Analysis of dielectric relaxations of w/o emulsions in the light of theories of interfacial polarization

An attempt is made to apply dielectric theories of interfacial polarization to observations of dielectric relaxations for W/O emulsions. Approximate formulas for disperse systems in a W/O type were derived from the two theories: one proposed by Maxwell and Wagner for dilute disperse systems of spherical particles, and the other developed by Hanai for concentrated disperse systems. Dielectric measurements were carried out on concentrated W/O emulsions prepared from kerosene and distilled water or KCl aqueous solutions by minimal use of emulsifiers. Marked dielectric relaxations were observed with the emulsions, the dielectric parameters having been determined to characterize the relaxation data. Phase parameters such as relative permittivity, electric conductivity and volume fraction of the disperse phase were evaluated from the dielectric parameters by use of the approximate formulas of the respective theories. The phase parameters evaluated and the frequency dependence of complex permittivity of the W/O emulsions deduced from the theory for concentrated disperse systems are in excellent agreement with the observed data in comparison to that for dilute disperse systems. It is concluded that the dielectric relaxations due to the interfacial polarization of disperse systems of spheres are explained satisfactorily by the theory for concentrated disperse systems.     

FREQUENCY DEPENDENCE OF THE DIELECTRIC RELAXATION OF 1,2-POLYBUTADIENES

The dielectric loss factor and permittivity of a series of 1, 2-polybutadienes with different contents of 1, 2-units and different contents of syndiotactie 1, 2-units were determined over a frequency range from 30Hz to 100KHz at different temperatures. The WLF equation was evaluated for various samples with T_θat 100KHz as a reference temperature and the master curves of various samples have been constructed, which are in accordance with those calculated by Havriliak-Negami equation. The frequency dependence of the dielectric relaxation of 1, 2-polybutadienes was investigated over a frequency range from 10~0 Hz to 10~(12) ZHz in terms of the experimental data and the master curves.     

Dielectric Relaxation Study of Liquids Having Chloro Group with Associated Liquids. I. Chlorobenzene with Methanol, Ethanol, and 1-Propanol

The complex permittivity for chlorobenzene–alcohol binary mixtures have been determined over the frequency range of 10 MHz to 20 GHz, at 15, 25, 35, and 45°C, using the time-domain reflectometry (TDR) method for 11 concentrations of each chlorobenzene–alcohol system. The alcohols used were methanol, ethanol, and 1-propanol. The values of static dielectric constant, relaxation time, the corresponding excess properties, the Redlich–Kister coefficients up to the third order, the Kirkwood correlation factor, and thermodynamic parameters of the mixtures have been determined. The excess permittivity is found to be negative for chlorobenzene–methanol and chlorobenzene–ethanol, whereas it is positive in the 1-propanol rich region. The excess inverse relaxation time is negative for all the systems studied here. The Kirkwood effective correlation factor increases with an increasing in the molecular size of the alcohol, but decreases with increasing temperature.     

Bio-silica incorporated barium ferrite composites: Evaluation of structure,morphology, magnetic and microwave absorption traits

A series of bio-silica incorporated barium-ferrite-composites with the composition of (x)Bio-SiO₂:(80-x)γ-Fe₂O₃:(20)BaO, where x = 0, 1, 2, and 3 wt% were prepared using the modified solid-state reaction method. The influence of different bio-silica (extricated from sintered rice husk) contents on the surface morphologies, structures, and magnetic characteristics of these composites were assessed. The relative complex permittivity and permeability were resolved using the Nicholson-Ross-Weir strategy in the frequency range of 8–13 GHz. Meanwhile, the reflection loss was estimated through the transmission/reflection line theory to assess the MW absorption properties of the composites. Incorporation of the bio-silica in the barium ferrite composites generated a new hexagonal phase (Ba₃Fe₃₂O₅₁) and a tetragonal phase (BaFeSi₄O₁₀) which led to a decrease in the saturation magnetization and significant shift in the MW frequency absorption peak positions.     

