Near‐Infrared (NIR) Organic Light‐Emitting Diodes (OLEDs): Challenges and Opportunities

The rapid development of the science and technology of organic semiconductors has already led to mass application of organic light‐emitting diodes (OLEDs) in television monitors of outstanding quality as well as in a large variety of smaller displays found in smartphones, tablets, and other gadgets, while introduction of the technology to the illumination sector is imminent. Notably, the requirements of all such applications for emission in the visible range of the electromagnetic spectrum are well tuned to the optical and electronic properties of typical organic semiconductors, thereby representing relatively “low‐hanging fruits,” in terms of material development and exploitation. However, the question arises as to whether developing materials suited for efficient near‐infrared (NIR, 700–1000 nm) emission is possible, and, crucially, desirable to enable new classes of applications spanning from through‐space, short‐range communications to biomedical sensors, night vision, and more generally security applications to name but a few. Here, the major fundamental hurdles to be overcome to achieve efficient NIR emission from organic π‐conjugated systems are discussed, recent progress is reviewed, and an outlook for further development of both materials and applications is provided.     

复杂目标的近场散射特性分析

详细分析了目标散射随距离而变化的特征，根据散射特点的不同将目标的散射特性分为远场散射、准近场散射、近场散射等三种情况，并对三种情况下的描述的手段进行了讨论，提出在近场条件下，用反射功率比的概念直接对散射目标的特性进行描述。     

冲击噪声背景下的近场源二维参数估计方法

本文针对背景噪声为冲击噪声的情况,提出了一种新的近场源二维参数估计方法.本方法利用协变异(或协变异系数)构造矩阵,并通过求根的方法估计近场源的方向角和距离参数.该算法可以抑制冲击噪声对估计性能的影响,同时具有无需谱峰搜索的优点.仿真实验证明了该算法的有效性.     

Kinetic study of the crosslinking reaction of 1,2‐polybutadiene with dicumyl peroxide in the absence and presence of vinyl acetate

The crosslinking reaction of 1,2-polybutadiene (1,2-PB) with dicumyl peroxide (DCPO) in dioxane was kinetically studied by means of Fourier transform near-infrared spectroscopy (FTNIR). The crosslinking reaction was followed in situ by the monitoring of the disappearance of the pendant vinyl group of 1,2-PB with FTNIR. The initial disappearance rate (R₀) of the vinyl group was expressed by R₀ = k[DCPO]^0.8[vinyl group]^−0.2 (120 °C). The overall activation energy of the reaction was estimated to be 38.3 kcal/mol. The unusual rate equation was explained in terms of the polymerization of the pendant vinyl group as an allyl monomer involving degradative chain transfer to the monomer. The reaction mixture involved electron spin resonance (ESR)-observable polymer radicals, of which the concentration rapidly increased with time owing to a progress of crosslinking after an induction period of 200 min. The crosslinking reaction of 1,2-PB with DCPO was also examined in the presence of vinyl acetate (VAc), which was regarded as a copolymerization of the vinyl group with VAc. The vinyl group of 1,2-PB was found to show a reactivity much higher than 1-octene and 3-methyl-1-hexene as model compounds in the copolymerization with VAc. This unexpectedly high reactivity of the vinyl group suggested that an intramolecular polymerization process proceeds between the pendant vinyl groups located on the same polymer chain, possibly leading to the formation of block-like polymer. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4437–4447, 2004     

Electromagnetic energy flow near nanoparticles—I: single spheres

The electromagnetic (EM) energy flow near single spheres is investigated by applying Mie theory. From the patterns of the energy flow, the absorption and the scattering of light can be understood in the microscopic point of view. In the absorption profiles of metallic particles, most absorbed energy is consumed on the surface of the particles, which indicates that the resonance of surface plasmon is different from that of the bulk plasmon. Two mechanisms to enhanced local EM field are also distinguished. One is the surface plasmon resonance, and another one is the intensified energy flow.     

Near field imaging in microwave regime using double layer split-ring resonator based metamaterial

A planar metamaterial structure consisting of two layers of split-ring resonator (SRR) arrays is demonstrated to form the image of a point source with subwavelength resolution. The source frequency is swept through the resonance gap of the metamaterial layers and the lateral field intensity distribution is recorded on the transmission side of the metamaterial. When the source is tuned to the resonance frequency of SRRs, the metamaterial acts as a high permeability medium and a distinct image with subwavelength resolution in the lateral direction is obtained. Increasing the distance between the individual SRR layers reduces the interlayer coupling, and the intensity and spatial resolution of the image decrease rapidly.     

The completion of the classification of the regular near octagons with thick quads

Brouwer and Wilbrink [3] showed the nonexistence of regular near octagons whose parameters s, t₂, t₃ and t satisfy s ≥ 2, t₂ ≥ 2 and t₃ ≠ t₂(t₂+1). Later an arithmetical error was discovered in the proof. Because of this error, the existence problem was still open for the near octagons corresponding with certain values of s, t₂ and t₃. In the present paper, we will also show the nonexistence of these remaining regular near octagons. MSC2000 05B25, 05E30, 51E12 Postdoctoral Fellow of the Research Foundation - Flanders     

The valuations of the near hexagons related to the Witt designs S(5,6,12) and S(5,8,24)

Valuations of dense near polygons were introduced in 16 . In the present paper, we classify all valuations of the near hexagons ??₁ and ??₂, which are related to the respective Witt designs S(5,6,12) and S(5,8,24). Using these classifications, we prove that if a dense near polygon S contains a hex H isomorphic to ??₁ or ??₂, then H is classical in S. We will use this result to determine all dense near octagons that contain a hex isomorphic to ??₁ or ??₂. As a by‐product, we obtain a purely geometrical proof for the nonexistence of regular near 2d‐gons, d ≥ 4, whose parameters s, t, t_i (0 ≤ i ≤ d) satisfy (s, t₂, t₃) = (2, 1, 11) or (2, 2, 14). The nonexistence of these regular near polygons can also be shown with the aid of eigenvalue techniques. © 2005 Wiley Periodicals, Inc. J Combin Designs 14: 214–228, 2006     

干扰抵消型多用户检测器性能分析

用模块化的方法描述了 ＳＩＣ、ＭＳＳＩＣ、ＰＩＣ和ＰＳＩＣ干扰抵消多用户检测算法，给出算法的实现结构图，并且在渐近有效性、抗远近效应、系统容量和实现复杂度诸方面进行了性能比较分析。分析表明需要进行功率排序的ＭＳＳＩＣ、ＰＳＩＣ和ＳＩＣ算法比ＰＩＣ算法具有更好的抗远近效应的性能，ＭＳＳＩＣ和 ＰＳＩＣ算法在渐近有效性和系统容量方面要显著强于ＳＩＣ和ＰＩＣ算法。     

改进的FD—TD法分析二维理想导体TM近区散射问题

本文针对一般ＦＤ－ＴＤ方法分析计算二维理想导体散射问题所遇到散射体边角处难以精确处理的缺点进行了改进。将边角处总场近似解析解直接引入ＦＤ－ＴＤ法差分公式，得到了有关修正系数，为了检验此方法的有效性，有无限长导体方柱为例分别用一般ＦＤ－ＴＤ法和本文的ＦＤ－ＴＤ方法进行了分析研究，并与ＭＯＭ法进行了比较，所得结果说明改进后的ＦＤ－ＴＤ方法对分析计算导体边角附近电流分布特性是较有效的。