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1.
2.
Through improved synthesis process, resistance reduction effect of (K0.5Bi0.5)TiO3 (KBT) doping in Y–Mn co-doped BaTiO3 (BT) lead free ceramics was investigated. By different doping methods (doping K2O, Bi2O3 and TiO2 or synthesized KBT), medium Curie temperature (around 130 °C) lead free BT ceramics were obtained with ultra-low resistivity (13.84 Ωcm) with a temperature maintaining process at 700 °C. In this contribution, effect of sintering process and doping methods is discussed in detail. 相似文献
3.
Three N-heteroleptic Pt(II) complexes, [Pt(C^C)(O^O)] [O^O = acetylacetonate, C^C = 1-phenyl-1,2,4-triazol-5-ylidene (1), C^C = 4-phenyl-1,2,4-triazol-5-ylidene (2), C^C = 2-phenylpyrazine (3)] have been investigated with density functional theory (DFT) and time-dependent density functional theory (TDDFT). The radiative decay rate constants of complexes 1–3 have been discussed with the oscillator strength (fn), the strength of spin–orbit coupling (SOC) interaction between the lowest energy triplet excited state (T1) and singlet excited states (Sn), and the energy gaps between E(T1) and E(Sn). To illustrate the nonradiative decay processes, the transition states between triplet metal-centered (3MC) and T1 states have been optimized and were verified with the calculations of vibrational frequencies and intrinsic reaction coordinate (IRC). In addition, the minimum energy crossing points (MECPs) between 3MC and ground states (S0) were optimized. At last, the potential energy curves relevant to the nonradiative decay pathways are simulated. The results show that complex 3 has the biggest photoluminescence quantum yield because the complex 3 has the biggest radiative decay rate constant and the smallest nonradiative decay rate constant in complexes 1–3. 相似文献
4.
Dr. Liat Avram Dr. Václav Havel Ronit Shusterman-Krush Dr. Mark A. Iron Dr. Moritz Zaiss Prof. Vladimír Šindelář Dr. Amnon Bar-Shir 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(7):1687-1690
The accumulated knowledge regarding molecular architectures is based on established, reliable, and accessible analytical tools that provide robust structural and functional information on assemblies. However, both the dynamicity and low population of noncovalently interacting moieties within studied molecular systems limit the efficiency and accuracy of traditional methods. Herein, the use of a saturation transfer-based NMR approach to study the dynamic binding characteristics of an anion to a series of synthetic receptors derived from bambusuril macrocycles is demonstrated. The exchange rates of BF4− are mediated by the side chains on the receptor (100 s−1<kex<5000 s−1), which play a critical role in receptor-anion binding dynamics. The signal amplification obtained with this approach allows for the identification of different types of intermolecular interactions between the receptor and the anion, something that could not have been detected by techniques hitherto used to study molecular assemblies. These findings, which are supported by a computational molecular dynamic study, demonstrate the uniqueness and added value of this NMR method. 相似文献
5.
Yingchun Wu Haipeng Li Xuecheng Wu Gérard Gréhan Lutz Mädler Cyril Crua 《Proceedings of the Combustion Institute》2019,37(3):3211-3218
Droplet evaporation characterization, although of great significance, is still challenging. The recently developed phase rainbow refractometry (PRR) is proposed as an approach to measuring the droplet temperature, size as well as evaporation rate simultaneously, and is applied to a single flowing n-heptane droplet produced by a droplet-on-demand generator. The changes of droplet temperature and evaporation rate after a transient spark heating are reflected in the time-resolved PRR image. Results show that droplet evaporation rate increases with temperature, from ?1.28 m2/s at atmospheric 293 K to a range of (?1.5, ?8) m2/s when heated to (294, 315) K, agreeing well with the Maxwell and Stefan–Fuchs model predictions. Uncertainty analysis suggests that the main source is the indeterminate gradient inside droplet, resulting in an underestimation of droplet temperature and evaporation rate. With the demonstration on simultaneous measurements of droplet refractive index as well as droplet transient and local evaporation rate in this work, PRR is a promising tool to investigate single droplet evaporation in real engine conditions. 相似文献
6.
