全文获取类型
收费全文 | 182篇 |
免费 | 11篇 |
国内免费 | 12篇 |
专业分类
化学 | 49篇 |
力学 | 1篇 |
综合类 | 4篇 |
数学 | 51篇 |
物理学 | 8篇 |
综合类 | 92篇 |
出版年
2023年 | 1篇 |
2022年 | 4篇 |
2021年 | 1篇 |
2020年 | 4篇 |
2019年 | 3篇 |
2018年 | 2篇 |
2017年 | 5篇 |
2016年 | 2篇 |
2015年 | 6篇 |
2014年 | 7篇 |
2013年 | 11篇 |
2012年 | 6篇 |
2011年 | 11篇 |
2010年 | 8篇 |
2009年 | 7篇 |
2008年 | 7篇 |
2007年 | 10篇 |
2006年 | 7篇 |
2005年 | 11篇 |
2004年 | 9篇 |
2003年 | 14篇 |
2002年 | 13篇 |
2001年 | 13篇 |
2000年 | 8篇 |
1999年 | 6篇 |
1998年 | 9篇 |
1997年 | 8篇 |
1996年 | 2篇 |
1995年 | 3篇 |
1994年 | 2篇 |
1991年 | 2篇 |
1988年 | 1篇 |
1986年 | 1篇 |
1984年 | 1篇 |
排序方式: 共有205条查询结果,搜索用时 0 毫秒
1.
采用NP催化剂的芥酸氢化制备山嵛酸工艺研究 总被引:5,自引:1,他引:4
秦振平 《延安大学学报(自然科学版)》1998,17(1):49-53
本文制备了高效加氢NP催化剂,并讨论了芥酸采用该催化剂加氢制备山嵛酸时,催化剂浓度、氢气压力、反应温度、搅拌速度等因素对反应的影响。试验结果表明其适宜的工艺条件为:催化剂浓度0.6%,氢气压力8.11×105Pa,反应温度413K,脉冲式搅拌速度80次/min。 相似文献
2.
Exact rotamer optimization for protein design 总被引:1,自引:0,他引:1
Computational methods play a central role in the rational design of novel proteins. The present work describes a new hybrid exact rotamer optimization (HERO) method that builds on previous dead-end elimination algorithms to yield dramatic performance enhancements. Measured on experimentally validated physical models, these improvements make it possible to perform previously intractable designs of entire protein core, surface, or boundary regions. Computational demonstrations include a full core design of the variable domains of the light and heavy chains of catalytic antibody 48G7 FAB with 74 residues and 10(128) conformations, a full core/boundary design of the beta1 domain of protein G with 25 residues and 10(53) conformations, and a full surface design of the beta1 domain of protein G with 27 residues and 10(60) conformations. In addition, a full sequence design of the beta1 domain of protein G is used to demonstrate the strong dependence of algorithm performance on the exact form of the potential function and the fidelity of the rotamer library. These results emphasize that search algorithm performance for protein design can only be meaningfully evaluated on physical models that have been subjected to experimental scrutiny. The new algorithm greatly facilitates ongoing efforts to engineer increasingly complex protein features. 相似文献
3.
Summary The highly complex matrix of diesel particulate extracts was analyzed for nitrated polycyclic aromatic hydrocarbons (nitro-PAH)
using fused-silica capillary-column gas chromatography along with a thermionic nitrogen-phosphorus detector (TID) and high-performance
liquid chromatography followed by on-line catalytic reduction of the nitro-PAH to amino-PAH and subsequent fluorescence detection.
Positive isomer identification and quantitation of nitro-PAH are from retention times of authentic standards and their mass
spectra. The ease of nitro-PAH formation by nitration of PAH raises the question regarding the origin of these species, whether
they are produced as “native” products during the engine combustion process and/or in the exhaust, or instead, formed as the
result of chemical conversion to produce artifacts during the sampling procedure. This problem is assessed examing 1-nitropyrene-concentration
in particulates of three light-duty diesel engines for different sampling times. 1-Nitropyrene concentrations show only a
moderate increase with sampling time under average sampling conditions.
Presented at the 15th International Symposium on Chromatography, Nürnberg, October 1984 相似文献
4.
