Fructose-selective calorimetric biosensor in flow injection analysis

A highly selective, interference free biosensor for the measurement of fructose in real syrup samples was developed. The assay is based on the phosphorylation of d(−)fructose to fructose-6-phosphate by hexokinase and subsequent conversion of fructose-6-phosphate to fructose-1,6-biphosphate by fructose-6-phosphate-kinase. The heat liberated in the second reaction is monitored using an enzyme thermistor. The major advantages of this biosensor are rapid and selective measurement of fructose without the need to eliminate glucose and inexpensive FIA-based, mediator-free calorimetric measurement suitable for regular fructose analysis. This method was optimised for parameters, such as pH, ionic strength, interference, operational stability and shelf life. Good and reproducible linearity (0.5-6.0 mM) with a detection limit of 0.12 mM was obtained. Fructose determination in commercial syrup samples and spiked samples confirmed the reliability of this set-up and technique. The biosensor gave reproducible results with good overall stability for continuous measurements over a period of three months besides a useful shelf life of six months. The method could be used for routine fructose monitoring in food samples.     

功利制度和制度公益——香港行政申诉制度研究

从价值伦理的角度对香港行政申诉制度进行研究,将有助于分析香港行政申诉制度在设计与运行过程中怎样实现功利性诉求和公益性保障两者的有机结合。探求一个制度必须具备怎样的价值伦理之维,才能在实现目标而又不违背社会正义的情况下,获得利害相关人的认同和支持,并得以有效运行。     

Improving the multiparty quantum secret sharing over two collective-noise channels against insider attack

The security of the multiparty quantum secret sharing protocol presented by Zhang [Z.J. Zhang, Physica A, 361 (2006) 233] is analyzed. It is shown that this protocol is vulnerable to the insider attack since eavesdropping detection is performed only when all states arrive at the last agent. We propose an attack strategy and give an improved version of the original protocol. The improved protocol is robust and has the same traits with the original one.     

MOCVD growth of spherical aggregates of SiC nanocrystallites

Spherical aggregates of SiC nanocrystallites can be grown in addition to SiC nanowires via metal organic chemical vapor deposition using methylvinyldichlorosilane as a source gas and Ni catalyst by controlling the growth temperature and the pressure of the source gas. Electron microscopy observations show that the aggregates are typically 300 nm in diameter, which consist of SiC nanocrystallites of about 5 nm in diameter. Electron diffraction reveals that the nanocrystallites have the 3C structure.     

线粒体外膜通道蛋白VDAC与靶向肿瘤细胞凋亡

VDAC(Voltage-dependent anion channel)是位于线粒体外膜上的一种主要通道蛋白,参与线粒体内外物质和能量的运输,在线粒体与细胞其它部位的通讯中起重要调节作用.近年来研究发现,VDAC也是线粒体与其它蛋白质相互作用的功能结合位点,可与多种凋亡调节蛋白(如HK-Ⅰ/Ⅱ、Bcl-2家族蛋白、tubulin、MAP2/4等)以及非蛋白调节因子相互作用,参与调控细胞凋亡.因此,VDAC成为线粒体凋亡通路中一种关键的靶蛋白.本文对近年来VDAC在肿瘤细胞凋亡中的作用机制进行简要综述.     

Multiparty quantum secret sharing based on Bell measurement

A multiparty quantum secret sharing scheme based on Bell measurement is proposed and analyzed. In this scheme, all agents are not required to prepare entangled states or perform any local unitary operation. The security of the protocol is also analyzed. It is shown that any eavesdropper will introduce errors invariably and be detected if he tries to steal information about Trent’s secret. Moreover, because no classical bit needs to be transmitted except those for detection, the total efficiency of the scheme approaches to 100%.     

An improved quantum key distribution protocol based on second-order coherence

We improve the quantum key distribution protocol proposed by Pereira et al. [S.F. Pereira, Z.Y. Ou, H.J. Kimble, Phys. Rev. A 62 (2000) 042311], by employing the second-order coherence of optical fields, which can be easy experimentally measured with a Hanbury-Brown and Twiss intensity interferometer. It is shown that eavesdropping can be directly detected without sacrificing extra secret bits as test key. The efficiency of the improved system is enhanced greatly, since no secret bit needs to be discarded.     

Application of optical and luminescent techniques to the characterization of oxide thin films

The interaction between light and electrons in oxide compounds forms the basis for many interesting and practical effects, which are related to microstructure, energy band, traps, carrier transport and others. Thin films of oxides like WO₃, Ga₂O₃, Y₂O₃ and SrTiO₃ were investigated using various improved optical and luminescent techniques. The home-made systems for optical and luminescent measurements were described in detail. The facilities of photo-Hall and photoconductivity transients have been proven to be powerful tools in the studies, which allow us to perform photoinduced process and relaxation measurements over a wide time range from 10⁻⁸ to 10⁴ s. Furthermore, we extended the measurement capabilities of the commercial luminoscope by using an interferometer system with optical fiber and illuminance meter instead of an optical microscope. The cathodoluminescent measurements can be performed at a relative high pressure (20-60 mTorr) compared to ultra-high-vacuum condition of most commercial products. Luminescent characterization was employed as a probe to study doping ions, oxygen vacancies, trap and/or exciton levels in oxide thin films. Our results suggest that various traps and/or excitons in thin films of WO₃, Ga₂O₃ and SrTiO₃ involve in the process of photoconductivity relaxation and emission.     

Spin dynamics of layered triangular antiferromagnets with uniaxial anisotropy

The spin dynamics of the semiclassical Heisenberg model with uniaxial anisotropy, on the layered triangular lattice with antiferromagnetic coupling for both intralayer nearest neighbor interaction and interlayer interaction is studied both in the ordered phase and in the paramagnetic phase, using the Monte Carlo-molecular dynamics technique. The important quantities calculated are the full dynamic structure function S(q,ω)$S(\mathbf{q},\omega )$, the chiral dynamic structure function _Schi(ω)$S_{\mathrm{chi}}(\omega )$, the static order parameter and some thermodynamic quantities. Our results show the existence of propagating modes corresponding to both S(q,ω)$S(\mathbf{q},\omega )$ and _Schi(ω)$S_{\mathrm{chi}}(\omega )$ in the ordered phase, supporting the recent conjectures. Our results for the static properties show the magnetic ordering in each layer to be of coplanar 3-sublattice type deviating from 120^°${120}^{°}$ structure. In the presence of magnetic trimerization, however, we find the 3-sublattice structure to be weakened along with the tendency towards non-coplanarity of the spins, supporting the experimental conjecture. Our results for the spin dynamics are in qualitative agreement with those from the inelastic neutron scattering experiments performed recently.