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1.
《Arabian Journal of Chemistry》2020,13(11):8424-8457
Nowadays, increasing extortions regarding environmental problems and energy scarcity have stuck the development and endurance of human society. The issue of inorganic and organic pollutants that exist in water from agricultural, domestic, and industrial activities has directed the development of advanced technologies to address the challenges of water scarcity efficiently. To solve this major issue, various scientists and researchers are looking for novel and effective technologies that can efficiently remove pollutants from wastewater. Nanoscale metal oxide materials have been proposed due to their distinctive size, physical and chemical properties along with promising applications. Cupric Oxide (CuO) is one of the most commonly used benchmark photocatalysts in photodegradation owing to the fact that they are cost-effective, non-toxic, and more efficient in absorption across a significant fraction of solar spectrum. In this review, we have summarized synthetic strategies of CuO fabrication, modification methods with applications for water treatment purposes. Moreover, an elaborative discussion on feasible strategies includes; binary and ternary heterojunction formation, Z-scheme based photocatalytic system, incorporation of rare earth/transition metal ions as dopants, and carbonaceous materials serving as a support system. The mechanistic insight inferring photo-induced charge separation and transfer, the functional reactive radical species involved in a photocatalytic reaction, have been successfully featured and examined. Finally, a conclusive remark regarding current studies and unresolved challenges related to CuO are put forth for future perspectives. 相似文献
2.
《印度化学会志》2023,100(2):100890
The pristine ZnO and ZnO-Graphene hybrid composites at various graphene ratios were synthesized via facile ultrasonic assisted solution approach. The crystal structure is identified by powder XRD technique and disclosed the hexagonal wurtzite structure. The synthesized ZnO exhibited uniform spherical like morphology with low degree of aggregation. The formation of hybrid composite of graphene and ZnO could improve the light absorption ability and separation of photo generated carriers of ZnO, which is confirmed through photoluminescence and UV–Vis DRS analysis. The photo catalytic degradation of Crystal violet, Cr (VI) and 2, 4 D were evaluated under visible light irradiation. The Zn-Graphene hybrid composite exhibited higher photo catalytic activity towards CV dye, Cr (VI) and 2, 4-D, such as high photo degradation efficiency and good stability than bare ZnO. This could be due to the high surface area and synergic effect between the graphene and ZnO p–n junctions. The mechanism of enhanced photo catalytic activity of Zn-Graphene composite discussed in detail. 相似文献
3.
Natalia Quici Marta I. Litter Andr M. Braun Esther Oliveros 《Journal of photochemistry and photobiology. A, Chemistry》2008,197(2-3):306-312
The vacuum-UV- (VUV-) photolysis of water is one of the advanced oxidation processes (AOP) based on the production of hydroxyl radicals (HO) that can be applied to the degradation of organic pollutants in aqueous systems. The kinetics of the VUV-photolyses of aqueous solutions of citric acid (1) or gallic acid (2) were investigated in the presence or absence of dissolved molecular oxygen (O2) and under different pH conditions. In the case of 1, the rate of consumption of the substrate was faster at pH 3.4 than in alkaline solution (pH 11), whereas, in the case of 2, the variation of pH (2.5–7.5) did not affect the course of the reaction. Unexpectedly, the rates of depletion of both 1 and 2 decreased in the absence of O2, this effect being much more pronounced in the case of 2. In order to explain these results, possible reaction pathways for the degradation of 1 and 2 are proposed, and the roles of the oxidizing (HO) and reducing (H and eaq−) species produced by the VUV-photolysis of water are discussed. 相似文献
4.
Traditional approach of design by contract, due to mixing the contract code with application code, is difficult for the extensibility and reusability of software system. This paper presents a framework named JADBC for design by contract based on Aspect-Oriented Programming (AOP) to resolve these problems. By providing a new modularized element, aspect, the framework successfully separates the contracts in design by contract, from functional codes. The implementation of this framework is based on dynamic AOP which can have the contract changed at runtime, consequently, enhancing program flexibility. JADBC framework modularizes the contracts in a clear-cut fashion that is easier to design, implement, and maintain. Biography: WEN Jing (1982–), female, Ph.D. candidate, research directions: software engineer, aspect-oriented software development. 相似文献
5.
