Online Fourier-transform near infrared (FT-NIR) spectroscopy in combination with a fiber optic probe was utilized to study the kinetics of the anionic polymerization of butadiene. The conversion of the butadiene to methylene protons in the polymer was monitored in solution polymerization conditions by monitoring the absorbance at 1632 nm. The off-line gel permeation chromatography, GPC, technique was used to validate the online FT-NIR spectroscopy method. Butadiene polymerization kinetics in cyclohexane initiated with n-butyllithium at different initiator concentrations and temperatures was studied. A phenomenological kinetic expression for the anionic polymerization of butadiene in cyclohexane initiated with n-butyllithium was determined. The predictions of the kinetic expression were in agreement with kinetic data reported in the literature. 相似文献
We consider the problem faced by an online service platform that matches suppliers with consumers. Unlike traditional matching models, which treat them as passive participants, we allow both sides of the market to exercise their choices. To model this setting, we introduce a two-sided assortment optimization model wherein each participant's choice is modeled using a multinomial logit choice function, and the platform's objective is to maximize its expected revenue. We first show that the problem is NP-hard even when the number of suppliers is limited to two and provide a mixed-integer linear programming formulation. Next, we discuss two simple greedy heuristics and argue that these can lead to arbitrarily bad solutions. We then develop relaxations that provide upper and lower bounds and investigate the tightness of these relaxations by obtaining parametric approximation guarantees. Finally, we present numerical results on synthetic data demonstrating the practical utility of these relaxations. 相似文献
Massey University is a world-leading university in remote-instruction, online and mixed teaching based on the Stream teaching platform. This paper analyzed the advantages of the Stream teaching platform, resource utilization, course format, teaching team cooperation and course evaluation in Massey University. The paper also analyzed the enlightenment of teaching experience of Massey University to undergraduate teaching. During the outbreak of COVID-19 epidemic, drawing on Massey's experience, combined with the rapid development of information technology in China, the teaching team of organic chemistry adopted the multi-teaching strategy of "teacher-centered and student-centered", and the teaching mode of "teacher-led and self-taught by students". The online teaching practice of organic chemistry was carried out in agriculture university. It has been demonstrated that this model can effectively improve teaching effects. 相似文献
The use of recorded lecture videos (RLVs) in mathematics instruction continues to advance. Prior research at the post-secondary level has indicated a tendency for RLV use in mathematics to be negatively correlated with academic performance, although it is unclear whether this is because regular users are generally weaker mathematics students or because RLV use is somehow depressing student learning. Through the lens of cognitive engagement, a quasi-experimental pre- and post-test design study was conducted to investigate the latter possibility.
Cognitive engagement was operationalized using the Revised Two-Factor Study Process Questionnaire (R-SPQ-2F), which measures learning approaches on two major scales: surface and deep. In two mathematics courses at two universities, in Australia and the UK, participants were administered the questionnaire near the course start and finish. Overall findings were similar in both contexts: a reduction in live lecture attendance coupled with a dependence on RLVs was associated with an increase in surface approaches to learning.
This study has important implications for future pedagogical development and adds to the sense of urgency regarding research into best practices using RLVs in mathematics. 相似文献
The first example of application of nanosized polystyrene-based cation exchanger (NSCE) with sulfo groups as a dynamic coating of capillary walls was demonstrated. The conditions of dynamic coating formation were optimized and ensured the long-term stability of the coating. Capillary-to-capillary and day-to-day repeatabilities were 4% and 3%, correspondingly. The NSCE coating stability at various pH and influence of pH on the EOF mobility were investigated. The developed NSCE-modified coated capillaries provided improved resolution (Rs = 0.9–3.2 for catecholamines and Rs = 1.7–2.8 for amino acids) and efficiencies (330–520 ×103 t.p./m) of basic analytes, which are 1.5 times higher compared to untreated capillary. The optimized conditions were as follows: 50 mM phosphate buffer solution at pH 2.2 with 5 μM NSCE. The effect of the NSCE concentration in BGE on the electrophoretic mobilities of the analytes was investigated. The various online concentration techniques were tested in order to decrease the LODs. The simultaneous application of NSCE capillaries and field-amplified sample stacking provided the lowest LODs of catecholamines and amino acids and allowed to determine these analytes in human urine. 相似文献