沉积铁钝化膜的傅立叶变换表面增强拉曼光谱

利用恒电流沉积技术、傅立叶变换表面增强拉曼散射技术现场研究了0 1mol/LNaOH溶液中铁金属电极在不同电位下的表面氧化物的组成。结果表明,在电极预钝化区,表面首先生成的Fe(OH)2可由拉曼谱图中出现的550cm-1表征,证实了以往的研究结果。进入钝化区,表面二价氧化物逐步转化为高价氧化物Fe3O4及α 、δ 和γ FeOOH。在电位回扫的过程中,各氧化产物的还原以及铁表面SERS活性的逐渐消失导致谱峰强度降低。     

Introduction to Hardy Spaces

Basic material from the theory of Hardy spaces is presented. The principle of positive energy representations is used as motivation to introduce these spaces.     

Preservation of transform orders under a semiparametric model and its mixture

In this paper, sufficient conditions for preservation of several transform orders under a typical family of semiparametric distributions are made. The preservation properties are developed to compare mixture semiparametric distributions. Possible applications of the achieved results to compare scale family of distributions and also compare coherent systems with dependent but identical components and series and parallel systems with randomized number of components are provided.     

Bias in modal parameters due to aliasing in the time domain

This paper deals with some aliasing effects in the time domain that can lead to unacceptable misestimations of modal parameters. When a frequency response function of a vibrating system is sampled and inverse Fourier transformed, the resulting impulse response is given by an infinite geometric series, the single term of which is the impulse response itself shifted in time. For this reason, some modal parameters, if estimated in the time domain, are biased; in particular, while the damping factor and the natural frequency are not influenced by the aliasing phenomenon, the magnitude and phase of the residue can be highly biased. Corrective terms are theoretically evaluated and their efficiency is shown in numerical simulations.

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Sommario In questo articolo e' presentato un metodo per correggere gli errori che si compiono nella stima di alcuni parametri modali, quando essi vengono ricavati nel dominio del tempo. Infatti se la funzione di risposta in frequenza e' ottenuta con eccitazioni particolari—quali ad esempio lo pseudo-random, lo stepped-sine a passo costante o lo sweep in frequenza-la risposta impulsiva, ottenuta per mezzo dell'antitrasformata discreta di Fourier, risulta periodica, con periodo pari all'inverso della spaziatura tra le righe spettrali. Cio' comporta un errore nella stima dell'ampiezza e della fase del residuo, mentre nessuna conseguenza si ha sulla frequenza naturale e sul fattore di smorzamento. L'errore sulle stime risulta tanto piu' grande, quanto meno smorzata e' la risposta impulsiva all'interno dell'intervallo di osservazione.Partendo dall'inviluppo e dalla fase istantanea dei segnali complessi, ottenibili per mezzo della trasformata di Hilbert, si sono ricavati i termini correttivi sia per il modulo, che per la fase del residuo. La validita' delle correzioni e' mostrata con esempi numerici.

     

Efficient synthesis of magnetic nanoparticle-Musa acuminata peel composite for the adsorption of anionic dye

The impregnation of magnetite (Mt) nanoparticle (NPs) onto Musa acuminata peel (MApe), to form a novel magnetic combo (MApe-Mt) for the adsorption of anionic bromophenol blue (BPB) was studied. The SEM, EDX, BET, XRD, FTIR and TGA were used to characterize the adsorbents. The FTIR showed that the OH and CO groups were the major sites for BPB uptake onto the adsorbent materials. The average Mt crystalline size on MApe-Mt was 21.13 nm. SEM analysis revealed that Mt NPs were agglomerated on the surface of the MApe biosorbent, with an average Mt diameter of 25.97 nm. After Mt impregnation, a decrease in BET surface area (14.89 to 3.80 m²/g) and an increase in pore diameter (2.25–3.11 nm), pore volume (0.0052–0.01418 cm³/g) and pH point of zero charge (6.4–7.2) was obtained. The presence of Pb(II) ions in solution significantly decreased the uptake of BPB onto both MApe (66.1–43.8%) and MApe-Mt (80.3–59.1%), compared to other competing ions (Zn(II), Cd(II), Ni(II)) in the solution. Isotherm modeling showed that the Freundlich model best fitted the adsorption data (R² > 0.994 and SSE < 0.0013). In addition, maximum monolayer uptake was enhanced from 6.04 to 8.12 mg/g after Mt impregnation. Kinetics were well described by the pseudo-first order and liquid film diffusion models. Thermodynamics revealed a physical, endothermic adsorption of BPB onto the adsorbents, with ΔH^o values of 15.87–16.49 kJ/mol, corroborated by high desorption (over 90%) of BPB from the loaded materials. The viability of the prepared adsorbents was also revealed in its reusability for BPB uptake.     

