C2（a 3Πu）+NO 的反应机理研究

在G2 (CC ,MP2 )理论水平上研究了C2 (a3 Πu)自由基与NO分子的反应 .计算了反应体系最低二重态势能面上各驻点的构型参数、振动频率和能量 ,揭示了此反应存在两种反应机理 :由NO中的O原子进攻C2 自由基形成CCON中间体的CCON机理和NO中的N进攻C2 自由基形成CCNO中间体的CCNO机理 ,分析了对应与这两种反应机理的五个可能的反应通道 ,得出了由NO中的N原子进攻3 C2 自由基 ,生成中间体CCNO自由基 ,最终得到产物CN +CO的通道是最有利的通道 .     

A MINI MULTI-GAS DETECTION SYSTEM BASED ON INFRARED PRINCIPLE

To counter the problems of gas accidents in coal mines, family safety resulted from using gas, a new infrared detection system with integration and miniaturization has been developed. The infrared detection optics principle used in developing this system is mainly analyzed. The idea that multi gas detection is introduced and guided through analyzing single gas detection is got across. Through researching the design of cell structure, the cell with integration and miniaturization has been devised. The way of data transmission on Controller Area Network (CAN) bus is explained. By taking Single-Chip Microcomputer (SCM) as intelligence handling, the functional block diagram of gas detection system is designed with its hardware and software system analyzed and devised. This system designed has reached the technology requirement of lower power consumption, mini-volume, big measure range, and able to realize multi-gas detection.     

浅议CS与CC的融合

论述了顾客满意战略（CS）与企业文化（CC）的融合是我国企业文化建设的必然趋势，二者的融合实质上是企业文化建设的重塑，指出企业文化的建设在经历了从CI（企业形象）到CS的转变之后，实际上已形成了一种崭新的企业文化，而这对于我国企业改革取得最终的成功有着重大的意义。     

Design of highly active heterogeneous palladium catalysts for the activation of aryl chlorides in Heck reactions

In situ generation of highly active palladium species by intermediate dissolution of Pd from solid supported catalysts has been demonstrated to be a very successful approach for the activation of aryl chlorides in Heck reactions. The new ‘heterogeneous’ Pd catalysts act as reservoir for molecular Pd species with unsaturated coordination sphere in solution. Crucial Pd leaching and re-deposition onto the support can be controlled by optimization of reaction conditions and by the properties of the catalysts. Pd is re-deposited onto the support at the end of the reaction. The catalysts, palladium supported on activated carbon, on various metal oxides or fluorides and Pd complexes in zeolites, are easy to prepare, though the preparation conditions are crucial. The catalysts convert all aryl bromides completely within minutes (TON 100,000). Aryl chlorides (even deactivated ones) are converted with high yields, within 2-6 h. The catalysts belong to the most active ones in Heck reactions at all (including best homogeneous systems) and fulfill all relevant requirements for practical applications in laboratory and industry.     

PFBC—CC燃机叶片试片腐蚀／磨蚀初步研究

介绍了ＰＦＢＣ－ＣＣ燃机叶片腐蚀／磨蚀试验装置的系统，主要部件，允许试验参数及其主要特点，累计４００多小时的热态试验表明该装置性能稳定，达到了设计要求，初步试验结果是，高，低温试验区均为腐蚀／磨蚀联合作用，高温试验区腐蚀为主，低温试验区磨蚀为主。     

CC专家库的研究与设计

CC工具箱系统是遵循CC标准而设计的一套对信息技术产品和系统的安全功能及相应保证措施进行自动化评估的软件系统．该系统主要包括CC工具箱和CC专库（CCEB)两个模块．提出了CC专家库(CCEB)的规划设计思路，并将此设计规划方案进行了实现，以及将CCEB导入CC工具箱，以完成对CC工具箱系统的支持．实践证明，CCEB方案是有效和实用的。     

Applicability of medium-size basis sets in calculations of molecular dynamic polarisabilities

Static and dynamic average polarisabilities and polarisability anisotropies of seven linear non-polar and polar molecules are calculated within the CCS, CC2, and CC3 approximations using a range of medium-sized basis sets: the polarised LPol-n (n = ds, dl, fs, fl), the aug-pc-n (n = 1, 2), the def2-SVPD, and -TZVPD basis sets. Reference values are obtained using a hierarchy of Dunning's (d-)aug-cc-pVXZ (X = D, T, Q, 5) basis sets. The results are discussed together with the available CCSD values in terms of basis set and correlation method errors, and their ratio. Detailed analysis shows that already the def2-SVPD basis set can be used in CCS polarisability calculations. When affordable, the slightly larger aug-pc-1 basis set is recommended, as it leads to significant reduction of basis set error. The def2-TZVPD, LPol-ds, and aug-pc-2 basis sets are optimal choice within the CC2 approximation, with the latter allowing to approach the CC2 basis set limit. The LPol-ds, -dl, and def2-TZVPD sets outperform the aug-cc-pVTZ set in average polarisability CCSD calculations, with the def2-TZVPD being competitive to other reduced-size sets also in determination of polarisability anisotropy. The aug-pc-2 basis is a particularly attractive choice for CCSD, giving the accuracy of aug-cc-pVQZ at a significantly reduced computational cost. The polarisability anisotropy is shown to be more computationally demanding than the average polarisability, in particular with respect to the accuracy of the correlation method and an accurate evaluation of this property requires at least the CCSD model.     

Ugi three-component coupling reaction for the synthesis of 2-(6-oxo-11-phenyl-7,8-dihydrobenzo[b]pyrrolo[1,2-d][1,4]diazocin-5(6H)-yl)-2-phenylacetamide derivatives

A three-component, four center Ugi reaction of 3-(1-(2-aminophenyl)-5-phenyl-1H-pyrrol-2-yl)propanoic acid with aromatic aldehyde and t-butyl isocyanide has been achieved to produce a novel class of N-tert-butyl-2-(6-oxo-11-phenyl-7,8-dihydrobenzo[b]pyrrolo[1,2-d][1,4]diazacine-5(6H)-yl)-2-phenylacetamides in moderate to good yields.     

新一代天气雷达运行状态短信监视系统设计与实现

针对目前云南省新一代天气雷达运行状态监控的现状,结合业务的需要,设计并实现了云南省新一代天气雷达运行状态手机短信监视系统.该系统基于.NET平台,采用SQL2000数据库和C#编程语言,实现了雷达故障信息短信报警和运行状态短信查询功能.通过该系统,相关机务员和管理者可以第一时间获得雷达故障信息,实现无人值守式全天候的实时监视,为雷达故障信息和状态信息的管理提供了有效的手段和方法,确保了新一代天气雷达的正常业务运行.     

CCL25/CCR9与骨髓祖细胞胸腺归巢

在骨髓中多种祖细胞有T细胞系潜能,但骨髓祖细胞胸腺归巢具有选择性.骨髓祖细胞胸腺归巢是多级粘附分子和趋化因子的级联过程,趋化因子CCL25及其受体CCR9在这一过程中发挥了重要作用.综述了CCL25/CCR9的结构特征及其对骨髓祖细胞胸腺归巢的作用和调节机制.