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1.
M.Yu. Tretyakov V.V. Parshin M.A. Koshelev A.P. Shkaev A.F. Krupnov 《Journal of Molecular Spectroscopy》2006,238(1):91-97
Extension of the working frequency of modern resonator spectrometers into submillimeter wave range is described. Experimental record of atmospheric absorption spectrum covering 45-370 GHz range is demonstrated for the first time, and measured water vapor J′ka′, kc′-Jka, kc = 51,5-42,2 at 325 GHz line parameters are presented. For the first time pressure lineshift for the 325-GHz water vapor line is measured. Further extension of working range is discussed. New estimations of physical limits of time needed for measurements of absorption in the whole Backward Wave Oscillator (BWO) range are given for phase continuous synthesizer regime. Basic schemes of fast broadband continuous phase synthesized sources are discussed. Verification of the previous measurements of water vapor 31,3-22,0 at 183 GHz line parameters is presented. Comparisons with ringdown resonator spectrometers are given. 相似文献
2.
田富鹏 《西北民族学院学报》1994,15(1):14-17
介绍了Monte Carlo方法的基础上,分析了以往的文献中发电系统的随机生产模拟分布的不足之处后,提出了发电系统随机生产模拟的韦伯分布法及模拟方法。 相似文献
3.
R. Schuch I. Bergström K. Blaum T. Fritioff Sz. Nagy A. Solders M. Suhonen 《Hyperfine Interactions》2006,173(1-3):73-83
We report here about measurements of reaction and decay Q values by precise determination of pairs of atomic masses. These were performed with the Penning trap mass spectrometer SMILETRAP.
Measurements with Penning traps give reliable and accurate masses, in particular Q values, due to the fact that certain systematic errors to a great deal cancel in the mass difference between the two atoms
defining the Q value. Some Q values that are of fundamental interest will be discussed here, for example, a new Q value for the 6Li (n,γ) 7Li reaction, for the β-decay of tritium, related to properties of the electron neutrino mass, and for the neutrino-less double
β-decay of 76Ge, related to the question of whether the neutrino is a Majorana particle or not. In case of the latter two we report the
most accurate Q values, namely 18,589.8(12) eV for the tritium decay and 2,038.997(46) keV for the neutrino-less double β-decay of 76Ge. 相似文献
4.
CE-MS has evolved into a strong alternative to LC-MS. Most of CE-MS applications deal with characterization and identification. However, quantitative aspects have gained importance in, e.g., pharmaceutical and biotechnological applications. Here we summarize and evaluate various methodological aspects in order to achieve sensitive and reproducible results. Similar to LC-MS, aspects of matrix influence on the electrospray process need to be carefully addressed when quantitative results are intended by CE-MS. Due to a more complicated coupling special emphasis needs to be put on the CE-MS interface. Generally linearity over more than three orders of magnitude can be achieved by CE-ESI-MS. Furthermore, a literature survey has been performed in order to give an overview over quantitative measurements performed by CE-MS. The precision can be doubled when changing from a structural related to an isotopically labeled internal standard. Thus a level of precision better than 5% RSD can be achieved. 相似文献
5.
Mechanical properties decay and morphological behaviour of biodegradable films for agricultural mulching in real scale experiment 总被引:1,自引:0,他引:1
Giacomo Scarascia-Mugnozza Giuliano Vox Barbara Immirzi 《Polymer Degradation and Stability》2006,91(11):2801-2808
The use of plastic materials in agriculture causes the serious drawback of huge quantities of waste. The introduction of biodegradable materials, which can be disposed directly into the soil, can be one possible solution to this problem. Biodegradable materials are actually innovative materials; therefore, their physical properties must be evaluated in relation to their functionality during the use in field. In the present research results of experimental tests carried out on biodegradable films used in strawberries protected cultivation are presented. The decay of some relevant physical parameters of biodegradable films during the cultivation period was monitored by laboratory tests (SEM analysis, mechanical tensile tests and infrared reflectance spectroscopy). Infrared spectroscopy clearly indicated that the mechanical degradation starts from the starch component of the material. Tensile tests showed that the value of elongation at break of biodegradable materials decreased in some cases by 300% after 10 days of field application. 相似文献
6.
7.
光谱添加剂在粉末样品分析中的作用 总被引:1,自引:0,他引:1
通过模拟实验,研究了具有不同作用的4种光谱添加剂对铁矿粉末样品分析的影响。实验结果表明,最佳载体效应和最佳缓冲效应所对应的添加剂质量分数一般不同。 相似文献
8.
高长春 《河北理工学院学报》1993,(4)
国家国土局批准的行业标准《城镇地籍调查规程》(简称《规程》)、国测局批准的局标准《地籍测量规范》(简称《规范》),是当前从事城镇地籍调查可遵循的两个技术标准。对《规程》、《规范》制定的指导思想、精度指标以及实践中如何执行等方面进行了探讨。 相似文献
9.
Peter-Th. Wilrich 《Accreditation and quality assurance》2007,12(5):231-240
Interlaboratory experiments often contain results that strongly deviate from other results obtained in the same laboratory
under repeatability conditions, or laboratory means that strongly deviate from other laboratory means. In ISO 5725-2 [1] and IUPAC [2], the basic standards for the organisation and analysis of interlaboratory experiments for the determination of precision
of a measurement method, outlier tests are performed in order to detect such situations and to finally decide whether these
values are retained in the analysis or discarded as outliers. This outlier treatment, which always has a subjective aspect,
becomes unnecessary by using robust estimates of the repeatability and reproducibility standard deviation. This paper proposes
to use Rousseeuw’s Q
n as an extremely robust and efficient estimate of the standard deviation. Two examples show the performance of the new method. 相似文献
10.
The dispersion of the quantitative results in the analysis of volatile compounds from multicomponent mixtures by different fractionation techniques (solid-phase microextraction and direct thermal desorption) followed by GC or GC-MS presents nonrandom patterns related to the existence of different factors in the fractionation process or in the chromatographic separation which affect, to a different extent, the recovery of the sample components. Statistical techniques have been used to show the relative importance of these factors. The improvement in data precision achieved by using volatile compound concentration ratios is discussed. 相似文献