Linear and Nonlinear Optical Properties of Novel Multi-branched Oligomers

We investigate the fluorene-vinylene unit dependent photo-physical properties of multi-branched truxene based oligomers (Tr-OFV_n, n=1-4) employing steady-state absorption and emission spectroscopy, transient absorption spectroscopy, two-photon fluorescence, and z-scan technique. The results show that the increasing of fluorene-vinylene unit leads to a red-shift in the spectra of absorption and fluorescence, and shortens the excited state lifetime. Meanwhile, two-photon fluorescence efficiency and two-photon absorption cross section of truxene based oligomers gradually enhance in company with the extension of π-conjugated length. In addition, the values of two-photon absorption cross section modeled on the sum-over-state approach agree well with the experimental ones. The results indicate multi-branched truxene based oligomers bearing oligo(fluorene-vinylene) arms are promisingorganic materials for two-photon applications.     

大型水电机组匝间短路保护动作性能分析

随着我国水力发电的大规模发展,水电机组的单机容量越来越大,对大容量水电机组配置有效的主保护方案对机组和系统稳定运行具有重要意义。大容量水轮发电机定予绕组采用多分支结构,其内部故障数量巨大,根据以往的保护设计经验,相间故障一般由纵差保护灵敏反应,本文分析了三峡右岸哈电机组的绕组结构和内部故障形式,利用暂态仿真结果对匝间保护动作性能进行分析,给出了匝间保护配置建议。     

煤层气多分支水平井钻井技术研究

煤层气多分支水平井钻井技术的应用极大地促进了煤层气的开发,是煤层气开发的主要工艺之一。本文简要分析了煤层气多分支水平井的增产机理和基本模式,并剖析了该工艺中井位优选,井眼轨迹控制,钻井液设计等重要环节的技术要点。     

星型低聚物线性和非线性光学性质

利用稳态吸收和发射光谱、瞬态吸收光谱、双光子荧光和z扫描技术,系统地研究了一系列星型芴乙烯撑三聚茚低聚物(Tr-OFV_n,n=1～4)的光物理性质. 结果显示,芴乙烯撑单元的增加会导致吸收光谱和荧光谱的带边发生红移,同时也缩短了激发态物种的寿命. 伴随着π共轭长度的增加,三聚茚低聚物的双光子荧光效率和双光子吸收截面也逐渐增强. 基于态求和方法数值模拟了材料的双光子吸收截面,同实验值吻合较好.