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排序方式: 共有129条查询结果,搜索用时 640 毫秒
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Ashraf Bastawros Abhijit Chandra Yongjin Guo Bo Yan 《Journal of Electronic Materials》2002,31(10):1022-1031
The role of a porous pad in controlling material-removal rate (MRR) during the chemical-mechanical planarization (CMP) process
has been studied numerically. The numerical results are used to develop a phenomenological model that correlates the forces
on each individual abrasive particle to the applied nominal pressure. The model provides a physical explanation for the experimentally
observed domains of pressure-dependent MRR, where the pad deformation controls the load sharing between active-abrasive particles
and direct pad-wafer contact. The predicted correlations between MRR and slurry characteristics, i.e., particle size and concentration,
are in agreement with experimentally measured trends reported by Ouma1 and Izumitani.2 相似文献
3.
Yi Chen Deng-Gao Chen Yi-An Chen Cheng-Ham Wu Kai-Hsin Chang Fan-Yi Meng Meng-Chi Chen Jia-An Lin Chun-Ying Huang Jianhua Su He Tian Prof. Pi-Tai Chou 《Chemistry (Weinheim an der Bergstrasse, Germany)》2019,25(72):16755-16764
With the aim of generalizing the structure–properties relationship of bending heterocyclic molecules that undergo prominent photoinduced structural planarization (PISP), a series of new dihydrodibenzo[ac]phenazine derivatives in which one nitrogen atom is replaced by oxygen ( PNO ), sulfur ( PNS ), selenium ( PNSe ), or dimethylmethanediyl ( PNC ) was strategically designed and synthesized. Compounds PNO , PNS , and PNSe have significantly nonplanar geometries in the ground state, which undergo PISP to give a planarlike conformer and hence a large emission Stokes shift. A combination of femtosecond early relaxation dynamics and computational approaches established an R*→I* (intermediate)→P* sequential kinetic pattern for PNS and PNSe , whereas PNO undergoes R*→P* one-step kinetics. The polarization ability of the substituted heteroatoms, which is in the order O<S<Se, correlates with their increase in π conjugation, and hence the Stokes shift of the emission is in the order PNO < PNS < PNSe . Compound PNSe with the largest PISP barrier was shown to be a highly sensitive viscosity probe. Further evidence for heteroatom-harnessing PISP is given by PNC , in which the dimethylmethanediyl substituent lacks lone pair electrons for π extension, showing the normal emission of the bent structure. The results led to the conclusion that PISP is ubiquitous in dihydrodibenzo[ac]phenazines, for which the driving force is elongation of the π delocalization to gain stabilization in the excited state. 相似文献
4.
针对不合腐蚀抑制剂苯并三氮唑(BTA)的碱性铜粗抛液,通过对3英寸(1英寸=2.54 cm)铜片上的动态抛光速率和静态腐蚀速率的研究来模拟评估氧化剂对晶圆表面平坦化的影响.在12英寸铜镀膜片和TM1图形片上分别研究氧化剂体积分数对表面平坦化的影响.实验结果表明:动态抛光速率和静态腐蚀速率均随着氧化剂体积分数的增加先逐渐增大,达到最大值,然后下降,趋于平缓.片内非均匀性和剩余高低差均随H2O2体积分数的增加,先呈下降趋势,后缓慢上升.当氧化剂体积分数为3%时,动态去除速率(vRR)为398.988 nm/min,静态腐蚀速率vER为6.834 nm/min,vRR/vER比值最大,片内非均匀性最小为3.82%,台阶高低差最小为104.6 nm/min,此时晶圆片有较好的平坦化效果. 相似文献
5.
Guangchen Sun Yu-Chen Wei Dr. Zhiyun Zhang Jia-An Lin Zong-Ying Liu Dr. Wei Chen Prof. Jianhua Su Prof. Pi-Tai Chou Prof. He Tian 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(42):18770-18777
Herein, we introduce the cyclic 8π-electron (C8π) molecule N,N′-diaryl-dihydrodibenzo[a,c]phenazine ( DPAC ) as a dual-functional donor to establish a series of new donor–linker–acceptor (D–L–A) dyads DLA1 – DLA5 . The excited-state bent-to-planar dynamics of DPAC regulate the energy gap of the donor, while the acceptors A1 – A5 are endowed with different energy gaps and HOMO/LUMO levels. As a result, the rate and efficiency of the excited-state electron transfer vs. energy transfer can be finely harnessed, which is verified via steady-state spectroscopy and time-resolved emission measurements. This comprehensive approach demonstrates, for the first time, the manifold of excited-state properties governed by bifunctional donor-based D–L–A dyads, including bent-to-planar, photoinduced electron transfer (PET) from excited donor to acceptor (oxidative-PET), fluorescence resonance energy transfer (FRET), bent-to-planar followed by electron transfer (PFET), and PET from donor to excited acceptor (reductive-PET). 相似文献
6.
Ryo Kimura Hikaru Kuramochi Pengpeng Liu Takuya Yamakado Atsuhiro Osuka Tahei Tahara Shohei Saito 《Angewandte Chemie (International ed. in English)》2020,59(38):16430-16435
Flapping fluorophores (FLAP) with a flexible 8π ring are rapidly gaining attention as a versatile photofunctional system. Here we report a highly photostable “flapping peryleneimide” with an unprecedented fluorogenic mechanism based on a bent‐to‐planar conformational change in the S1 excited state. The S1 planarization induces an electronic configurational switch, almost quenching the inherent fluorescence (FL) of the peryleneimide moieties. However, the FL quantum yield is remarkably improved with a prolonged lifetime upon a slight environmental change. This fluorogenic function is realized by sensitive π‐conjugation design, as a more π‐expanded analogue does not show the planarization dynamics. With strong visible‐light absorption, the FL lifetime response synchronized with the flexible flapping motion is useful for the latest optical techniques such as FL lifetime imaging microscopy (FLIM). 相似文献
7.
8.
Chemical mechanical planarization(CMP) of amorphous Ge2Sb2Te5(a-GST) is investigated using two typical soft pads(politex REG and AT) in acidic slurry.After CMP,it is found that the removal rate(RR) of a-GST increases with an increase of runs number for both pads.However,it achieves the higher RR and better surface quality of a-GST for an AT pad.The in-situ sheet resistance(Rs) measure shows the higher Rs of a-GST polishing can be gained after CMP using both pads and the high Rs is beneficial to lower the reset current for the PCM cells. In order to find the root cause of the different RR of a-GST polishing with different pads,the surface morphology and characteristics of both new and used pads are analyzed,it shows that the AT pad has smaller porosity size and more pore counts than that of the REG pad,and thus the AT pad can transport more fresh slurry to the reaction interface between the pad and a-GST,which results in the high RR of a-GST due to enhanced chemical reaction. 相似文献
9.
10.
The evaluation methods of planarization capability of copper slurry are investigated.Planarization capability and material removal rate are the most essential properties of slurry.The goal of chemical mechanical polishing(CMP) is to achieve a flat and smooth surface.Planarization capability is the elimination capability of the step height on the copper pattern wafer surface,and reflects the passivation capability of the slurry to a certain extent.Through analyzing the planarization mechanism of the CMP process and experimental results,the planarization capability of the slurry can be evaluated by the following five aspects:pressure sensitivity,temperature sensitivity,static etch rate,planarization efficiency and saturation properties. 相似文献