HART通信协议在汽油机速度测量和监控方面的应用

首先介绍了HART通信协议及他的优点，然后介绍了HART通信协议在汽油机测速方面的软件实现。该软件主要采用目前流行的VB编程语言。可设计出界面友好、功能强大的测量和监控软件。     

A Generalized Unpaired Electron Spin Density Equation and Organic Hyperconjugation Mechanism

A large class of stereochemcial and related interactions in organic chemistry are repulsive and others are attractive, but the relative orientation of two methyl groups and the amount of energy required to twist one relative to the other (the hindered rotation energy barriers), or the alignment of such a group with respect to a conjugated ring to which it is attached (widely attributed to a mechanism called “hyperconjugation”) are estimated to be small in compared with the total energy of the molecule. We used theories of both isotropic and anisotropic proton hyperfine interactions in the π‐electron systems developed in the early sixties. They are approximated by the magnetic dipole nteractions between each proton and an electron spin magnetization that is distributed in 2s and 2p Slater atomic orbitals center on carbon atoms. We have extended these theories to the non‐planar olefinic cation radicals, which are very important in biochemistry as well as in petroleum catalysis. A three dimensional electron spin density equation has been developed in this paper to handle some Jahn‐Teller vibronic molecules. The new electron spin density equation related the observed proton hyperfine splittings to the non‐planar structures of the open‐chain alkene cation radicals generated by radiolysis and various chemical oxidation methods. The spin densities and the conformational calculations based on valence bond theory and symmetry principles are compared with some more elaborated molecular orbital calculations in the literature. The localized valence bond approaches are better in accord with our experimental results. The anomalous line‐width effect of the four methyl groups observed in the 2,3‐dimethyl‐2‐butene cation radicals also confirmed the positive sign of the electron‐proton hyperfine constant of hyper‐conjugation mechanism. A methyl substituent attached to a conjugated molecule often behaves as if it formed part of the region of conjugation; the charge appears to flow from the methyl group into the π electron system and it may also give rise to an appreciable dipole moment. Methylation also gives rise to an appreciable dipole moment, and the resultant red shift of electronic absorption bands is of some importance in the design of dye molecules.     

利用串行口实现计算机对PLC的实时监控

本文采用可视化软件VB的串行通信控件,通过计算机串行口实现了计算机与西门子S7-200系列PLC间的串行数据传输,进而由VB的Timer控件实现了计算机与PLC的实时通信,最终达到计算机对PLC所连接设备工作状态的实时监控。     

Photocatalytic and antifouling properties of TiO2-based photocatalytic membranes

Photocatalysis has been extensively studied due to its potential ability to avoid the excessive use of chemical reagents and reduce the energy consumption by employing solar energy. Moreover, to alleviate the reduction in the membrane permeation selectivity, separation efficiency, and membrane service life caused by the emerging micro-pollutants and membrane fouling, membrane technology is often coupled with microbial, electrochemical, and catalytic processes. However, although physical/chemical cleaning and membrane module replacement can overcome the inherent limitations caused by membrane fouling and other membrane separation processes, high operating costs limit their practical applications. In this review, common preparation methods for TiO₂ photocatalytic membranes are described in detail, and the main approaches to enhancing their photocatalytic performance are discussed. More importantly, the mechanism of the TiO₂ photocatalytic membrane antifouling process is elucidated, and some applications of photocatalytic membranes in other areas are described. This review systematically outlines future research directions in the field of photocatalytic membrane modification, including metal and non-metal doping, fabrication of heterojunction structures, control over reaction conditions, increase in hydrophilicity, and increase in membrane porosity.     

Valence bond theoretical study for chemical reactivity

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基于VB与PCI-1712采集卡的电流监视系统设计与实现

在分析了目前船载雷达天线伺服系统电机电流监视中存在不足的基础上,提出了基于VB与PCI-1712采集卡的电机电流监视系统设计方案,详细说明了PCI-1712数据采集卡的主要驱动函数和特征,搭建了硬件平台并对监视系统的数据采集、数据处理、图形输出、故障报警、数据库、记录输出进行了详细的介绍.     

SolidWorks二次开发在CAE仿真分析中的应用

随着CAD/CAE技术的普及与结合,CAD/CAE一体化系统的开发越来越受到企业的欢迎。本文通过对SolidWorks二次开发的研究,提出了利用SolidWorks二次开发进行CAE自动仿真分析。系统借助VB语言首先通过CAD模块进行参数化建模,然后利用CAE模块进行仿真分析,将结果对比记录,最后通过优化模块对不符合要求的零部件进行重新设计分析,直到满足设计要求为止。     

Beyond labels: A review of the application of quantum dots as integrated components of assays, bioprobes, and biosensors utilizing optical transduction

A comprehensive review of the development of assays, bioprobes, and biosensors using quantum dots (QDs) as integrated components is presented. In contrast to a QD that is selectively introduced as a label, an integrated QD is one that is present in a system throughout a bioanalysis, and simultaneously has a role in transduction and as a scaffold for biorecognition. Through a diverse array of coatings and bioconjugation strategies, it is possible to use QDs as a scaffold for biorecognition events. The modulation of QD luminescence provides the opportunity for the transduction of these events via fluorescence resonance energy transfer (FRET), bioluminescence resonance energy transfer (BRET), charge transfer quenching, and electrochemiluminescence (ECL). An overview of the basic concepts and principles underlying the use of QDs with each of these transduction methods is provided, along with many examples of their application in biological sensing. The latter include: the detection of small molecules using enzyme-linked methods, or using aptamers as affinity probes; the detection of proteins via immunoassays or aptamers; nucleic acid hybridization assays; and assays for protease or nuclease activity. Strategies for multiplexed detection are highlighted among these examples. Although the majority of developments to date have been in vitro, QD-based methods for ex vivo biological sensing are emerging. Some special attention is given to the development of solid-phase assays, which offer certain advantages over their solution-phase counterparts.     

MIMO-OFDM系统的低复杂度递推信道跟踪算法

该文针对时变多径信道下的MIMO-OFDM系统,基于变分贝叶斯原理,提出了一种新的联合信号检测和信道跟踪的低复杂度半盲贝叶斯迭代接收机。针对该接收机,基于递推变分期望最大化(RVBEM)算法,提出了一种RVBEM信道跟踪算法。由于RVBEM算法需要进行矩阵求逆,因此以该算法为基础推导得到了一种时频域联合递推的低复杂度信道跟踪(TF-LCRVBEM)算法。TF-LCRVBEM算法不仅完全避免了矩阵求逆运算,还通过合理的近似使得算法只具有线性复杂度。分析和仿真表明,在时变多径信道下,所提迭代接收机具有远优于传统接收机和接近理想接收机的性能。