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1.
Prof. Dr. Peter Hess 《Chemphyschem》2022,23(6):e202100880
In the periodic table the position of each atom follows the ‘aufbau’ principle of the individual electron shells. The resulting intrinsic periodicity of atomic properties determines the overall behavior of atoms in two-dimensional (2D) bonding and structure formation. Insight into the type and strength of bonding is the key in the discovery of innovative 2D materials. The primary features of 2D bonding and the ensuing monolayer structures of the main-group II–VI elements result from the number of valence electrons and the change of atom size, which determine the type of hybridization. The results reveal the tight connection between strength of bonding and bond length in 2D networks. The predictive power of the periodic table reveals general rules of bonding, the bonding-structure relationship, and allows an assessment of published data of 2D materials. 相似文献
2.
Real-time multimedia applications have to use forward error correction (FEC) anderror concealment techniques to cope with
losses in today’s best-effort Internet. The efficiency of these solutions is known however to depend on the correlation between
losses in the media stream. In this paper we investigate how the packet size distribution affects the packet loss process,
that is, the distribution of the number of lost packets in a block, the related FEC performance and the average loss run length.
We present mathematical models for the loss process of the MMPP+M/D/1/K and the MMPP+M/M/1/K queues; we validate the models
via simulations, and compare the results to simulation results with an MPEG-4 coded video trace. We conclude that the deterministic
packet size distribution (PSD) not only results in lower stationary loss probability than the exponential one, but also gives
a less correlated loss process, both at a particular average link load and at a particular stationary loss probability as
seen by the media stream.Our results show that for applications that can only measure the packet loss probability, the effects
of the PSD on FEC performance are higher in access networks, where a single multimedia stream might affect the multiplexing
behavior. Our results show that the effects of the PSD on FEC performance are higher in access networks, where a single multimedia
stream might affect the multiplexing behavior and thus can improve the queuing performance by decreasing the variance of its
PSD. 相似文献
3.
The possibility of realizing SASE Free Election Laser in x-ray waveband with EM-wave wiggler is studied in this paper. SASE effect including saturation length, saturation power and nonlinear process is explored through a 3-D simulation code. A utilization of seed light from laser plasma x-ray is also analyzed, which demonstrates the feature of shortening the interaction length for saturation. The results show that sizeable output power of x-ray laser would be generated with a middle energy electron beam. 相似文献
4.
5.
本文报导了最近研制成功的用于提高国产氩离子激光器相干长度的相干扩展器。利用这种基于F-P理论的相干扩展器可以使国产氩离子激光器的相干长度由不足5cm一下提高到m的量级,功率损耗在25%~40%之间,有着很好的应用前景。 相似文献
6.
7.
During the course of our investigation of the electron transfer properties of some redox species through highly hydrophobic
long chain alkanethiol molecules on gold in aqueous and non-aqueous solvents, we obtained some intriguing results such as
unusually low interfacial capacitance, very high values of impedance and film resistance, all of which pointed to the possible
existence of a nanometer size interfacial gap between the hydrophobic monolayer and aqueous electrolyte. We explain this phenomenon
by a model for the alkanethiol monolayer—aqueous electrolyte interface, in which the extremely hydrophobic alkanethiol film
repels water molecules adjacent to it and in the process creates a shield between the monolayer film and water. This effectively
increases the overall thickness of the dielectric layer that is manifested as an abnormally low value of interfacial capacitance.
This behaviour is very much akin to the ‘drying transition’ proposed by Lum, Chandler and Weeks in their theory of length
scale dependent hydrophobicity. For small hydrophobic units consisting of apolar solutes, the water molecules can reorganize
around them without sacrificing their hydrogen bonds. Since for an extended hydrophobic unit, the existence of hydrogen bonded
water structure close to it is geometrically unfavourable, there is a net depletion of water molecules in the vicinity leading
to the possible creation of a hydrophobic interfacial gap. 相似文献
8.
9.
M/G/1非空竭服务休假排队系统随机分解的简化算法 总被引:2,自引:0,他引:2
本文根据M/G/1非空竭服务休假排队系统稳态队长随机分解的结构特征提出一种统一算法,该方法简洁高效,避免了再生循环方法繁杂的运算。运用该方法得出的结果与已知的用再生循环方法得出的结论一致。并且修正了Levy(1989)关于Bernoulli闸门服务休假排队系统随机分解的一个错误。 相似文献
10.