致密砂岩储层可动流体赋存特征及影响因素

应用核磁共振、恒速压汞、铸体薄片等实验手段,分析辽河西部凹陷南段沙三段致密砂岩储层可动流体赋存特征及影响因素。结果表明:可动流体T2谱截止值低,孔隙内可动流体饱和度与可动流体孔隙度低且数值波动大;T2谱形态主要呈单峰型、左峰高右峰低型和左峰低右峰高型;T2弛豫时间受孔喉结构控制,喉道特征决定流体的可动程度,孔喉半径比、分选系数和微观均质系数反映孔隙结构非均质程度与流体参数线性相关性较强,T2谱分布特征与孔隙组合类型和孔喉结构特征有关;胶结物类型、产状与含量对可动流体影响较大。微观孔隙结构特征是可动流体赋存特征的主要影响因素,胶结物次之,物性对可动流体的影响是两者的综合反映。     

Formulation of Visible Light-Curable Glass-Ionomer Cements Containing N-Vinylpyrrolidone

Abstract

The best graft ratio of the light-curable N-vinylpyrrolidone (NVP) modified terpolymers (LC NVPM TPs) with the molar ratio of 8:2:1 (acrylic acid:itaconic acid:NVP) and the optimal formulation for this light-curable glass-ionomer cement, based on the best graft ratio, were determined. Statistical models were utilized to predict the optimal formulations. The terpolymer was prepared using a free-radical polymerization reaction. The LC NVPM TPs were produced by grafting 2-isocyanatoethyl methacrylate (IEM) onto the terpolymer. Cements were formed by both light-curing and the reaction with glass particles. Compressive strength was used as the basic screening property to find the optimal formulation. Diametral tensile and flexural strengths were also used to evaluate the mechanical properties. The strength values were recorded on the specimens conditioned in distilled water at 37&C for 24 hours or 7 days. The best graft ratio for IEM in this system was 15% of the terpolymer by a molar ratio. The optimal formulation was found to be at the weight ratio of 55:15:30 [LC NVPM TP:2-hydroxyethyl methacrylate (HEMA): H₂O]. Stress-strain curves showed that a relatively high amount of water in the formulation led to higher elastic modulus and proportional limit and lower malleability, whereas a relatively high amount of HEMA gave the opposite results. The light-curable NVP modified glass-ionomer cements showed statistically significantly higher values in compressive, diametral tensile, and flexural strengths than the commercial Vitremer^TM.     

日产2000吨水泥熟料预分解窑仿真系统

介绍了由计算机和仪表组成的水泥厂预分解窑仿真系统的计算机网络、仪表控制柜、动态流程图的硬件组成及软件实现思想。该系统采用仿集散型控制系统DCS类型的控制系统与过程全仿真形式。详细介绍了双系统硬件结构、仪表仿真盘台接口线路框图。系统对日产 2 0 0 0吨水泥熟料预分解窑中央控制室进行仿真 ,可模拟中控室人员进行工厂生产控制并进行故障排除训练。     

Effect of Solvent on the Radical Copolymerizability of Styrene with 3(2-Methyl)-6-methylpyridazinone

Abstract

The radical copolymerization of styrene (St, M₁) with 3(2-methyl)-6-methylpyridazinone (I, M₂) has been carried out in several p-substltuted phenols at 60 and 70°C. Monomer reactivity ratios (r₁) and activation parameters of copolymerization were found to be affected by phenols. The values of the activation energy (δδE?) and entropy (δδS?) increased with the increase of the interaction of I with the solvents. Linear relationships were observed between the [sgrave]-values of p-substituents of phenols and the values of log 1/r₁ and also of δδE? and δδS?. The radical copolymerization of St (M₁) with 6-substituted 3(2-methyl)-pyridazinone was also carried out.     

电厂煤粉炉联产高硅硫铝酸盐水泥熟料试验

在对不同系列水泥熟料化学和矿物组成分析的基础上,进行了水泥主要原料和煤灰渣化学成分的比较,分析了高硫煤联产水泥熟料的可行性及联产水泥熟料的品种,提出了高硫煤联产硫铝酸盐水泥熟料的配料方案,并在两段多相试验台进行了长广煤联产水泥熟料试验研究,结果表明联产样品熟料为高硅硫铝酸盐水泥熟料。