关于水泥砂浆墙面起砂问题的防治

分析了水泥砂浆墙面起砂的原因，并提出了预防措施和处理办法。     

缓凝砂浆螺旋输送理论研究

缓凝预应力筋包覆装置是将新型独特的缓凝材料应用于预应力混凝土体系的一种施工设备．通过对缓凝砂浆的流变性能分析，建立了螺旋输送物理模型，运用粘性流体力学的运动微分方程研究缓凝砂浆螺旋输送的速度场和流率，从而对其装置的设计和运行参数的合理选择提供了理论依据．     

Application of the essential work of fracture concept to nanostructured polymer materials

The first part of the paper deals with a critical discussion of the methodical basis of essential work of fracture (EWF) concept with respect to the specimen geometry (especially the notch depth) and application to polymers. In the second part, an in situ testing device, which combines a tensile testing machine with an optical strain-field measuring system, has successfully demonstrated possibility of characterization of fracture behaviour of polystyrene-polybutadiene block copolymers and block copolymer/homopolymer blends as examples of nanostructured polymer materials. It has been shown that knowledge of the time evolution of the strain field close to the crack tips leads to a simple verification of the basic precondition for the applicability of the EWF concept, the precondition “plastic zone coalescence-before-stable crack propagation”.     

Reaction of η5-cyclopentadienylbis(triphenylphosphine)cobalt(I) with alkadiynes. Preparation and reactions of bicyclic cobalt metallocycles and a stable trimethylsilyl-substituted mono-complexed alkadiyne. Comments on the mechanism of cobalt-catalyzed alkyne cooligomerization

Reactions of η⁵-cyclopentadienylbis(triphenylphosphine)cobalt(I) (5) with several 2,n-alkadiynes (2) were investigated. Each of these reactions leads initially to a material in which one of the acetylene functional groups is π-coordinated to cobalt; this complex then undergoes conversion to a metallocycle. In cases where the two acetylene functions are connected by three- and four-carbon bridges (2b, 2c), metallocycles formed by intramolecular reaction of two acetylene functions in the same molecule may be isolated. In cases where the acetylene functions are joined by larger or smaller bridges, the reactions are more complex, and both inter- and intramolecular metallocycles are formed. Reactions of 5 with 1,8-bis(trimethylsilyl)-1,7-octadiyne (16) gives an isolable crystalline mono-acetylene complex (17), this material is stable in the solid state but undergoes conversion to metallocycle (18) in benzene solution. The relationship of these results to the mechanism of the CpCo(CO)₂-catalyzed benzocycloalkene synthesis is discussed; it is suggested that intramolecular metallocycles are intermediates in reactions leading to benzocyclopentanes and -cyclohexenes, but intermolecular metallocycles are probably involved in reactions leading to benzocyclobutenes.     

Thermal characterization of portland cement-magnesia blends

Summary Due to growing environmental concerns and the need to use less energy-intensive building products, alternatives and improvements to Portland cement (PC) are being actively researched worldwide. Use of supplementary materials is now a common practice where PC is the predominant component of inorganic building products. This study aims to investigate the potential of magnesia (MgO), derived from a naturally occurring raw material magnesite, as a supplementary material. Results from mortar samples prepared with 10 and 20% replacements of ordinary Portland cement (OPC) by MgO are presented. DTA-TG was used to study and characterise the hydration behaviour of MgO in OPC environment after 3, 7, 14, 28, 56 and 90 days of moist curing. Microstructural and compressive strength determinations providing additional information on the influence of hydrated phases are also reported.     

Photochemistry of β, γ-unsaturated ketones-V: The direct irradiation of some γ-phenyl β, γ-enones

The photochemistry of some members of the two series of γ-phenyl substituted acyclic β, γ-unsaturated ketones 1 and 2 upon direct irradiation with γ 310nm has been investigated, viz 1c–1h and 2b+2c.The alkyl substituted (E)-5-phenyl-4-penten-2-ones 1c–1h yield the corresponding 1,3-acyl shift products and (Z)-isomers, and 1g and 1h in addition two decarbonylated products. 2b only yields the (Z)-isomer and some benzaldehyde, but 2c yields the 1,3-acyl shift product, the ODPM product, three hydrocarbons formed by disproportionation of the allyl radical, and some benzaldehyde. The β-phenyl β, γ-UK 3a proved to be photostable. The 1,3-acyl shift products of 1c–1h result mainly from the singlet excited state in a cage radical process. The exclusive formation of the (E)-configuration of the 1,3-acyl shift product is explained in terms of conformational preference of the intermediate allyl radical. It is proposed that the formation of the (Z)-isomer proceeds from ¹T(π -π^*) which is populated according to

. Evidence is presented which supports the proposed mechanism.The β,γ-UK 2b containing a benzoyl moiety leads to a higher degree of (E)-(Z) isomerization than the corresponding 1d which has an acetyl moiety.The triplet energies of (E)- and (Z)-1h are 56 and ca 70 kcal/mol respectively.     

PKI/CA互操作模型的应用研究

随着电子商务、电子政务、电子事务的不断发展，PKI／CA体系所带来的互操作问题制约了PKI／CA技术的应用。本文就PKI／CA互操作问题进行分析，对国内外已存在的几大互操作技术比较讨论，最后提出可行方案：混合式的树状／桥接CA模型结构。     

双向地震耦合作用对基础摩擦隔震结构的影响

采用多质点层间剪切型模型,建立了基础摩擦隔震多层砌体结构在水平与竖向耦合地震作用下的运动微分方程及滑动与啮合状态判别准则·通过数值计算,分析了竖向地震作用对隔震结构的影响,研究表明,竖向地震作用的存在,使隔震结构下部各层,特别是首层的层间位移,层间剪力增加,隔震层加速度增加,且随地震烈度,竖向加速度峰值增大而增加,并使隔震层的滑动位移幅值有增大的可能·建议在高烈度震区考虑竖向地震作用对结构反应的影响·     

一种电子商务税收征管系统模型的研究

探讨了网上交易的过程,给出了一个基于SET协议和CA认证的税收征管方案．     

胶砂质量比对钢纤维砂浆力学性能的影响

对胶砂质量比和纤维直径对钢纤维水泥浆体和砂浆的力学性能的影响进行了研究 .在水泥浆体中 ,微细钢纤维的增强和增韧作用显著高于较大直径的钢纤维 .在砂浆中 ,随着胶砂质量比的降低 ,较大直径的钢纤维的作用越来越强 ,而微细钢纤维的作用逐渐降低 .不同几何尺寸的钢纤维在水泥浆体和砂浆中具有不同的作用效果 ,尺寸效应显著