微波遥感典型地物介电常数实地测量

在微波遥感定量化研究中,要求对遥感目标的介电特性有较准确的了解.为此采用自由空间法在野外实地测量典型目标的介电常数.给出了基本原理,定标方法及在X波段对黑土,草地,和冰所测的介电常数。分析比较了测量结果。     

RECONSTRUCTION OF ONE DIMENSIONAL MULTI-LAYERED MEDIA BY USING A TIME DOMAIN SIGNAL FLOW GRAPH TECHNIQUE

A novel inverse scattering method to reconstruct the permittivity profile of one-dimensional multi-layered media is proposed in this paper.Based on the equivalent network ofthe medium,a concept of time domain signal flow graph and its basic principles are introduced,from which the reflection coefficient of the medium in time domain can be shown to be a series ofDirac δ-functions(pulse responses).In terms of the pulse responses,we will reconstruct both thepermittivity and the thickness of each layer will accurately be reconstructed.Numerical examplesverify the applicability of this method     

同轴探头测量材料电磁参数变频率法的改进

本文针对我们实验室早期提出的用开口同轴探头变频率法同时测量雷达吸波材料的介电常数和磁导率技术^(6,7)在实用中遇到的问题,提出应用线性插值技术来修正电磁参数随频率的变化,使用拟合技术来克服测得反射系数的随机误差对电磁参数提取的影响,建立多频率点上电磁参数的矛盾方程方法来减少参数提取时所产生的伪根等改进技术,从而有效地克服原方法所存在的问题,使之能够用于实际测量。并通过对具体样品的测量证明了改进技术的合理性及有效性。     

Permeability enhancement by induced displacement current in magnetic material with high permittivity

Based on a analytical model, this paper reveals that instead of demagnetization, the induced displacement current in a Mn–Zn ferrite core due to its high permittivity can produce a magnetic field that effectively adds to the incident magnetic field in the low-loss frequency region. This leads to a resultant magnetic field being larger than incident field in magnitude, and results in measured permeability being higher than its intrinsic value in the low-loss frequency region. It is also found that such effect is more pronounced in large core than in small core. With increasing frequency and consequently the core being more lossy, the induced magnetic field due to both conductivity and imaginary part of complex permittivity demagnetize the magnetic material and counteracts the incident magnetic field. In consequence, the measured real part of complex permeability becomes smaller than its intrinsic value. The larger the core dimension, the smaller the real part of complex permeability is. These conclusions based on the numerical analysis are in good agreement with the experimental observation in the aspect of change tendency of permeability versus frequency.     

用复合谐振腔法测量介质谐振器材料的介电特性

本文根据Barlow提出的在TE(01n)模谐振腔上耦合一段截止波导构成复合腔的原理，首次在C波段对介质谐振器材料的介电性能进行了测量，并从理论上证明了该方法对相对介电系数有很高的测试灵敏度，本文给出了几种介质谐振器材料的测试结果，最后就样品厚度对测试精度的影响作了分析。     

Oxidation temperature dependent properties of MgO thin film on alumina

The magnesium oxide thin films were prepared by thermal oxidation (in air) of vacuum evaporated magnesium thin film on alumina. It was found that oxidation temperature (623 K, 675 K and 723 K) and thickness (103 nm and 546 nm) dependent effects were prominently manifested in the surface morphology. Electrical and microwave properties (8-12 GHz) of the MgO thin films were also carried out. X-ray diffraction showed orientation along (2 0 0) and (2 2 0) directions. Flowerlike morphology was observed from SEM and flake like morphology for films of higher thickness oxidized at higher temperatures. The magnesium oxide thin film showed NTC behavior. Microwave transmittance was found to increase with increase in oxidation temperature but was lower than alumina. Frequency and oxidation temperature dependent microwave permittivity was obtained. The microwave dielectric constant varied in the range 8.3-15.3.