载钴沸石上Co^3＋的还原作用

本文釆用XRD,XPS,TGA和TPR-XRD技术考察浸渍钴HZSM-5沸石催化剂的还原作用,结果表明:浸渍型载钴沸石经焙烧后,钴主要以Co_3O_40.形态存在于沸石外表面,其粒度为350(?)左右。同时有部分钴离子进入孔内与H~+进行交换,以类似Co(OH)_2形态存在于沸石内表面。500℃还原后,还原度随载钴量增加而增大,其大于57%,粒度在250-270(?)间。还原过程中,出现2个TPR峰,分别相应于过程中的Co~(3+)→Co~(2+)→Co二个阶段,各阶段的特征温度依次为:591-624°K;644-658°K。     

高校自然科学学报学术评价研究

文章以统计资料为基础,对科技期刊及其自然科学学报学术评价的科学性和客观性进行了分析讨论,认为对期刊学术质量的认定,尤其是对高校自然科学学报来说,一定要实事求是科学客观地看待,不能绝对化,只有这样才能作出正确的学术定位,从而促进期刊健康地发展。     

EL的特性及集成电路驱动的研究

在分析了EL电致发光特性的基础上，介绍了EL的应用领域及驱动特点．同时介绍了美国Sipex公司生产的电致发光驱动芯片SP4422A和美国IMP公司的IMP803电致发光驱动芯片及其实用电路的分析．     

优质肉鸡ADSL及GART基因PCR-SSCP分析

采用PCR-SSCP技术对大恒鸡S01品系共计300只鸡的ADSL及GART基因进行多态性分析,结果显示：ADSL基因第9个外显子存在一个SNP位点,测序结果显示其纯合子CC与TT相比有一个C10191T的单碱基突变;GART基因在5’侧翼序列存一个SNP位点,其纯合子AA与BB相比有一个C153T单碱基突变,采用独立性x2分析发现,ADSL及GART基因都达到Hardy-Weinberg平衡.     

IMP在过热器再热器在线故障诊断系统中的应用——原理与编程

系统介绍了IMP数据转换器在过热器、再热器在线诊断系统中作为现场数据采集环节的原理和性能,并对其硬件系统的构成和软件的二次开发作了详细说明。     

智能化再现机器人的设计问题讨论

对开式链机器人的运动分析问题进行研讨,进而采用IMP机械系统通用分析方法,得以完满的解决.引入了"虚拟杆”的概念.在求解过程中,给出了迭代的新方法,求解了多关节、远距离、不连续运动要求的机器人运动学逆问题的最优解,最后,通过实例计算,给以了验证.     

绿色照明CCFL电子镇流器的设计

电子镇流器的研制是CCFL电光源产业化的关键.论文阐述了基于半桥驱动芯片IMP3521开关电路的设计,分析验证了变压器漏感镇流电路的等效模型,探讨了灯管异常保护电路的设计.针对照明CCFL灯管的电气特性,采用高集成度的IMP3521和变压器漏感镇流技术,设计了一种高性价比的电子镇流器.     

A reversible dual-channel chemosensor for fluoride anion

A colorimetric and fluorescent fluoride probe bearing phenolic hydroxy and imine groups has been designed and synthesised. This receptor could visually and spectroscopically recognise F^?  with high selectivity over other anions. After the addition of fluoride ions to the solution of ([1,1′-biphenyl]-4,4′-diylbis (azanylylidene)) bis (methanylylidene)) bis (naphthalen-2-ol) (TY), since the deprotonation reaction occurred between the sensor and fluoride, the fluorescence intensity of the solution changed significantly. Furthermore, the quenched fluorescence caused by fluoride ions could be recovered upon the addition of calcium ions to this complex solution. This resulted in an ‘OFF-ON-OFF’ type sensing. In particular, an IMP logic gate has been proposed using the output obtained from the fluorescence studies. The fluorescence, UV-vis titration and ¹H NMR titration experiments indicated that the effects might occur via a combined process including hydrogen bond and deprotonation between the sensor and F^? .     

NMR metabolic profiling of organic and aqueous sea bass extracts: implications in the discrimination of wild and cultured sea bass

The nuclear magnetic resonance (NMR) technique was used as analytical tool to determine the complete metabolic profiling of sea bass extracts: water-soluble metabolites belonging to different classes such as sugars, amino acids, dipeptides and organic acids as well as metabolites soluble in organic solvent such as lipids, sterols and fatty acids were identified. The metabolite profiling together with a suitable statistical analysis were used to discriminate between wild and cultured sea bass samples. Preliminary results show that discrimination between wild and cultured sea bass was obtained not only using fatty acid composition but also cholesterol and phosphatidylethanolamine and some water-soluble metabolites such as choline, trimethylamine oxide, glutamine, fumaric and malic acids.     

提高酵母菌AMP产量方法研究

酵母菌体内含有丰富的核糖核酸,是生产核酸类物质的重要原料.本方法在酵母菌培养液中加入IMP,在控制一定氨离子浓度的条件下,利用酵母酶系作用使IMP在该条件下高效地转化为AMP.以离子交换法提取产物,最终AMP产量为2.96 g.L-1,产品纯度可达90%以上.