Chemical bonding in representative astrophysically relevant neutral,cation, and anion HCnH chains

Most existing studies assign a polyynic and cumulenic character of chemical bonding in carbon-based chains relying on values of the bond lengths. Building on our recent work, in this paper we add further evidence on the limitations of such an analysis and demonstrate the significant insight gained via natural bond analysis. Presently reported results include atomic charges, natural bond order and valence indices obtained from ab initio computations for representative members of the astrophysically relevant neutral and charged HC_2k/2k+1H chain family. They unravel a series of counter-intuitive aspects and/or help naive intuition in properly understanding microscopic processes, e.g., electron removal from or electron attachment to a neutral chain. Demonstrating that the Wiberg indices adequately quantify the chemical bonding structure of the HC_2k/2k+1H chains—while the often heavily advertised Mayer indices do not—represents an important message conveyed by the present study.     

Simultaneous quantification of leukotrienes and hydroxyeicosatetraenoic acids in cell culture medium using liquid chromatography/tandem mass spectrometry

Leukotrienes (LTs) and hydroxyeicosatetraenoic acids (HETEs) are important bioactive lipid mediators that participate in various pathophysiological processes. To advance understanding of the mechanisms that regulate these mediators in physiological and pathological processes, an analytical method using liquid chromatography/tandem mass spectrometry for the simultaneous quantification of LTB₄, LTC₄, LTD₄, LTE₄, 5‐HETE_, 8‐HETE, 12‐HETE and 15‐HETE in cell culture media was developed. A Supel?‐Select HLB solid‐phase extraction cartridge was used for sample preparation. The compounds were separated on a C₁₈ column using gradient elution with acetonitrile–water–formic acid (20:80:0.1, v/v/v) and acetonitrile–formic acid (100:0.1, v/v). The calibration curves of LTB₄, LTD₄, LTE₄ and HETEs were linear in the range of 0.025–10 ng/mL, and the calibration curve of LTC₄ was linear in the range of 0.25–10 ng/mL. Validation assessment showed that the method was highly reliable with good accuracy and precision. The stability of LTs and HETEs was also investigated. Using the developed method, we measured LTs and HETEs in the culture supernatant of the human mast cell line HMC‐1. The present method could facilitate investigations of the mechanisms that regulate the production, release and signaling of LTs and HETEs. Copyright © 2014 John Wiley & Sons, Ltd.     

Stereo matching cost computation based on nonsubsampled contourlet transform

A new matching cost computation method based on nonsubsampled contourlet transform (NSCT) for stereo image matching is proposed in this paper. Firstly, stereo image is decomposed into high frequency sub-band images at different scales and along different directions by NSCT. Secondly, by utilizing coefficients in high frequency domain and grayscales in RGB color space, the computation model of weighted matching cost between two pixels is designed based on the gestalt laws. Lastly, two types of experiments are carried out with standard stereopairs in the Middlebury benchmark. One of the experiments is to confirm optimum values of NSCT scale and direction parameters, and the other is to compare proposed matching cost with nine known matching costs. Experimental results show that the optimum values of scale and direction parameters are respectively 2 and 3, and the matching accuracy of the proposed matching cost is twice higher than that of traditional NCC cost.     

人工免疫原理在网络入侵检测系统中的研究

文章分析了人工免疫系统的原理,简单建立了一种基于否定选择算法的网络入侵检测系统,引入了一种用于异常事件识别的r-字符块匹配规则,并对规则存在的漏洞进行了分析。     

以一种新的距离度量作为反馈的相关跟踪方法

基于相关的模板匹配方法在图像跟踪中得到了广泛的应用,但是这种方法的主要缺点是对图像噪声非常敏感,而且由这种方法得出的相关曲面比较平坦。为了有效抑制噪声和局部遮挡对图像的影响,提出用鲁棒统计中的一个值代替相关值作为距离度量。它不是计算两幅图像的对应像素差值,而是计算两幅图像中差别不大的对应像素对的个数。实验证明这样得到的曲面相对　　收稿日期:2003 08 31;　修订日期:2003 10 28作者简介:张桂林(1944 ),男,天津人,教授,博士生导师,主要研究方向为自动识别、人体生物统计特征识别、图像处理算法与系统性能评估等。　　　　　　　要尖锐得多。当上述的距离度量应用于跟踪过程中时,模板的合理更新对跟踪非常重要。基于上述的距离度量方法,提出了一种新的模板更新策略。利用两幅图像中近似像素在整修匹配模板像素中所占的比例大小决定加权系数。这种加权策略可以自适应地根据图像序列的变化选择更新相关模板,同时在一定程度上减小模板漂移的危险。     

238C防盗报警系统的改进

漯河中波台自安装238C防盗报警系统以来,多次出现误报现象,严重影响了发射及其他工作的正常进行。首先对该系统的工作原理进行了简单介绍,然后对误报故障现象进行了分析、处理,并改进了电路设计中存在的不足。改进后的运行数据表明,系统误报率明显下降,达到了预期的目的。最后,对本系统的设计提出了进一步完善的建议。     

Nonlinear Propagation of Coupling Optical Pulse under Compton Scattering in Laser Medium

After considering Kerr nonlinear effect,group velocity dispersion of host and gain distribution of active particle in laser amplifying medium,a basic equation describing propagation of the coupling optical pulse under the multi-photon nonlinear Compton scattering in the laser amplifying medium has been deduced. Besides,the profile and power spectrum of a picosecond-level super-Gaussian coupling pulse in the laser amplifying medium have been discussed when its central frequency coincides with the gain peak frequency of the laser amplifying medium.     

Scheduling Algorithms for Packet-Oriented MAC Protocols in Wireless Multimedia Systems

Future generation wireless multimediacommunications will require efficient Medium AccessControl (MAC) protocols able to guarantee suitable Qualityof Service (QoS) levels for different traffic classes whileachieving a high utilization of radio resources. This paperproposes a new scheduling technique to be adopted at the MAClevel in wireless access systems, named Dynamic Scheduling-Time DivisionDuplexing (DS-TDD), that efficiently managesvideo, voice, Web and background traffics. A theoretical approachis proposed in this paper to evaluate the DS-TDD performance withvoice and Web traffics. Simulation results have permitted tohighlight the following promising characteristics of the DS-TDDscheme: (i) a high capacity of real-time traffics isattained with a QoS insensitive to Web and background trafficloads; (ii) a high throughput can be guaranteed whilepreserving the QoS levels of the different traffic classes;(iii) heavier downlink traffic loads do not modify the QoSof uplink traffics. Finally, extensive comparisons with differentscheduling schemes proposed in the literature have permitted tohighlight the better performanceof DS-TDD.     

A New Approach for Built‐in Self‐Test of 4.5 to 5.5 GHz Low‐Noise Amplifiers

This paper presents a low‐cost RF parameter estimation technique using a new RF built‐in self‐test (BIST) circuit and efficient DC measurement for 4.5 to 5.5 GHz low noise amplifiers (LNAs). The BIST circuit measures gain, noise figure, input impedance, and input return loss for an LNA. The BIST circuit is designed using 0.18 μm SiGe technology. The test technique utilizes input impedance matching and output DC voltage measurements. The technique is simple and inexpensive.