Simultaneous determination of cinnamaldehyde and its metabolite in rat tissues by gas chromatography–mass spectrometry

Cinnamaldehyde (CA), an active ingredient isolated from the traditional Chinese medicine Cortex Cinnamomi, has a wide range of bioactivities. To clarify the distribution characteristics of CA, a selective and sensitive method utilizing gas chromatography–mass spetrometry was initially developed for simultaneously determining the concentration of CA and its metabolite cinnamyl alcohol in rat tissues. Selected ion masses of m/z 131, 105 and 92 were chosen, and separation of the analytes was performed on a DB‐5 ms (30 m × 0.25 mm, 0.25 µm, thickness) capillary column by gas chromatography–mass spectrometry. The calibration curves demonstrated good linearity and reproducibility over the range of 20–2000 and 20–4000 ng/mL for various tissue samples. Recoveries ranged from 86.8 to 107.5%, while intra‐ and interday relative standard deviations were all <11.3%. The analysis method was successfully applied in tissue distribution studies for CA and cinnamyl alcohol. As CA and cinnamyl alcohol may inter‐convert to one another, simultaneous determination of both analytes provides a comparative and accurate data for tissue study. The concentrations of CA and cinnamyl alcohol remaining in spleen were the highest among the main organs, including heart, liver, spleen, lung, kidney and brain. In addition, there was no long‐term accumulation of CA in rat tissues. Copyright © 2014 John Wiley & Sons, Ltd.     

3维Maxwell方程局部1维多辛格式的能量恒等式

在理想导体边界条件下,对3维Maxwell方程的局部1维多辛Preissman格式的能量守恒性质进行研究.运用能量分析法推导了2个能量恒等式,这些恒等式说明了给出的格式在所定义的离散范数下是能量守恒和无条件稳定的,数值算例验证了结论的正确性.     

基于一维数据逐段均匀条件下的参考分布研究

聚类分析中一个重要的问题是估计聚类数,GS方法通过参考分布对聚类数进行合理的估计,解决了其他聚类方法无法对应分为一类的数据进行分类的问题,具有更好的分类效果;目前已通过理论证明得出,在分布为对数凹且一维情况下,GS方法的参考分布为均匀分布,而有关其在其他条件下的参考分布研究较少;针对这一情况,提出解决一维且逐段均匀条件下GS方法的参考分布问题,以类内平方和为评价标准,通过拉格朗日乘数法求解与问题等价的优化问题,理论证出条件下总体均匀分布是类内平方和最大的情况,进而得出对于一维数据,逐段均匀条件下的参考分布仍为均匀分布的结论。     

斜入射时Salisbury屏电磁参数匹配规律研究

利用电磁波传输理论,研究并推导出了电磁波斜入射时Salisbury屏后向反射率公式,使用三维网格法讨论了各个电磁参数、隔离层厚度、入射波频率等同后向反射率之间的关系.研究结果表明:在2～18GHz范围内,角度后向反射率有很大;在f=16GHz时,μ_(r1)和μ_(r2)取值的增加使得材料的磁损耗和储能能力加强,导致材料有很好的吸收效果;然而ε_(r1)和ε_(r2)取值增加时,由于表面反射效应增强,使得吸波效果下降;在2～18GHz频段内后向反射率均可达到4.5dB以上,能够满足军事和民用的要求.     

Lithium Insertion Mechanism in Iron-Based Oxyfluorides with Anionic Vacancies Probed by PDF Analysis

The mechanism of lithium insertion that occurs in an iron oxyfluoride sample with a hexagonal–tungsten–bronze (HTB)-type structure was investigated by the pair distribution function. This study reveals that upon lithiation, the HTB framework collapses to yield disordered rutile and rock salt phases followed by a conversion reaction of the fluoride phase toward lithium fluoride and nanometer-sized metallic iron. The occurrence of anionic vacancies in the pristine framework was shown to strongly impact the electrochemical activity, that is, the reversible capacity scales with the content of anionic vacancies. Similar to FeOF-type electrodes, upon de-lithiation, a disordered rutile phase forms, showing that the anionic chemistry dictates the atomic arrangement of the re-oxidized phase. Finally, it was shown that the nanoscaling and structural rearrangement induced by the conversion reaction allow the in situ formation of new electrode materials with enhanced electrochemical properties.     

基于DIS数字信息化系统对透光物质透光性能的研究

采用DIS数字信息化系统,对不同浓度的蓝墨水溶液在激光光源照射下的透射平均照度及照度分布图像进行实验研究,得到了平均照度值随溶液浓度变化的规律。对不同颜色塑料膜片对白炽灯光源透过照度值及照度分布图像进行实验研究得到及其相关之规律。     

雷电波分析与比较研究

本文对双指数雷电流模型和 IEC1 3 1 2—— 1推荐的雷电流模型进行了分析和研究 ,计算了这两种雷电流模型的雷电流参数。在此基础上 ,用 FFT方法分析了雷电流的频谱分布     

用DDM实现分布式三维虚拟环境

介绍了HLA中数据分发管理(DDM)的过滤原理;研究分析了目前几种实现DDM过滤机制的方法及其存在的问题,并提出一种简单易行的DDM实现策略,以实现三维虚拟环境的分布式,来提高它的响应速度.     

环境法的需求与供给——一个法经济学视角

环境法是环境与资源要素相对价格提高、科技发展、人们对良好环境形成偏好条件下的产物。它的供给要受到所在国家利益格局、社会科学知识的积累、法律供给传统等诸要素的影响。在完善一个国家的环境法时，必须充分调动这些因素，以形成可持续发展。     

执政信任问题初探

执政信任的形成、实现、巩固和增强,需要执政者追求并实现公正合理的执政理念,树立良好卓著的执政形象,特别需要执政者公正、为民、清廉、诚信;同时还需要执政者建立与健全民主制度,实行法治。执政信任是社会团结的重要道德基石,是执政者的政治灵魂和政治生命,对于政治文明建设具有十分重要的意义。