High-throughput screening of fuel cell electrocatalysts

The drawbacks of our earlier report of preparing fuel cell catalyst arrays by borohydride reduction of inkjet prepared arrays of metal salts are discussed along with the need for inclusion of state-of-the-art metrics in all array screening. An alternative method for screening of hydrogen/air cathode catalysts, direct methanol fuel cell (DMFC) anode catalysts, and catalyst loading studies is provided. State-of-the-art Johnson Matthey catalysts were used in control experiments to demonstrate the utility of the array fuel cell for high throughput screening of fuel cell catalysts in the 3-4 mg/cm² range. This report lays out hard learned rules for high throughput screening and demonstrates that the array fuel cell can be used for very precise screening of libraries of membrane electrode assembly (MEA) components without the pitfalls discussed in the introduction.     

图书馆服务器和磁盘阵列管理

本文论述了服务器和磁盘阵列在图书馆中的应用和管理,说明了服务器和磁盘阵列在图书馆电子资源建设中的重要作用,进一步揭示了网络安全和数据安全在服务器和磁盘阵列管理和维护过程中的重要性。     

Large-scale synthesis of tube-like ZnS and cable-like ZnS-ZnO arrays: Preparation through the sulfuration conversion from ZnO arrays via a simple chemical solution route

Arrayed structures are desirable for many applications, but the fabrication of many material arrays remains a significant challenge. As a prominent II-VI semiconductor, large-scale arrayed ZnS structure has not been easily fabricated. Here, we introduce a simple structure conversion route for the synthesis of novel arrayed structures, and large-scale tube-like ZnS structure arrays and cable-like ZnS-ZnO composite arrays were successfully prepared through sulfuration conversion from arrayed rod-like ZnO structure based on a hydrothermal method at low temperature. XRD, EDS, SEM, TEM and PL are used to confirm the formation of the novel arrayed structure and trace the conversion process. The results show that the conversion ratio can be conveniently tailored by the reaction time, and the PL properties of the obtained materials can be adjusted through the conversion ratio. Especially, the cable-like structure holds the PL properties of both ZnO and ZnS structures. This simple solution method can be further extended to the preparation of other semiconductor sulfide and selenide, and can amplify the application field of large-scale arrays of semiconductors.     

Simultaneous multichannel mass-specific detection for high-performance liquid chromatography using an array detector sector-field mass spectrometer

The use of a separation step, such as liquid chromatography, prior to inductively coupled plasma mass spectrometry (ICP–MS) has become a common tool for highly selective and sensitive analyses. This type of coupling has several benefits including the ability to perform speciation analysis or to remove isobaric interferences. Several limitations of conventional instruments result from the necessity to scan or pulse the mass spectrometer to obtain a complete mass spectrum. When the instrument is operated in such a non-continuous manner, duty cycle is reduced, resulting in poorer absolute limits of detection. Additionally, with scanning instruments, spectral skew can be introduced into the measurement, limiting quantitation accuracy. To address these shortcomings, a high-performance liquid chromatograph has been coupled to an ICP–MS capable of continuous sample introduction and simultaneous multimass detection. These features have been realized with a novel detector array, the focal plane camera. Instrument performance has been tested for both speciation analysis and for the elimination of isobaric interferences. Absolute limits of detection in the sub picogram to tens of picograms regime are obtainable, while the added mass dimension introduced by simultaneous detection dramatically increases chromatographic peak capacity.     

The MPE/UCB far-infrared imaging Fabry-Perot interferometer (FIFI)

FIFI is an imaging spectrometer with two or three Fabry-Perot interferometers (FPI) in series for airborne astronomical observations in the far-infrared range (=40...200m). It employs 5×5 arrays of photoconducting detectors and offers spectral resolutions as small as 2km/s. Resolution and bandwidth can be set over a wide range to match a variety of astronomical sources. Cryogenic optics minimizes thermal background radiation and provides for in-flight step tunable spatial resolution. At 158 m wavelength the background-limited NEP is 3 × 10^-15W/Hz at 40 km/s resolution and with two FPI's; with three FPI's the expected NEP is 10^-15WHz at 5 km/s resolution.The frequency-chopping mode of the high-resolution Fabry-Perot allows for line detection in extended objects. Absolute internal flux calibration ensures adequate flat fielding of the array elements.     

太阳能电池最大功率跟踪技术研究

本文介绍了光伏电池系统的输出特性及跟踪技术的基本原理．列举了多种常用的跟踪的方法．总结了当前的最大功率跟踪技术(MPPT)。并对各自的的优缺点进行了详细的分析比较。     

一种高精度测量交流系统功率的方案

提出了一种采用现场可编程门阵列(简称FPGA)实现交流系统功率测量的方法.FP GA中采用离散数学的方法实现DSP算法用于交流系统的功率测量,由于FPGA具有较高的分辨率和较好的性能,使功率测量精度不再受传统处理机的分辨率所限,测量的精度得到提高.文中采用硬件高精度的方法实现数字积分功能,克服了由于电压电流的波形偏离正弦波所带来的测量误差,为交流系统功率测量提供了一个高精度、快速的测量方案.     

高清晰度数字电视中的符号定时检测算法

分析研究了欧洲数字视频地面广播（DVB－T）系统，提出了基于FPGA的COFDM接收机同步解决方案，对该方案中的符号定时同步，步骤同步和采样钟同步作了简要阐述了，经大量的同步算法仿真分析，提出一种新的符号定时检测算法：通过设置门限、保持窗宽和相应时延可准确估计符号起始位置及频偏，相应的FPGA硬件电路经高清晰度数字电视功能样机调试证明，该算法实现复杂度低且性能优良。     

功能覆盖膜对场发射阵列（FEA）电子发射性能的影响

为了寻找适合真空微电子器件的场发射阵列（ＦＥＡ）覆盖材料，我们采用了一系列功能材料作为覆盖膜，薄膜淀积采用离子束辅助淀积（ＩＢＡＤ）以及其它淀积技术。在１０＾－６Ｐａ下测量具有不同覆盖膜的硅ＦＥＡ二极管的Ｉ－Ｖ特性，测量结果表明除Ａｕ和Ｍｏ外，其它覆盖材料都对ＦＥＡ电子发射性能有改进，经ＴａＮ覆盖的ＦＥＡ发射电流最大。由Ｆ－Ｎ曲线估算出有效表面功函数和有效发射面积，从而说明以上所得的实验结果。     

蒙特卡罗模拟方法对EAS阵列性能分析与优化设计的研究

建立了快速计算机阵列性能分析程序，由此阵列性能进行快速分析，对种种阵列设计方案进行比较搜寻，本文介绍其基本定理，方法、程序设计及部分计算结果。