全文获取类型
收费全文 | 280篇 |
免费 | 24篇 |
国内免费 | 10篇 |
专业分类
化学 | 158篇 |
晶体学 | 1篇 |
力学 | 1篇 |
数学 | 6篇 |
物理学 | 80篇 |
无线电 | 68篇 |
出版年
2024年 | 2篇 |
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 12篇 |
2020年 | 12篇 |
2019年 | 5篇 |
2018年 | 13篇 |
2017年 | 14篇 |
2016年 | 16篇 |
2015年 | 17篇 |
2014年 | 16篇 |
2013年 | 25篇 |
2012年 | 17篇 |
2011年 | 22篇 |
2010年 | 10篇 |
2009年 | 16篇 |
2008年 | 11篇 |
2007年 | 11篇 |
2006年 | 11篇 |
2005年 | 8篇 |
2004年 | 13篇 |
2003年 | 7篇 |
2002年 | 5篇 |
2001年 | 2篇 |
2000年 | 3篇 |
1999年 | 4篇 |
1998年 | 2篇 |
1997年 | 2篇 |
1995年 | 1篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 2篇 |
1989年 | 1篇 |
1979年 | 1篇 |
排序方式: 共有314条查询结果,搜索用时 15 毫秒
1.
《Mendeleev Communications》2022,32(3):395-396
A new method for assembling 1,3-selenazolines by the iodine- mediated reaction of the simplest building blocks such as elemental selenium, alkenes and acetonitrile has been discovered. A proposed mechanism includes the addition of the intermediate selenium iodides to alkene with subsequent solvent interception by the formed seleniranium ion. 相似文献
2.
Mariusz Marć Marek Tobiszewski Bożena Zabiegała Miguel de la Guardia Jacek Namieśnik 《Analytica chimica acta》2015
This review summarizes the different tools and concepts that are commonly applied in air quality monitoring. The monitoring of atmosphere is extremely important as the air quality is an important problem for large communities. Main requirements for analytical devices used for monitoring include a long period of autonomic operation and portability. These instruments, however, are often characterized by poor analytical performance. Monitoring networks are the most common tools used for monitoring, so large-scale monitoring programmes are summarized here. Biomonitoring, as a cheap and convenient alternative to traditional sample collection, is becoming more and more popular, although its main drawback is the lack of standard procedures. Telemonitoring is another approach to air monitoring, which offers some interesting opportunities, such as ease of coverage of large or remote areas, constituting a complementary approach to traditional strategies; however, it requires huge costs. 相似文献
3.
4.
Technical advances in the development of field-deployable capillary and microchip electrophoretic instruments and reports of their deployment between 2013 and 2017 were reviewed. Strategies and considerations in the design of the injection, separation and detection hardware, chemistry and associated infrastructure were discussed from an in-field perspective, with portability, robustness and automation/“ease of use” featuring as key requirements. Integration of functionality is important for adequate in-field performance. Progress was made towards the use of multiple channel devices for increased throughput and/or resolving power, mixing devices for on-line/in-line sample derivatization, battery operation and temperature control. The strengths and weaknesses of the various approaches described in the literature are discussed from the perspective of in-field operation. An overview of the applications of the field electrophoretic instruments is provided, including environmental science and planetary investigation. 相似文献
5.
6.
A portable chip-CE system with potential gradient detection (PGD) was developed and applied to the determinations of alkali metals and alkaloids. The separation efficiency appeared to be satisfactory and nonaqueous capillary electrophoresis (NACE) proved to be applicable to PGD or conductivity detection. The power supplies, separation and detection were built on a device of 3 kg in weight. A branch channel near the end of the separation channel was designed to perform PGD and make the application of relatively high field strength possible. The study is the first report on the application of PGD on the microchip platform. The design of the chip-CE system shows several advantages, such as simplicity, miniaturization and wide applicability. 相似文献
7.
便携式微波等离子体离子化检测器气相色谱仪用于气体分析的研究 总被引:2,自引:0,他引:2
本文使用自制的便携式微波诱导等离子体离子化检测器气相色谱仪对可燃气体中N_2、O_2、H_2和CH_4的测定方法进行了研究。以氩气为载气和工作气体,考察了改进后的微波诱导等离子体离子化检洲器(MIPID)的工作参数对测定的影响。对煤气和乙炔中的O_2、N_2、H_2和CH_4进行了测定,分析结果与热导池检测器(TCD)的气相色谱法一致。讨论了高电离电位(>11.7ev)气体组分在MIPID中响应特性。 相似文献
8.
Shu Ping XU* Huan Wen CHEN Ai Min YU Qin Han JIN Hua Ying LIAO Changchun R&D Center for Analytical Instruments Department of Chemistry Jilin University Changchun Key Laboratory for Supramolecular Structure Spectroscopy of Ministr 《中国化学快报》2002,13(7):660-661
In recent years, the determination of Cr (VI) has attracted great attention because of its toxicity to human, plants and animals1-5. Usually, in the industrial waste water, the concentration of Cr (VI) is relatively high and should be determined frequently. So, an accurate, quick, and convenient method for the measurement of Cr (VI) in environmental water, as well as in river, lake, sea and tap water, is of great importance. The method for determination of Cr (VI) by diphenylcarbazine … 相似文献
9.
毫米波雷达的安装角度校准是雷达正常使用并与摄像头进行数据融合的重要前提,雷达安装角度偏
转过大会导致雷达数据与摄像头数据融合失败,影响高级驾驶辅助系统(Advanced Driving Assistance System,ADAS)
的正常使用。文中提出一种基于曲线拟合的毫米波雷达安装角度校准方法,当车辆在道路上行驶时辅以车辆输入
的车速和偏航角信息,通过2000 个静止点进行曲线拟合得到雷达需要补偿的角度。相较于选择有护栏的道路进行
绕行和在标定场地部署角反射器进行安装角度校准的方法,这种方法适用的场景种类更多并且校准时间从15 分钟
以上缩短为5 分钟以下。经过实验验证,在花费更短时间完成校准后,校准精度与其它自校准方法相同为±5°。 相似文献
10.
A novel methodology for the regio- and stereoselective synthesis of amino alcohol derivatives from allylalcohols/ethers via intramolecular nucleophilic participation by the sulfilimine moiety is disclosed. The sulfilimine moiety is stereospecifically transformed to a sulfinyl moiety with an inverted configuration. The reaction is general and affords highly functionalised products. 相似文献