Functionalization of polyethylene/silane copolymers in posttreatment reactions

7‐Octenyldimethylphenylsilane was copolymerized with ethylene via Et(Ind)₂ZrCl₂ methylaluminoxane catalyst system without loss of catalyst activity or decrease in molar mass. The comonomer contents in the polymer samples were at a level of 0.15–1.0 mol % and the reactive phenylsilane groups were posttreated to different alcoxy‐ and halosilane groups, for example, Si? F, Si? Cl, Si? OCH₃, and Si? OCH₂CH₃. The posttreatment reactions had no major effect on the molar masses or on the thermal properties (measured with differential scanning calorimetry) of the copolymers. The reaction pathways were nearly independent of the comonomer contents and the reactions reached 70–100% conversions. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1461–1467, 2004     

正确认识和理解体育教师的创造性与主体性

树立大体育观、正确理解体育课程、参与学校体育计划的制订和实践学校体育是体育教师创造性和主体性的客观要求和具体体现.学校体育教师应参与到学校体育全过程中去,以全面、正确理解学校体育,并亲自执行使之变为现实.     

师范院校体育教育专业篮球普修课教学改革的思考

通过对师范院校体育教育专业篮球教学目标、教学内容、教学模式、课的结构及对学生的学业成绩评价进行分析和思考 ,提出了当今篮球教学中存在的问题及其解决方法。     

教师的创造性人格及培养模式

创造性的人格特征是教师素质的重要方面,在教师创造活动中起着动力、导向、调节作用.教师的创造性人格特征,一方面为创造型教师的成长提供帮助,另一方面也为教师培养学生的创造精神、创造能力提供重要手段.本文在阐述教师创造性人格的基础上,论述教师创造性人格特征的培养模式,即认知切入、情境陶冶、活动交往、体验反思.     

Kinetic features of ethylene polymerization over supported catalysts [2,6‐bis(imino)pyridyl iron dichloride/magnesium dichloride] with AlR3 as an activator

The effects of polymerization temperature, polymerization time, ethylene and hydrogen concentration, and effect of comonomers (hexene‐1, propylene) on the activity of supported catalyst of composition LFeCl₂/MgCl₂‐Al(i‐Bu)₃ (L = 2,6‐bis[1‐(2,6‐dimethylphenylimino)ethyl] pyridyl) and polymer characteristics (molecular weight (MW), molecular‐weight distribution (MWD), molecular structure) have been studied. Effective activation energy of ethylene polymerization over LFeCl₂/MgCl₂‐Al(i‐Bu)₃ has a value typical of supported Ziegler–Natta catalysts (11.9 kcal/mol). The polymerization reaction is of the first order with respect to monomer at the ethylene concentration >0.2 mol/L. Addition of small amounts of hydrogen (9–17%) significantly increases the activity; however, further increase in hydrogen concentration decreases the activity. The IRS and DSC analysis of PE indicates that catalyst LFeCl₂/MgCl₂‐Al(i‐Bu)₃ has a very low copolymerizing ability toward propylene and hexene‐1. MW and MWD of PE produced over these catalysts depend on the polymerization time, ethylene and hexene‐1 concentration. The activation effect of hydrogen and other kinetic features of ethylene polymerization over supported catalysts based on the Fe (II) complexes are discussed. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 5057–5066, 2007     

试论我国体育产业的品牌战略

体育品牌主要界定于(属于)体育产业及其相关产业范畴。体育企业为使自己的品牌最大限度地赢得市场，以增强赢利能力和长远的生存能力，必须进行一系列的布置规划，即所谓的体育战略，包括体育品牌创建、渗透、维护等。实施体育品牌战略能够加强中国体育品牌的国际竞争能力，促进我国对外贸易的发展，振兴体育品牌。     

信息技术与学科教学的整合需要研究型教师

信息技术与学科的有效整合需要教师具备整合的基本能力，并成为研究型教师。指出教师要不断更新信息技术知识和技能，利用现代教学设施，依据教学实践开展研究，从而探索出有效的整合模式。     

体育专业函授生自学能力培养浅议

首先分析了体育专业函授生的一般特点，并提出了构成体育专业函授生自学能力结构的四大要素，然后着重阐述了体育专业函授生自学能力培养的四项基本措施．     

面向21世纪浙江省高等师范教育的走向

在我国高等师范教育进行着诸多改革的背景下 ,分析浙江省高等师范教育现状及面临的问题 ,探讨其改革发展的走向 ,提出了一系列的办学模式和发展思路。     

中小学教师教育技术能力培训中的绩效评价指标体系

中小学教师教育技术能力培训评价是中小学教师教育技术能力培训活动的构成部分之一。本文将绩效评价的特点引入到教师教育技术培训评价中，结合《中小学教师教育技术能力标准（试行）》，制定了培训绩效评价指标体系，给参与中小学教师教育技术能力培训活动的相关人员提供参考。