Kai Xu Zhenchang Tang Yan Zhang Wanshu Li Haiou Li Lihui Wang Liming Liu Honghang Wang Feng Chi Xiaowen Zhang 《Current Applied Physics》2019,19(10):1076-1081
Germanium dioxide (GeO2) aqueous solutions are facilely prepared and the corresponding anode buffer layers (ABLs) with solution process are demonstrated. Atomic force microscopy, X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy measurements show that solution-processed GeO2 behaves superior film morphology and enhanced work function. Using GeO2 as ABL of organic light-emitting diodes (OLEDs), the visible device with tris(8-hydroxy-quinolinato)aluminium as emitter gives maximum luminous efficiency of 6.5 cd/A and power efficiency of 3.5 lm/W, the ultraviolet device with 3-(4-biphenyl)-4-phenyl-5-tert-butylphenyl-1,2,4-triazole as emitter exhibits short-wavelength emission with peak of 376 nm, full-width at half-maximum of 42 nm, maximum radiance of 3.36 mW/cm2 and external quantum efficiency of 1.5%. The performances are almost comparable to the counterparts with poly (3,4-ethylenedioxythiophene):poly (styrenesulfonate) as ABL. The current, impedance, phase and capacitance as a function of voltage characteristics elucidate that the GeO2 ABL formed from appropriate concentration of GeO2 aqueous solution favors hole injection enhancement and accordingly promoting device performance. 相似文献
7.
Ben-Jye Chang 《Telecommunication Systems》2006,33(4):333-352
3G Wideband CDMA systems adopt the Orthogonal Variable Spreading Factor code tree as the channelization codes management for
achieving high data rate transmission in personal multimedia communications. It assigns a single channelization code for each
accepted connection. Nevertheless, it wastes the system capacity when the required rate is not powers of two of the basic
rate. One good solution is to assign multiple codes for each accepted connection but it causes two inevitable drawbacks: long
handoff delay and new call setup delay due to high complexity of processing with multiple channelization codes, and high cost
of using more number of rake combiners. Especially, long handoff delay may result in more call dropping probability and higher
Grade of Service, which will degrade significantly the utilization and revenue of the 3G cellular systems. Therefore, we propose
herein an adaptive efficient codes determination algorithm based on the Markov Decision Process analysis approach to reduce
the waste rate and reassignments significantly while providing fast handoff. Numerical results demonstrate that the proposed
approach yields several advantages, including the lowest GOS, the least waste rate, and the least number of reassignments.
Meanwhile, the optimal number of rake combiners is also analyzed in this paper.
This research was supported in part by the National Science Council of Taiwan, ROC, under contract NSC-93-2213-E-324-018. 相似文献
8.
With the proliferation of mobile computing technologies, location based services have been identified as one of the most promising
target application. We classify mobile information service domains based on feature characteristics of the information sources
and different patterns of mobile information access. By carefully examining the service requirements, we identify the dynamic
data management problem that must be addressed for effective location based services in mobile environments. We then devise
a general architecture and cost model for servicing both location independent and location dependent data. Based on the architecture
and cost model, we propose a set of dynamic data management strategies that employs judicious caching, proactive server pushing
and neighborhood replication to reduce service cost and improve response time under changing user mobility and access patterns.
Detail behavior analysis helps us in precisely capturing when and how to apply these strategies. Simulation results suggest
that different strategies are effective for different types of data in response to different patterns of movement and information
access.
Shiow-yang Wu is an associate professor of the Department of Computer Science and Information Engineering at National Dong Hwa University,
Hualien, Taiwan, R.O.C. He received the BS and MS degrees in computer engineering from National Chiao Tung University, Hsinchu,
Taiwan, ROC, and the PhD degree in computer science from the University of Texas at Austin in 1984, 1986, and 1995, respectively.
His research interests include data/knowledge bases, mobile computing, distributed processing, intelligence information systems,
and electronic commerce.
Kun-Ta Wu was born in Taipei, Taiwan, R.O.C., in 1976. He received the B.S. degree in computer science from Soochow University, Taipei,
Taiwan, R.O.C., in 1999 and the M.S. degree in computer science and information engineering from National Dong Hwa University,
Hualien, Taiwan, R.O.C., in 2001.
Currently, he is an Assistant Researcher in the Domestic Division at Science and Technology Information Center, National Science
Council, R.O.C., as a member of Information Gathering and Analysis Group of National Information and Communication Security
Taskforce. His research interests include mobile computing, wireless network and information security. 相似文献
9.
表面贴装工艺流程的关键工序之一就是焊膏印刷,其工艺控制的好坏直接影响着装配的线路板的质量。通过对印刷工艺参数的分析,利用试验设计的方法来找出关键工艺参数,并加以优化设定,从而为控制工序参数奠定基础。 相似文献
10.