持相量机中,实现癫痫的发作预测,最后采用癫痫发作预测特征方法对预测结果进行评估.实验结果表明:采用多变量希尔伯特频域模型分析方法预测δ波和θ波的癫痫发作,癫痫预测范围在30~45 min,患者有足够的时间采取措施应对;癫痫发作周期在5~10 min,缩短患者等待时间,降低焦虑程度;与多种相关方法进行比较,该方法具有较低的错误预报率和较高的预测敏感度. 相似文献
10.
Inner derivations and norm equality 总被引:3,自引:0,他引:3
Mohamed Barraa Mohamed Boumazgour 《Proceedings of the American Mathematical Society》2002,130(2):471-476
We characterize when the norm of the sum of two bounded operators on a Hilbert space is equal to the sum of their norms.