细粒度角色访问控制模型及其应用 总被引:2,自引:0,他引:2
廖尔崇 《河北省科学院学报》2009,26(3):55-58
针对传统的角色访问控制模型权限控制粒度较大、权限控制代码横切业务功能模块、难以有效支持软件复用等问题.提出了一种细粒度角色访问控制模型。该模型通过引入外权限和内权限细化了权限控制粒度.并通过AOP技术实现了内权限的动态配置,提高了组件复用度和模块独立性。该模型已在实际项目中得到应用,验证了模型的正确性和有效性。 相似文献
6.
对废水的深度氧化,包括光化学氧化,超声波氧化过程中自由基的种类、捕获技术与氧化方式进行了简述。 相似文献
7.
基于事件驱动编程原理,提出方面事件处理器(Aspect Event Handler,AEH)方法,用以有效地处理面向方面软件系统中出现的各类横切功能的调用与维护.结合其在 Java EE 银行业务系统 CrossDebit 相关模块开发中的应用,详细介绍 AEH 方法的实际应用流程和技巧. 相似文献
8.
《Arabian Journal of Chemistry》2022,15(7):103900
Emerging pharmaceutical ingredients (APIs) like sulfamethoxazole (SMX), metronidazole (MNZ) and ciprofloxacin (CIP) are biopersistent and toxic to the environment and public health. In this study, UV/TiO2 photodegradation was applied in the degradation of SMX, MNZ and CIP individually and in a mixture. For a 5 mg/L SMX solution, about 97% of SMX was degraded within 360 min, which was reduced to 80% for 80 mg/L of SMX solution at the same TiO2 dosage and photodegradation time. The maximum removals of MNZ and CIP as individual components were 100% and 89%, respectively at 600 min of photodegradation reaction time. For binary mixtures, the highest removal (100%) was achieved for MNZ and CIP ([MNZ] = [CIP] = 40 mg/L) mixture at 120 min whereas the degradations were 97% and 96% for SMX and MNZ, and SMX and CIP binary mixtures, respectively, even after 600 min of experimental time at the same concentrations. For tertiary mixture, the maximum degradation 99% was observed for (SMX = CIP] = 20 mg/L and [MNZ] = [40 mg/L) at 600 min. The observed reaction rate was 0.01085 min?1 when SMX concentration was 5 mg/L, which decreased to 0.00501 min?1 for SMX concentration of 80 mg/L, indicating decreasing of reaction rate at higher concentration. The results indicate that the UV/TiO2 process is promising to apply for the treatment of pharmaceutical wastewaters. 相似文献
9.
面向切面编程(Aspect-Oriented Programming,简称AOP)作为一种新的编程技术正日益引起人们的关注.文章介绍了AOP产生背景和理论价值,并结合作者所设计的状态机工作流框架,详细讨论了如何通过在该框架中引入AOP机制来克服纯面向对象编程的不足,从中分析了AOP的优势和应用价值,最后对AOP和OOP的关系进行了讨论. 相似文献
10.
AOP event manager in open service gateway〖WT5\"HZ〗Abstract:〖WT5\"BZ〗〖WT5”HZ〗Key words:〖WT5”BZ〗
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The Open Service Gateway Initiative (OSGi) has played an important role in ubiquitous environments that support interoperability among embedded devices, such as home appliances and network devices. However, the OSGi does not have a common event mechanism yet, and it is difficult to communicate among services asynchronously. In the present work, a common event manager, AspectOriented Event Manager (AOEM), was designed on an OSGi framework. AOEM supports services to generate and provide notification of events. This paper presents the implementation of AOEM as an OSGi bundle with AspectJ. The experiment on transferring between device service and application service demonstrate that AOEM provides good abstraction of the services and convenience. 相似文献