Direct Transformation of Arenols Based on C—O Activation

In the view of substrate availability, atomic efficiency and cost, directly using arenols as coupling partners in cross‐coupling, would be one of the most attractive goals. Up to date, many efforts have been made to activate the C—O bond of phenols with different strategies, for example, through in‐situ formed intermediates, through a catalytic reductive dearomatization‐condensation‐rearomatization sequence or catalytic deoxygenation. In this review, we summarized recent advances in cross‐couplings of arenols as the electrophiles via C—O activation.     

基于两层均匀媒质的GPEN SAR地下目标成像方法及其性能分析

地表穿透合成孔径雷达(Ground PENetration SAR,GPEN SAR)为了探测掩埋在地下的目标,通常工作在多层媒质的环境中。传统成像模型是建立在同一均匀媒质的假设上,不再适合于GPEN SAR的实际情况。本文首先建立了两层分区均匀媒质中的成像模型,然后利用后向投影(BP)算法定量分析了成像几何参数、土壤参数等对成像的影响,进而提出了一种修正的后向投影(MBP)算法。MBP算法不仅能够校正两层分区均匀媒质对成像定位的影响,还能估计目标的掩埋深度,提供目标三维位置坐标。仿真结果验证了MBP算法在不同信噪比环境下,对多目标的三维定位精度能满足实际的需要。     

雷达电子战自适应捷变频对抗技术研究

介绍了雷达自适应变频抗干扰技术,分析了与之相对应的干扰技术,并对雷达自适应变频对抗效果度量问题进行了研究。     

ANALYSIS OF THE SCATTERING OF RIVET ON AIRCRAFT

This letter investigates the scattering characteristic of the rivets on aircraft.The electric Field Integral Equation (EFIE)is used with the moment to calculate the current distribution on the surface of the rivet.With the application of Gaussian integral corresponding triangular cell,the time to fill the Z matrix is greatly reduced.Finally,the RCS of a type of rivet on aircraft is analyzed.     

平面近场测试系统在天线测试和诊断中的应用

介绍了天线近场测量的基本原理和HD-1型平面近场测试系统,并对近场测量在实际天线测试中的应用情况、发展方向和应用前景等作了简单的描述。     

Algorithms for flattened Gaussian beams passing through apertured and unapertured paraxial ABCD optical systems

The propagation property of flattened Gaussian beams (FGBs) is studied based on the Collins formula, and analytical propagation equations for FGBs with and without an aperture are derived. It is shown that the closed-form expressions for the FGB of order N passing through paraxial ABCD optical systems without an aperture can be written as the combinations of Confluent Hyper-geometric Functions, and that the analytical equations for the FGB of order N passing through apertured paraxial ABCD optical systems may involve Error Functions. The proposed algorithms for the considered beams can save computing time, provide intuitive physical insights, and help to design optical systems. Our results are confirmed and illustrated with numerical examples.     

A highly selective solid phase extraction sorbent for pre-concentration of sameridine made by molecular imprinting

Summary A novel approach to solid phase extraction, based on the use of a highly selective molecularly imprinted polymer, is presented. The versatility of this type of sorbent for solid phase extraction was demonstrated in a model batch-wise pre-concentration of sameridine prior to gas chromatography. Problems associated with leakage of remaining imprint molecules during the desorption phase could be eliminated by the use of a close structural analogue of sameridine as the imprint species. It was found that a major benefit of the imprinted polymer was its specificity, which lead to distinctly cleaner chromatographic traces and ability to improve sensitivity by extracting sameridine from larger sample volumes.     

Alkenylidenes in Organic Synthesis

Alkenylidenes R₂C?C: (= alkylidene carbenes) undergo regio- and stereoselective intramolecular C? H insertion reactions that are excellently suited for the synthesis of cyclopentenes. The 1, 2-shifts occurring with R?H and R?Ar are useful for the preparation of alkynes. Alkenylidenes are efficiently generated from carbonyl compounds by diazomethylation, from vinyl halides by α-elimination, from alkynyliodonium salts by addition of nucleophiles, and from alkynes by retro-1, 2-shifts. Specific applications of the various methods, particularly in the synthesis of natural products, are discussed.     

裂解气相色谱质谱法研究增塑剂邻苯二甲酸二甲酯的热降解机理

用裂解气相色谱-质谱联用方法研究了橡胶产品中使用的增塑剂邻苯二甲酸二甲酯(DMP)在不同温度条件下的热裂解行为.对不同温度条件下裂解产物的分析表明,在初始阶段DMP的裂解产物主要为二氧化碳、苯、甲苯和苯甲酸甲酯.随着温度的升高苯甲酸甲酯进一步裂解成为分子质量更小的自由基,并发生稠环化反应形成更稳定的菲、蒽、间-联三苯、三亚苯等芳香族多环化合物.根据分析实验提供的裂解产物信息和有机物热裂解化学反应的原理对DMP的热裂解反应机理作了探讨,表明在废旧合成橡胶热裂解回收过程中,增塑剂DMP的高温裂解会产生多环芳烃污染物.应选择合适裂解工艺和裂解温度,以减少对环境的污染.     

平面波谱法分析电磁波在管道中的传播

通过分析电磁波从管道开口耦合进入管道的绕射机理及场在腔体内的射线特征，将进入管道的绕射场展开为平面波谱，利用平面波在自由空间的传播特性分析了电磁波沿管道的传输和反射特征。通过算例验证了该算法的有效性。