《Arabian Journal of Chemistry》2020,13(1):1198-1228
Vanadate and vanadium compounds exist in many environmental, biological and clinical matrices, and despite the need only limited progress has been made on the analysis of vanadium compounds. The vanadium coordination chemistry of different oxidation states is known, and the result of the characterization and speciation analysis depends on the subsequent chemistry and the methods of analysis. Many studies have used a range of methods for the characterization and determination of metal ions in a variety of materials. One successful technique is high performance liquid chromatography (HPLC) that has been used mainly for measuring total vanadium level and metal speciation. Some cases have been reported where complexes of different oxidation states of vanadium have been separated by HPLC. Specifically reversed phase (RP) HPLC has frequently been used for the measurement of vanadium. Other HPLC methods such as normal phase, anion-exchange, cation-exchange, size exclusion and other RP-HPLC modes such as, ion-pair and micellar have been used to separate selected vanadium compounds. We will present a review that summarizes and critically analyzes the reported methods for analysis of vanadium salts and vanadium compounds in different sample matrices. We will compare various HPLC methods and modes including sample preparation, chelating reagents, mobile phase and detection methods. The comparison will allow us to identify the best analytical HPLC method and mode for measuring vanadium levels and what information such methods provide with regard to speciation and quantitation of the vanadium compounds. 相似文献
5.
《Physics letters. A》2019,383(19):2290-2295
Cooling rate is critical in synthesizing nanoparticles (NPs), which determines the microstructure and the corresponding mechanical, thermal and electrical properties. This research, as the most initiative one, studies microstructure formation of three different sized high entropy alloy (HEA) NPs under three different cooling rates, employing molecular dynamics (MD). Through analysis of potential energy, “common neighbor analysis”, radial distribution function, and also the mean square displacement, it is found that phase transition temperature is independent of HEA NP size, and as cooling rate decrease, more amorphous atoms transform to fcc and hcp orders, which can alternate the mechanical and thermodynamic properties of the final structure. The Cr atoms are found to aggregate into one cluster inside the NP and also try to migrate to the surface of the HEA NP, due to the large diffusivity. This research provides new insights in the size dependency of the nanoparticles, which may motivate more applications in which the strong size dependency is not desirable. 相似文献
6.
In this study, nanocrystalline cellulose (NCC) prepared from microcrystalline cellulose using high‐intensity ultrasonication as mechanical method without any chemical treatment. The obtained NCC with around 30–50 nm diameters, utilized as support, reducing and stabilizing agent for in‐situ green and eco‐friendly synthesis of silver nanoparticles (Ag NPs). The catalytic activity of composite was examined for degradation of environmental pollutants. The structure of as‐synthesized composite (Ag@NCC) was characterized by ultraviolet–visible spectroscopy (UV–vis), field emission scanning electron microscopy (FE‐SEM); Transmission electron microscopy (TEM); Energy dispersive spectroscopy (EDS), Fourier transform infrared spectroscopy (FT‐IR), X‐ray diffraction (XRD) and thermogravimetric analysis (TGA). The results of the catalytic reaction experiments showed that spherically shaped silver nanoparticles of around 20 nm distributed on the surface of nanocellulose demonstrated high catalytic efficiency towards the removal of methyl orange (MO) and 4‐nitrophenol (4‐NP). 相似文献
7.
Miho Kusakari Yurie OhtaHideaki Nakagawa Hiroshi KatagiriTatsuro Kijima Satoshi MurakamiShigeru Matsuba Bunpei Hatano 《Tetrahedron letters》2014
An enantioresolution of 2-methoxy-2-(1-naphtyl)propionic acid (MαNP acid) using the diastereomeric salt with chiral (R)-phenylethylamine was achieved to give enantiopure (R)-MαNP acid in 29% yield with >99% ee based on rac-MαNP acid. X-ray crystallographic analysis of diastereomeric salt revealed that (R)-MαNP acid was tightly arranged by four independent hydrogen bonds and one CH–π interaction with (R)-phenylethylamine. 相似文献
8.
蚁群优化算法的原理及其应用 总被引:1,自引:0,他引:1
陈昊 《湖北大学学报(自然科学版)》2006,28(4):350-352
蚁群优化算法是近年来出现的一种新的启发式搜索算法,首先介绍了蚁群算法的基本原理,然后着重讨论了如何将其用于求解旅行商问题(TSP),最后分析了蚁群算法的一些基本特征. 相似文献
9.
The knowledge of hydrocarbon/water phase equilibria is important in the design and operation of equipment for petroleum transport and refining and petrochemical plants. The presence of water in a hydrocarbon mixture can affect the product quality and damage the operation equipment due to corrosion and formation of gas hydrates. Tracing the concentration of hydrocarbons in aqueous media is also important for technical purposes like preventing oil spills and for ecological concerns such as predicting the fate of these organic pollutants in the environment. 相似文献
10.
In this work we compute the thermodynamic properties of the 3-satisfiability problem in the infinite connectivity limit. In this limit the computation can be strongly simplified and the thermodynamic properties can be obtained with a high accuracy. We find evidence for a continuous replica symmetry breaking in the region of high number of clauses, >c. 相似文献