全文获取类型
收费全文 | 2367篇 |
免费 | 37篇 |
国内免费 | 342篇 |
专业分类
化学 | 1134篇 |
晶体学 | 30篇 |
力学 | 239篇 |
综合类 | 2篇 |
数学 | 33篇 |
物理学 | 700篇 |
综合类 | 608篇 |
出版年
2024年 | 11篇 |
2023年 | 42篇 |
2022年 | 74篇 |
2021年 | 69篇 |
2020年 | 108篇 |
2019年 | 51篇 |
2018年 | 47篇 |
2017年 | 115篇 |
2016年 | 121篇 |
2015年 | 100篇 |
2014年 | 116篇 |
2013年 | 154篇 |
2012年 | 115篇 |
2011年 | 192篇 |
2010年 | 157篇 |
2009年 | 166篇 |
2008年 | 136篇 |
2007年 | 161篇 |
2006年 | 124篇 |
2005年 | 72篇 |
2004年 | 66篇 |
2003年 | 64篇 |
2002年 | 71篇 |
2001年 | 43篇 |
2000年 | 27篇 |
1999年 | 47篇 |
1998年 | 50篇 |
1997年 | 25篇 |
1996年 | 22篇 |
1995年 | 25篇 |
1994年 | 22篇 |
1993年 | 31篇 |
1992年 | 17篇 |
1991年 | 20篇 |
1990年 | 12篇 |
1989年 | 23篇 |
1988年 | 14篇 |
1987年 | 13篇 |
1986年 | 9篇 |
1985年 | 6篇 |
1984年 | 4篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1978年 | 1篇 |
1973年 | 1篇 |
排序方式: 共有2746条查询结果,搜索用时 20 毫秒
1.
In the pursuit to enlarge the library of polyimide materials for energy applications, new polyimide/MWCNTs composite films have been developed by MWCNTs-assisted polycondensation reaction of a hydroxyl and triphenylmethane-containing diamine with benzophenone tetracarboxylic dianhydride targeting to highlight their electrical storage capability as flexible electrodes in micro-supercapacitors (mSCs). The Fourier-transform infrared spectroscopy, proton nuclear magnetic resonance, UV–vis, fluorescence, and Raman spectroscopies were used to demonstrate the evolution of interfacial interactions between MWCNTs and the precursors (diamine monomer and intermediate polyamidic acid) and polyimide matrix that proved to be the origin of MWCNTs homogeneous dispersion. Thus, composite films incorporating 1, 3, 5, and 10 w.t.% MWCNTs were obtained and thoroughly investigated with regard to their morphology, mechanical behavior, thermal stability, and electrical conductivity. The electrochemical performance of these composites was first analyzed in a classical three-electrode cell by cyclic voltammetry and galvanostatic charge-discharge in both aqueous and organic electrolyte systems. By far, the best electrical storage capacity was obtained with the composite polyimide film containing 10% MWCNTs that was further used as both active material and current collector in a flexible symmetric mSC realized by a straightforward and low-cost procedure. In the attempt to better exploit the advantages of this composite film, it was layered with a graphite-containing paint and tested as an electrode in a flexible mSC, which provided satisfactory results. To our knowledge, this is the first report on the electrical charge storage capability of a polyimide/MWCNTs free-standing film as a flexible electrode in mSCs, which do not require time- and resource-consuming processing steps. 相似文献
2.
Luca Cimbaro 《哲学杂志》2019,99(12):1499-1514
A unified theory captures both brittle and ductile fracture. The fracture toughness is proportional to the applied stress squared and the length of the crack. For purely brittle solids, this criterion is equivalent to Griffith's theory. In other cases, it provides a theoretical basis for the Irwin-Orowan formula. For purely ductile solids, the theory makes direct contact with the Bilby-Cottrell-Swinden model. The toughness is highest in ductile materials because the shielding dislocations in the plastic zone provide additional resistance to crack growth. This resistance is the force opposing dislocation motion, and the Peach-Koehler force overcomes it. A dislocation-free zone separates the plastic zone from and the tip of the crack. The dislocation-free zone is finite because molecular forces responsible for the cohesion of the surfaces near the crack tip are not negligible. At the point of crack growth, the length of the dislocation-free zone is constant and the shielding dislocations advance in concert. As in Griffith's theory, the crack is in unstable equilibrium. The theory shows that a dimensionless variable controls the elastoplastic behaviour. A relationship for the size of the dislocation-free zone is derived in terms of the macroscopic and microscopic parameters that govern the fracture. 相似文献
3.
