CDMA基带信号发生器设计与仿真

主要研究了CDMA蜂窝通信系统的工作原理，且以基于IS－95标准的前向链路为主。利用MATLAB软件建立了前向链路中各器件的模块，实现了CDMA基带信号发生器，并在时域及频内进行了测量。     

Synthesis and Characterization of ChiralLiquid Crystal CMPPCDP

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Study of air pollution particulates by X-ray photoelectron spectroscopy

Summary This paper discusses the application of X-ray photoelectron spectroscopy to the determination of the chemical composition of sulfur and nitrogen species in air pollution particulates. Core electron chemical shift measurements are augmented by the determination of relative concentrations and volatility of particulate species.

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Untersuchung von Verunreinigungsteilchen in der Luft durch Röntgenphotoelektronen-Spektroskopie

Zusammenfassung Die Anwendung der Röntgenphotoelektronen-Spektroskopie auf die Bestimmung der chemischen Zusammensetzung von Schwefel und Stickstoff enthaltenden Verunreinigungsteilchen in Luft wird diskutiert. Messungen der chemischen Verschiebung werden ergänzt durch die Bestimmung der relativen Konzentrationen und der Flüchtigkeit der Verbindungen.

Presented at the 6th Annual Symposium on Recent Advances in the Analytical Chemistry of Pollutants, April 21–23, 1976; Vienna, Austria.     

The Route of Alkylation of 5-Substituted 1,3,4-Thiadiazoline-2-thiones

The reaction of 5-anilino(toluidino-, morpholino)-1,3,4-thiadiazoline-2-thiones at 80°C with allyl bromide and benzyl chloride in alcohol, acetonitrile or DMF in the presence of KOH and also with phenoxymethyloxirane in alcohol in the absence of base gives the corresponding novel allyl-, benzyl-, and 2-hydroxy-3-phenoxypropyl products substituted at the exocyclic S atom. Alkylation of the indicated thiones with benzyl chloride at 150-153°C in DMF in the presence of KOH occurs similarly. Under these conditions, allyl bromide forms alkylation products at the endocyclic N(3) atom as a result of an SN thio-Claisen rearrangement of the initially formed product which is allyl substituted at the exocyclic S atom.     

S-(N-(Thiocarbamoyl)benzimido)-dithiocarbamidsäureester

Zusammenfassung Die Synthese der Titelverbindungen3 (R ¹=R ²=C₂H₅;n-C₄H₉) durch Reaktionen von N-(N,N-Diethylthiocarbamoyl)-benzimidoylchlorid (2) mit Natriumdialkyldithiocarbamaten (1) in Aceton wird beschrieben. Die niedrigen Ausbeuten (bis 25% d.Th.) sind durch Nebenreaktionen bedingt. Die Strukturen der Verbindungen werden durch IR-,¹H-NMR-,¹³C-NMR-und Massenspektren bestätigt. Nebenreaktionen werden¹³C-NMR-spektroskopisch verfolgt und die Ergebnisse diskutiert.

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S-(N-(thiocarbamoyl)benzimido)dithiocarbamic esters

Summary The synthesis of the title compounds3 (R ¹=R ²=C₂H₅;n-C₄H₉) by reactions of N-(N,N-diethylthiocarbamoyl)benzimidechloride (2) with sodiumdialkyldithiocarbamates (1) in acetone is described. The low yields (<25%) are caused by the occurrence of side reactions. The structures of the compounds were confirmed by IR,¹H and¹³C NMR, and mass spectroscopy. Side reactions were detected by¹³C NMR spectroscopy; the results are discussed.

