应用于屋面蒸发降温的多孔质材料重复吸水性能实验

测试改性酚醛材料和醋酸纤维材料的重复吸水性数据,并通过改造原有的浸润吸水装置,实测改性酚醛材料和醋酸纤维材料在单面接触水源状态下的重复浸润的吸水特性曲线.根据前人的相关研究模型,计算两种材料实际的毛细吸水系数曲线并进行评价.结果表明:两种材料初次进行浸润后,吸水性能降低比例均在25%左右;改性酚醛材料快速吸水阶段会维持1 min左右,而醋酸纤维材料快速吸水阶段会维持10 s左右;两种材料实际应用于被动蒸发降温技术时仍需增强重复吸水性能.     

化学法改性煤沥青脱除苯并芘的研究

在管式反应器中采用苯甲酸、聚乙二醇、固体古马隆树脂（S）、液体古马隆树脂（L）为添加剂来降低煤沥青中有害物质苯并芘的含量，以期使得煤沥青可绿色化应用。采用紫外-可见分光光度计分析煤沥青中苯并芘含量。考察了反应温度、反应时间、添加剂添加量、催化剂等工艺条件对添加剂脱除煤沥青中苯并芘的影响。结果表明，不同工艺条件能降低煤沥青中苯并芘的含量。在优化条件下，不同添加剂对苯并芘脱除率由高到低依次为：液体古马隆树脂、聚乙二醇、苯甲酸和固体古马隆树脂。分析其反应机理，这与催化剂的酸性相关，发生亲电取代反应。结果表明，液体古马隆树脂（L）在催化剂存在下对煤沥青中苯并芘脱除率可达73.0%，显示了良好的应用前景。     

铜质结晶器表面涂覆层的研究进展

结晶器是连铸设备的核心部件。铜质结晶器表面损坏严重劣化钢坯的质量,加大了企业生产成本,延长了生产周期。分析了铜质结晶器表面材料的应用、失效的形式和主要原因;论述了电镀、激光涂覆和热喷涂表面改性技术在铜质结晶器上的应用现状及存在的问题;介绍了铜质结晶器表面涂覆层的性质及类型;提出了研发安全可靠、长寿命和高性能铜质结晶器的主要途径。     

氢化丁苯共聚物结构的核磁共振波谱表征Ⅱ.微观结构的定量计算

在氢化丁苯共聚物¹³C-NMR谱脂肪碳部分谱带归属的基础上,根据各谱带的主要来源,推导出六个二单元浓度的计算公式。计算出二单元、一单元的相对含量,各结构单元的数均序列长度、嵌段含量和其它结构参数。加氢前后的¹H-和¹³C-NMR谱的组成计算结果基本一致。初步探讨了作为粘度指数改进剂的氢化丁苯共聚物微观结构与性能的关系,为合成提供了依据。     

HF-Ⅰ新型改性酚醛树脂研制及性能评价

以苯酚、甲醛、环氧树脂、聚乙烯醇等为原料在酸性催化条件下 ,研制成一种新型环氧改性酚醛树脂 ,通过性能评价并从砂轮、切割片的应用表明。该粘合剂粘结性能、强度、韧性均达到国内同类产品先进水平 ,制做的砂轮、切割片性能优良。     

TMP选择丙烯醚化及PE气干型改性

本文研究三羟甲基丙烷单烯丙醚、双烯丙醚的合成方法及其在不饱和聚酯气干型改性应用。当选择５％摩尔量的四丁基溴化铵作相转移催化剂，５０％ＮａＯＨ，反应温度９００１７０，无溶剂的条件理，产物含２１．３％ＭＡＴＭＰ、７３．８％ＤＡＴＭＰ和４．９％三羟甲基丙烷三烯丙醚，总收率为８４．５％。     

Dextran-modified iron oxide nanoparticles

Dextran-modified iron oxide nanoparticles were prepared by precipitation of Fe（Ⅱ） and Fe（Ⅲ） salts with ammonium hydroxide by two methods. Iron oxide was precipitated either in the presence of dextran solution, or the dextran solution was added after precipitation. In the second method, the iron oxide particle size and size distribution could be controlled depending on the concentration of dextran in the solution. The nanoparticles were characterized by size-exclusion chromatography, transmission electron microscopy and dynamic light scattering. Optimal conditions for preparation of stable iron oxide colloid particles were determined, The dextran/iron oxide ratio 0-0,16 used in precipitation of iron salts can be recommended for synthesis of nanoparticles suitable for biomedical applications, as the colloid does not contain excess dextran and does not coagulate.     

Hydrogenation Properties of Zr Films Under Various Conditions of Hydrogen Plasma

The hydrogenation properties of Zr samples with and without an Ni overlayer under various plasma conditions were investigated by means of non-Rutherford backscattering and elastic recoil detection analysis.The theoretical maximum hydrogen capacity,66.7 at%,could be achieved at a hydrogen absolute pressure of-2Pa and a substrate temperature of-393K for a plasma irradiation of only 10min;this was significantly greater than that for gas hydrogenation under the same hydrogen pressure and substrate temperature.It was also found that the C and O contamination on the sample surface strongly influences the hydrogenation,and that the maximum equilibrium hydrogen content drops dramatically with the increasing total contamination.In addition,the influence of the Ni overlayer on the plasma hydrogenation is discussed.     

CdS改性TiO2光催化剂的制备及结构

在半导体光催化剂中，TiO2具有光催化活性高、无毒和抗光腐蚀性好等优点，但纯TiO2光催化剂直接利用太阳光进行光催化氧化的效率较低，而利用贵金属元素和稀土元素等在TiO2中进行掺杂改性时，改性光催化反应必须在高压汞灯或紫外灯下进行，不符合节能原则。