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J‐F. Masson Slaana Bundalo‐Perc Ana Delgado 《Journal of Polymer Science.Polymer Physics》2005,43(3):276-279
Differential scanning calorimetry (DSC) does not allow for easy determination of the glass‐transition temperature (Tg) of the polystyrene (PS) block in styrene–butadiene–styrene (SBS) block copolymers. Modulated DSC (MDSC), which deconvolutes the standard DSC signal into reversing and nonreversing signals, was used to determine the (Tg) of both the polybutadiene (PB) and PS blocks in SBS. The Tg of the PB block was sharp, at ?92 °C, but that for the PS blocks was extremely broad, from ?60 to 125 °C with a maximum at 68 °C because of blending with PB. PS blocks were found only to exist in a mixed PS–PB phase. This concurred with the results from dynamic mechanical analysis. Annealing did not allow for a segregation of the PS blocks into a pure phase, but allowed for the segregation of the mixed phase into two mixed phases, one that was PB‐rich and the other that was PS‐rich. It is concluded that three phases coexist in SBS: PB, PB‐rich, and PS‐rich phases. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 43: 276–279, 2005 相似文献
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通过数值求解一维瞬态受激布里渊散射(SBS)声光耦合波方程,从理论上分析了泵浦激光参数及光学材料参数对SBS过程发生阈值的影响。以SBS过程中建立起来的应力场抗拉(压)强度和散射场的反射率为判据,分析了激光脉宽及作用区域长度对激光超声破坏材料效果的影响,探讨了短脉冲激光(约ns)引起的激光超声对材料的破坏机理;讨论了通过参数配置有效遏制SBS过程激光超声对光学材料的破坏问题。 相似文献
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文章报道了利用双通放大结构进行受激布里渊散射(SBS)脉冲压缩,实验获得了近极限压缩的脉冲,压缩率近10倍。实验中同时观察到脉冲压缩中的相位跃变。相位跃变是受激背散射光与入射激光间的增益与损耗调制的结果。 相似文献
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磺化SBS薄膜的制备与表征 总被引:6,自引:3,他引:3
采用化学磺化法对SBS热塑性弹性体进行离子化,研究了不同磺化程度以及不同金属离子对磺化产物结构与性能的影响,发现离子化产物的动态模量、拉伸强度和伸长率均有明显提高,不同金属离子对离聚物性能影响不同。其中以Ni^2+中和的产物,离子基团间作用力强,产物力学性能最好。 相似文献
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The beam quality of a single-rod Nd: YAG laser with wavelength of 1.06 m was improved almost up to the diffraction limit by using a phase-conjugating mirror (PCM) based on stimulated Brillouin scattering (SBS) with acetone as the SBS medium. The new start cavity, which is the concave-convex cavity operating near the limit of stability in the g diagram, and the phase conjugation cavity of the SBS oscillator were designed. The thermal lens of the material with focal lengths of less than 140 m at pump powers of 60 J was compensated by the PCM. The laser is Q-switched by the nonlinear reflectivity of the PCM and the system works with an average repetition rate of about 5 kHz and single Q-switch pulse showed a width of 10 ns. It is demonstrated that if the start cavity is fit for SBS and the SBS phase conjugation mirror can be optimized, the beam quality of solid laser can be surely enhanced because of this technology of nonlinear optics. 相似文献
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对采用SBS调Q产生喇曼频移输出的激光器进行了理论分析,并对实验结果与染料调Q时的输出进行了对比,提出了改进该种激光器性能的方法。 相似文献