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1.
《Electroanalysis》2004,16(16):1311-1317
The determination of some toxic metals by stripping chronopotentiometry with a supporting solution having an unconventional composition has been investigated with the aim of using such components in disposable measuring cells preservable in dry state and quite ready for use, only needing addition of a small volume of sample. The new supporting solution is prepared with a solid strong acid, p‐toluenesulfonic acid, in the place of the inorganic acids commonly used to improve the cation availability. The other components are, as usual, sodium chloride, which fixes the potential of the screen‐printed silver – silver chloride reference electrode, and mercury(II) chloride as the plating agent. This supporting solution has been tested in batch measurements with the mercury film glassy carbon electrode as well as with screen‐printed carbon‐ink electrodes, either with mercury film or bare. The physical shape of the mercury layer electrolytically deposited on screen‐printed carbon‐ink electrodes from a supporting solution containing 0.1 M p‐toluenesulfonic acid and 0.1 M sodium chloride has been investigated by scanning electron microscopy (SEM) and energy dispersive spectrometry (EDS) microanalysis. In chronopotentiometric stripping p‐toluenesulfonic acid performs as well as the usual inorganic strong acids, particularly in terms of sensitivity. At 0.1 mol dm?3 it proved very suitable for the determination of toxic metals, in particular lead(II), at levels down to a few μg dm?3. The overall results appear promising and can open new avenues for preparing disposable cells for on‐field stripping chronopotentiometric determination of toxic metals. 相似文献
2.
Sachin B. Pandya Urmila H. Patel Kaushik P. Chaudhary Bhavesh N. Socha Nikita J. Patel Bhupesh S. Bhatt 《应用有机金属化学》2019,33(12)
Novel cobalt complex of 4‐amino‐N‐(6‐chloropyridazin‐3‐yl)benzene sulfonamide (sulfachloropyridazine) has been synthesized and characterized by elemental analysis, FT‐IR spectroscopy and magnetic susceptibility (VSM). Cobalt complex of Sulfachloropyridazine (Co‐SCP) crystallized in monoclinic space group P21/n with Z = 4. The structure is solved by direct method and refined to R = 0.099 for 4720 reflections with I ?4σ(I). The results of FT‐IR spectra suggest the binding of cobalt atom to the sulfonamide ligand which is in agreement with the crystal structure determination. In crystal structure, molecule is linked via, C‐H … π, C‐Cl … π and π … π intermolecular interactions. The computational studies like the optimization energy and root means square deviation compare with single crystal structure, frontier molecular orbital (Homo‐Lumo energy) and binding energy of the Co‐SCP has been carried out using DFT/B3LYP level of theory in gaseous phase. Hirshfeld surfaces and the 2D‐fingerprint analysis are performed to study the nature of interactions and their measurable contributions towards crystal packing. The interaction of the complex with DNA is investigated using viscosity measurement and absorption titration studies. The result shows the complex bind to DNA with intercalative mode with high DNA‐binding constant (Kb). Also, in vivo and in vitro cytotoxic studies are performed using S. pombe cells and brine shrimp lethality bioassay. DNA‐cleavage study shows better cleaving ability of the complex. 相似文献
3.
针对列车通信在越区切换过程中切换触发率和切换成功率均较低的问题, 提出一种基于改进遗传算法的自适应联合判决切换算法. 首先, 以遗传算法为基础, 在高速特性下对切换判决过程中的相关参数进行优化, 针对列车的不同运行速度动态选择出满足快速切换需求的迟滞容限值; 其次, 引入满意通信概率(SCP), 当列车在小区之间移动时, SCP值达不到要求的将不能接入下一个小区, 以保障通信质量的优良. 仿真结果表明, 与传统切换方案相比, 该方案可实现提高切换触发率和切换成功率的目标, 具有较高的满意通信概率. 相似文献
4.
张光辉 《科技情报开发与经济》2006,16(18):123-125
根据SCP范式中市场结构、行为、绩效之间的因果关系,以2005年中国风险投资市场运行数据为基础,分析了我国风险投资产业的现状,并针对政府对风险投资产业的管制,提出了构建我国风险投资产业生态环境的建议,以提高风险投资市场的运行效率。 相似文献
5.
An overview of analytical methodologies for the determination of antibiotics in environmental waters 总被引:3,自引:0,他引:3
The widespread occurrence of antibiotics as contaminants in the aquatic environment has increased attention in the last years. The concern over the release of antibiotics into the environment is related primarily to the potential for the development of antimicrobial resistance among microorganisms. This article presents an overview of analytical methodologies for the determination of quinolone (Qs) and fluoroquinolone (FQs), macrolide (MLs), tetracycline (TCs), sulfonamide (SAs) antibiotics and trimethoprim (TMP) in different environmental waters. The analysis of these antibiotics has usually been carried out by high-performance liquid chromatography (HPLC) coupled to mass spectrometry (MS) or tandem mass spectrometry (MS/MS) and to a lesser extent by ultraviolet (UV) or fluorescence detection (FD). A very important step before LC analysis is sample preparation and extraction leading to elimination of interferences and prevention of matrix effect and preconcentration of target analytes. 相似文献
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7.
研究了在不同队列长度、不同概率p(呼叫时到达间隔时间为0的概率)情况下令牌桶算法的健壮性,提出一种根据数据流速及波动性控制令牌速率的模糊控制算法.仿真结果表明该算法不仅具有简单令牌桶算法的良好健壮性,而且提高了过载数据的处理速度,有效减小了数据丢失,在一定程度上防止了过载引起的网络拥塞,缓解了业务控制点(SCP)的高负荷. 相似文献
8.
Jaime Rodríguez André Ferraz Raquel F. P. Nogueira Irene Ferrer Elisa Esposito Nelson Durán 《Applied biochemistry and biotechnology》1997,62(2-3):233-242
The lignin biodegradation process has an important role in the carbon cycle of the biosphere. The study of this natural process
has developed mainly with the use of basidiomycetes in laboratory investigations. This has been a logical approach since most
of the microorganisms involved in lignocellulosic degradation belong to this class of fungi. However, other microorganisms
such as ascomycetes and also some bacteria, are involved in the lignin decaying process. This work focuses on lignin biodegradation
by a microorganism belonging to the ascomycete class,Chrysonilia sitophila. Lignin peroxidase production and characterization, mechanisms of lignin degradation (lignin model compounds and lignin in
wood matrix) and biosynthesis of veratryl alcohol are outstanding. Applications of C.sitophila for effluent treatment, wood biodegradation and single-cell protein production are also discussed. 相似文献
9.
利用白地霉等酵母菌净化并资源化玉米淀粉工业废水,净化后废水COD值平均为281.4mg/mL,达到了国家污水排放标准;COD去除率为91.0%;pH值平均为7.0;每升废水还生产出干燥的SCP1.646g.同时对玉米淀粉废渣的综合利用进行了探讨。 相似文献
10.
刘春香 《浙江万里学院学报》2008,21(3):83-85
产业集群是提升区域竞争力的重要因素。在早期,产业集群仅仅作为一种企业的空间集聚现象而引起人们的注意。近年来越来越多的理论和实践表明,产业集群不仅仅是一种空间集聚现象,更重要的是,它是产业发展中的一种有效的生产组织方式,能够被用来作为产业发展的战略方式加以利用,进而大大提升特定产业的竞争力。为此,文章运用SCP范式分析了产业集群的竞争优势,为产业集群分析提供了一个新的研究视角。 相似文献