《自然科学进展(英文版)》2019,29(2):217-223
In view of the special requirements for strength, heat resistance and corrosion resistance of Al-Zn-Mg-Cu alloy for oil drilling, the Al-6.2 Zn-2.5 Mg-1.6 Cu alloy was prepared by increasing Cu content on basis of Russian Series 1953 alloy. The effect of heat treatment on the microstructures and properties of the alloy was characterized by optical microscope(OM), scanning electron microscope(SEM) and transmission electron microscope(TEM), and investigated by tensile test at room temperature, thermal exposure test and corrosion test. The results show that the strength after T6 aging treatment exhibit a decrease trend as an increase of the solution temperature from465 °C to 480 °C. After the solution treated by the rate of 470 °C/1 h, second phases dissolve into the matrix very well and the strength property reaches optimum. The alloy has better comprehensive properties treated by a solution treatment of 470 °C/1 h and then followed by an aging treatment of 120 °C/24 h + 170 °C/1 h + 120 °C/24 h. Under the aging state, the precipitated phases inside the grains are suitable in size, while on the grain boundary distribute discontinuously and the precipitate-free zone is obvious. Besides, the alloy still maintain high tensile properties. The yield strength, tensile strength and elongation are 650 MPa, 686 MPa,12.0%, respectively. The yield strength retention after heat exposure is 92%. The alloy has good corrosion resistance and the exfoliation corrosion degree. The average corrosion rate in the H_2S and CO_2 environment is 0.0024 mm/a, which is far less than the required 0.12 mm/a. It is insensitive to H_2S and CO_2 environments. 相似文献
4.
在分析微型热管的功能、技术要求及其加工工艺的基础上,设计了微型热管犁削-拔拉用成型刀具和系列模具.该刀具可使定位装夹方便,加工的热管直径尺寸稳定;模具保证了热管的外径尺寸并可方便地根据要求改变外径尺寸,热管外表面质量好,内部具有更加优良的毛细结构.刀具采用高速钢,模具采用45钢. 相似文献
5.
S. Mancini D. Vitali V. Giovannetti P. Tombesi 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,22(3):417-422
We show that the optomechanical coupling between an optical cavity mode and two movable cavity mirrors is able to entangle
two different macroscopic oscillation modes of the mirrors. This continuous variable entanglement is maintained by the light
bouncing between the mirrors and is robust against thermal noise. In fact, it could be experimentally demonstrated using present
technology.
Received 2 September 2002 / Received in final form 10 October 2002 Published online 7 January 2003 相似文献
6.
R. Martínez-Snchez J. A. Matutes-Aquino O. Ayala-Valenzuela S. D. De la Torre 《Physica B: Condensed Matter》2002,320(1-4):285-287
An amorphous phase containing traces of non-transformed Co and Ti powders was obtained by mechanical alloying nominal compositions of Co67Ti33 and Co50Ti50 in a high-energy ball-mill. These alloys were prepared from elemental powders of Co and Ti. The heat treatment of Co67Ti33 at 573, 873 and 1173 K crystallized nanoparticles of Co2Ti and Co3Ti compounds, while the same treatments conducted on Co50Ti50 resulted in the formation of Co2Ti and CoTi nanoparticles. The saturation magnetizations reached a maximum value in the amorphous state and they decreased when the temperatures of the heat treatment rose. Demagnetizing interparticle interaction effects were estimated through hysteresis loops and initial magnetization curves using the Fourier technique. 相似文献
7.
Karla J. Moreno Miroslaw Maczka Ulises Amador 《Journal of solid state chemistry》2006,179(12):3805-3813
The structural and microstructural characteristics of metastable Gd2(Ti1−yZry)2O7 powders prepared by mechanical milling have been studied by a combination of XRD and Raman spectroscopy. Irrespective of their Zr content, as-prepared powder phases present an anion-deficient fluorite-type of structure as opposed to the pyrochlore equilibrium configuration obtained for the same solid solution by other synthetic routes. These fluorites are stable versus thermal activation, at least up to temperatures of 800 °C. For the Ti-rich compositions, thermal treatments at higher temperatures facilitate the rearrangement of the cation and anion substructures and the relaxation of mechanochemically induced defects whereas for compositions with high Zr content, the fluorite crystal structure is retained even at temperatures as high as 1200 °C. Interestingly enough, transient pyrochlores showing a very unusual cation distribution were observed during the thermally induced defect-recovery process. 相似文献
8.
A. Vukics H. Ritsch 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2007,44(3):585-599
We present a framework for efficiently performing Monte Carlo
wave-function simulations in cavity QED with moving particles. It
relies heavily on the object-oriented programming paradigm as realised
in C++, and is extensible and applicable for simulating open
interacting qua
ntum dynamics in general. The user is provided with a
number of “elements”, e.g. pumped moving particles, pumped lossy
cavity modes, and various interactions to compose complex interacting
systems, which contain several particles moving in electromagnetic
fields of various configurations, and perform wave-function
simulations on such systems. A number of tools are provided to
facilitate the implementation of new elements. 相似文献
9.
10.
Yunshan Dong 《Applied Surface Science》2006,252(14):5057-5062
A series of Zr-Si-N composite films with different Si contents were synthesized in an Ar and N2 mixture atmosphere by the bi-target reactive magnetron sputtering method. These films’ composition, microstructure and mechanical properties were characterized by energy dispersive spectroscopy, X-ray diffraction, scanning electron microscopy, atomic force microscopy and nanoindentation. Experimental results revealed that after the addition of silicon, Si3N4 interfacial phase formed on the surface of ZrN grains and prevented them from growing up. Zr-Si-N composite films were strengthened at low Si content with the hardness and elastic modulus reaching their maximum values of 29.8 and 352 GPa at 6.2 at% Si, respectively. With a further increase of Si content, the crystalline Zr-Si-N films gradually transformed into amorphous, accompanied with a remarkable fall of films’ mechanical properties. This limited enhancement of mechanical properties in the Zr-Si-N films may be due to the low wettability of Si3N4 on the surface of ZrN grains. 相似文献