基于短时傅立叶变换和连续小波变换的先天性心脏病心音比较分析研究

介绍了将短时傅立叶变换(STFT)和连续小波变换(CWT)用于先天性心脏病(房间隔缺损、室间隔缺损、动静导管未闭)心音信号进行时频分析、特征提取的研究.两种方法都能较好的识别先天性心脏病人,总有效率为85%.论文对两种方法的优缺点进行了比较.小波变换比短时傅里叶变换能更有效的识别正常人与病人的心音信号的特征,可分性更好.但是短时傅里叶变换能量范围更集中,动态范围变化也更小一些.     

基于小波变换的数字遥感影像无损压缩编码系统的设计与开发

针对遥感影像的海量数据对其自身应用的影响，指出了研究图像压缩技术的必要性，从实用的角度出发，采用面向对象的技术方法，设计并实现了基于小波变换的数字遥感影像无损压缩编码系统。     

基于小波蚊子的车联网性能评价方法

数据传输可靠性已成为车联网研究的热点问题,首先给出了车辆之间数据传输可靠性的评价方法,并结合小波变换和群蚊子算法对数据评估模型进行求解,同时通过引入分类机制和决策权来引导搜索方向,以此加快算法收敛速度.最后利用仿真实验平台深入研究了影响该算法的关键因素,并讨论了数据包大小、车辆间距、发送功率和车辆速度与数据成功发送率之间的关系.与其他算法比较,该算法显示出较好适应性.     

阿达玛变换在示波计时电位法中的应用

报导了阿达玛变换在示波计时电位法中的应用．在 Ｎａ Ｏ Ｈ－ Ｐｂ２ ＋ 、 Ｋ Ｃｌ－ Ｃｄ２ ＋ 和 Ｌｉ Ｃｌ － Ａｌ３ ＋ 体系中,考察了两种示波计时电位曲线的阿达玛谐波电位同去极剂浓度 Ｃｏ  的关系．实验结果表明：对经典示波计时电位曲线ｄ Ｅ／ｄｔ－ Ｅ,一次谐波 Ｅ１ 随 Ｃｏ  增加而线性下降,二次谐波 Ｅ２ 与 Ｃｏ  成正比;而在示波伏安ｉｆ － Ｅ 曲线中,此规律则相反．这些线性关系可用于定量分析测试．同 Ｆｏｕｒｉｅｒ 变换相比,阿达玛变换具有运算速度快、更加适合于数字信号分析等突出优点     

基于联合变换相关器的像移测量仿真分析

对基于联合变换相关器的像移测量数学原理进行了说明,介绍了面阵CCD的安装位置以及输入图像的获取方法,分析了低信噪比输入图像、相对转动位移对测量精度的影响。应用MATLAB对输入图像进行傅里叶变换得到联合功率谱,对二值化处理的功率谱进行傅里叶变换得到相关输出,用质量中心算法计算出像移量。分析得出,输入图像信噪比大于5dB,测量均方误差小于0.05像素;输入图像相对转动位移在0.1°的范围内,转动位移对测量精度和峰噪比的影响可以忽略不计。综合分析表明像移测量均方误差小于0.05像素。