MBAMT,a new locating and chelating agen in TLC and ring colorimetric determination of Cu(II), Co(II), Ni(II), Pd(II), Pt(IV), and Rh(III)

Summary Synthesis of MBAMT (3-methyl-4-benzylideneamino-5-mercapto-1,2,4-triazole) and its IR and NMR spectral data are reported. The high stability of the characteristically coloured chelates with Cu(II), Co(II), Ni(II), Pd(II), Pt(IV) and Rh(III) has been made the basis for their efficient ascending TLC separations on silica gel G layers, when present together. Results of four different solvent systems are included to assess efficient resolution of the chelates along with their limits of identification and separation. TLC separations, followed by the ring colorimetric determination of the six metal ions (as ternary mixtures) are tabulated.MBAMT=3-methyl-4-benzylideneamino-5-mercapto-1,2,4-triazole.     

Finding transition states using reduced potential-energy surfaces

 We propose a method to locate saddle points that is based on the interplay between the driving coordinate and the restricted quasi-Newton algorithm. The method locates the transition state using a reduced potential-energy surface. The reduced potential-energy surface is characterized by the set of driving coordinates. The proposed algorithm starts at a point on the surface that is slightly perturbed from either reactant or product and, in principle, converges to the transition state. Finally we give a special type of update Hessian matrix formula that should be applied in optimizations carried out on reduced potential-energy surfaces. Received: 29 September 2000 / Accepted: 3 January 2001 / Published online: 3 April 2001     

MHNAMT,a new locating and chelating agent in thin-layer chromatographic determination of Cu(II), Co(II), Ni(II), Pd(II), Pt(IV), and Rh(III)

Summary Synthesis of MHNAMT [3-methyl-4-(2-hydroxy-1 naphthalideneamino)-5-mercapto-1,2,4-triazole] and its IR and NMR spectral data are reported. The high stability of the characteristically coloured chelates with Cu(II), Co(II), Ni(II), Pd(II), Pt(IV) and Rh(III) has been made the basis for their efficient ascending TLC separations on silica gel G layers, when present together. Results of three different solvent systems are included to assess efficient resolution of the chelates.     

选择定位基准提高机械加工精度的方法

定位基准选择正确与否,对于提高机械加工精度有着重要影响。本文着重探讨工件的定位方法、定位形式和定位基准的选择。     

视觉动态目标识别研究进展

近年来,基于计算机视觉的动态目标识别的研究和应用逐渐成为热点问题,通过介绍国内外基于计算机视觉的动态目标检测、确认、定位等领域的研究进展,展望目标识别的发展趋势.首先介绍目标识别过程中的典型方法,然后对基于计算机视觉的动态目标识别算法进行分类,接着对各种方法中采用的不同算法技术进行阐述,并分别介绍了各类别中具有代表性的算法及其优缺点,最后就动态目标识别领域的研究难点及发展趋势进行了简要论述.     

Sagnac/Mach-Zehnder分布式光纤传感系统探测及定位理论分析

利用3×3耦合器解调算法实现对光纤沿线破坏行为的探测及预警.在确定破坏行为发生的基础上,通过将光源切换为窄带光源,使Mach-Zehnder干涉系统工作.利用互相关方法实现对破坏行为的精确定位.详细介绍并分析了该方法的系统光路和探测定位原理.     

基于变权法多因素Fuzzy决策理论的客运专线车站选址

论文在当前我国大力发展高速铁路客运专线的背景下,运用多因素模糊决策理论中的变权分析理论对客运专线车站选址问题进行了分析,并通过算例分析,证明了该评判方法的可行性。     

十三陵抽水蓄能电站地下厂房位置的选择

十三陵抽水蓄能电站是以地下厂房为中心的大型水电工程。厂房位置的选取不论是在施工条件上,还是经济造价上,都是该工程最重要的问题之一。本文从厂房选取控制性因素厂区断裂特征的分析入手,依据各种物理力学指标对厂区洞室围岩进行了分类,同时分析评价了各种地质条件下的洞室围岩稳定性。最后对厂房3种布置方案的工程地质条件进行了分析对比,得出第三方案是本工程地下厂房最佳位置的结论。