     

Struktur von S-9,10-Dimethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantan und 9,10-Diethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantan

Structure of S-9,10-Dimethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantane and 9,10-Diethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantane S-9,10-Dimethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantane ( 1 ) and 9,10-diethyl-1,3,5,7-tetraarsa-2,4,6,8-tetraoxaadamantane ( 2 ) have been prepared by the reaction of propionic acid, propionic anhydride and butyric acid, butyric anhydride, respectively, with arsenic(III)-oxide. The crystals of 1 are rhombic, a = 6.902(4), b = 11.121(5), c = 13.988(8), space group P2₁2₁2₁. The crystals of 2 are monoclinic, a = 11.757(10), b = 11.255(10), c = 18.631 (18), β = 91.78(7), space group P2₁/n. The mean bond lengths and angles in 1 are AsO = 1.790 Å, AsC = 1.959 Å, OAsO = 100.60°, CAsO = 99.65°, AsOAs = 128.77°, AsCAs = 118.73°, and in 2 they are AsO = 1.780 Å, AsC = 1.978 Å, OAsO = 101.45°, CAsO = 99.55°, AsOAs = 129.64°, AsCAs = 117.72°.     

Medium effects on fluorescence quantum yields and lifetimes for coumarin laser dyes

Fluorescence quantum yields and lifetimes of coumarin dyes are sharply reduced in polar solvents if amine substituent groups are free to rotate. The polar solvent effect is interpreted in terms of relaxation of excited dye from an initial planar conformation to a twisted zwitterionic state.     

铝-钨丝混编阵的Z-箍缩实验研究

利用铝丝和钨丝混合编制的丝阵作为Z箍缩的负载，在俄罗斯Kurchatov研究所的S300强流装置上对其Z箍缩过程进行了实验研究，并与纯铝丝阵和纯钨丝阵的实验结果进行了比较.不同材料组成的丝阵的Z箍缩x射线能谱之间有明显差异，混编丝阵的铝K壳层的x射线辐射强度比纯铝丝阵的弱，在纯钨丝阵Z箍缩中没有发现波长小于1.6nm的线辐射.混编丝阵Z箍缩的x射线发光区域比纯铝丝阵的小，但比纯钨丝阵的大,混编丝阵的x射线产额比纯铝丝阵的大，但比纯钨丝阵的略低.在驱动电流为2.5—2.8MA条件下，Z箍缩的径向收缩比为4—5，x射线辐射脉冲脉宽为25ns左右，峰值为0.3—0.5TW，总能量为10—20kJ.激光探针的阴影像显示了丝阵等离子体形成的细致过程，还表明了等离子体的边界面不够清晰，其不稳定性有明显的发展，内部有丰富的结构. 关键词： Z箍缩 混编丝阵 S300强流装置     

Einige Neue N,S-Substituierte 2-Nitrodienverbindungen Aus Reaktionen Von Mono(p-fluorarylthio)substituierten Dienen Mit Aminen

2-Nitrodiene compound 1 was stirred with p-fluorothiophenol for a long time and compound 3 was obtained. Compound 1 gave bis(thio)substituted 2-nitrodiene compound 4 and tris(thio)substituted compound 5 with 2 moles of p-fluorothiophenol in the presence of NaOH in ethanol. The compounds 9a–g have been prepared from 8a–g and 3. Compound 7 was obtained from the reaction of mono(thio)substituted 2-nitrodiene with morpholine. Compound 3 gives 11a–d in the reaction with piperidines in CH₂Cl₂ (or ether). Compound 13a–b have been obtained from the reaction of compound 3 with primary amines 12a–b. Compound 3 gives 15 and 16 in the reaction with 2,5-dimethylpiperazine in CH₂Cl₂.

     

基于电子海图平台的多元异构数据融合研究

随着GIS的应用深入，对空问数据的需求越采越大，空间数据的大量重复获取不仅造成了人，财力巨大的浪费，而且还带来了空间数据的二义性问题。为了解决这一问题，提出了数据融合的方法。通过对空间数据融合，可以消除空间数据模型，物体的分类分级和几何位置的精度等引起的差异，为了实现空间数据的共享，扩大空间数据使用范围，减少空间数据的维护和获取费用。在深入研究IHO“数字海图测量数据转换标准”以及ARC／INFO，MAPINFO数据模型的基础上，探讨了符合IHOS-57V3．0的电子海图数据格式的融合的电子海图数据模型、并对多元异构数据的融合提出了一种实现方法。