全文获取类型
收费全文 | 4264篇 |
免费 | 179篇 |
国内免费 | 242篇 |
专业分类
化学 | 1083篇 |
晶体学 | 28篇 |
力学 | 35篇 |
综合类 | 12篇 |
数学 | 57篇 |
物理学 | 2258篇 |
无线电 | 1212篇 |
出版年
2024年 | 5篇 |
2023年 | 46篇 |
2022年 | 52篇 |
2021年 | 76篇 |
2020年 | 43篇 |
2019年 | 47篇 |
2018年 | 73篇 |
2017年 | 141篇 |
2016年 | 175篇 |
2015年 | 141篇 |
2014年 | 270篇 |
2013年 | 316篇 |
2012年 | 192篇 |
2011年 | 248篇 |
2010年 | 191篇 |
2009年 | 286篇 |
2008年 | 249篇 |
2007年 | 308篇 |
2006年 | 235篇 |
2005年 | 206篇 |
2004年 | 187篇 |
2003年 | 143篇 |
2002年 | 135篇 |
2001年 | 108篇 |
2000年 | 93篇 |
1999年 | 85篇 |
1998年 | 78篇 |
1997年 | 82篇 |
1996年 | 87篇 |
1995年 | 82篇 |
1994年 | 34篇 |
1993年 | 50篇 |
1992年 | 56篇 |
1991年 | 56篇 |
1990年 | 19篇 |
1989年 | 26篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1986年 | 9篇 |
1985年 | 2篇 |
1984年 | 9篇 |
1983年 | 2篇 |
1982年 | 7篇 |
1981年 | 5篇 |
1980年 | 8篇 |
1979年 | 4篇 |
1978年 | 2篇 |
1976年 | 2篇 |
1975年 | 2篇 |
排序方式: 共有4685条查询结果,搜索用时 109 毫秒
1.
Riboflavin was covalently linked to mesoporous SBA-15 silica surface via grafting technique. Then fluorescence properties of the system obtained were analyzed in the presence of several metal and organic cations. Both quenching and strengthening of fluorescence as well as significant changes in the maximum fluorescence wavelength were observed. The results were compared with absorption and fluorescence data obtained for riboflavin water solutions. 相似文献
2.
一种新颖的基于非压缩数字视频的水印盲检测算法 总被引:10,自引:0,他引:10
数字水印是一种嵌入到多媒体数据中用来进行版权标识的工具。在众多的宿主媒体中,数字视频因具有隐藏容量大、透明性好、鲁棒性强等诸多优点而受到日益广泛的关注。但是很多文献中提到的视频水印都是从数据流中提取单帧图像进行处理,这类算法与静态图像的水印方法如出一辙,没有充分利用视频文件的各种特性。而且对帧平均、视频压缩等常见的运动图像攻击方法十分敏感。针对这些问题,本文以非压缩视频文件为实验对象,结合人类视觉模型和彩色图像场景分割的方法,提出并实现了一种基于视频时间轴的数字水印盲检测算法。实验结果表明算法有效实用。 相似文献
3.
J.R. Cooper 《Journal of Molecular Spectroscopy》2006,239(1):51-58
The ν9 fundamental band of ethane occurs in the 12 μm region. It is the strongest band of ethane in a terrestrial window and is commonly used for the identification of ethane in the Jovian planets. The ν9 + ν4 − ν4 band occurs in the same region; neither can be analysed as an isolated band, since both are embedded in the torsional bath of the ground vibrational state. We report here two global fit models including data from both of these bands as well as the ν3 fundamental and the ν4, 2ν4 − ν4, and 3ν4 torsional transitions. The first is restricted to −5 ? KΔK ? 15 in the hot band and gives an excellent fit to the included data. Three resonant interactions are identified in this fit—a Coriolis interaction with two resonant cases between the ν9 torsional stack and that of the ground vibrational state (gs) and a resonant Fermi interaction between the ν3 fundamental and the gs. Hot band lines with KΔK < −5 are influenced by a fourth perturbation, with a crossing at −11 < KΔK < −10, which has been attributed to an interaction with the ν12 fundamental. A second fit, demonstrating a promising treatment of this interaction, is also presented. 相似文献
4.
Eldad Herceg 《Surface science》2006,600(19):4563-4571
The formation of a well-ordered p(2 × 2) overlayer of atomic nitrogen on the Pt(1 1 1) surface and its reaction with hydrogen were characterized with reflection absorption infrared spectroscopy (RAIRS), temperature programmed desorption (TPD), low energy electron diffraction (LEED), Auger electron spectroscopy (AES), and X-ray photoelectron spectroscopy (XPS). The p(2 × 2)-N overlayer is formed by exposure of ammonia to a surface at 85 K that is covered with 0.44 monolayer (ML) of molecular oxygen and then heating to 400 K. The reaction between ammonia and oxygen produces water, which desorbs below 400 K. The only desorption product observed above 400 K is molecular nitrogen, which has a peak desorption temperature of 453 K. The absence of oxygen after the 400 K anneal is confirmed with AES. Although atomic nitrogen can also be produced on the surface through the reaction of ammonia with an atomic, rather than molecular, oxygen overlayer at a saturation coverage of 0.25 ML, the yield of surface nitrogen is significantly less, as indicated by the N2 TPD peak area. Atomic nitrogen readily reacts with hydrogen to produce the NH species, which is characterized with RAIRS by an intense and narrow (FWHM ∼ 4 cm−1) peak at 3322 cm−1. The areas of the H2 TPD peak associated with NH dissociation and the XPS N 1s peak associated with the NH species indicate that not all of the surface N atoms can be converted to NH by the methods used here. 相似文献
5.
3-Hydroxy-4-hydroxymethyl pyrrolidin-2-ones, easily prepared from the Baylis–Hillman adduct 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate, are useful intermediates in the synthesis of bioactive compounds. In order to understand the mechanism involved in this reaction, vibrational and Montecarlo molecular mechanics conformational analysis on 1-ethyl-4-methyl-2-hydroxy-3-methylenebutanedioate were carried out, confirming the existence of a low energy intramolecular H-bonded five-member ring. 相似文献
6.
We have simultaneously used adsorption isotherm volumetry and Fourier transform infrared spectroscopy in order to take the investigations on amorphous ice structure a step further, especially concerning porosity and annealing-induced modifications. We have studied surface reorganization during annealing and found that the number of surface sites decreases before crystallization, their relative ratios being different for amorphous and crystalline ice. We also present results confirming that ice can have a large specific surface area and nevertheless be non-microporous. 相似文献
7.
M. Zandian J. G. Pasko J. M. Arias R. E. De Wames S. H. Shin 《Journal of Electronic Materials》1995,24(5):681-684
Measurements of 77K RoA and 300K reverse bias dynamic impedance (RdA) products at one volt reverse bias has been carried out to assess the degree of correlation of this figure of merit. Planar
P-on-n heterostructures were grown on near lattice-matched CdZnTe substrates with Hg1-xCdxTe (0.20< x <0.30) by molecular beam epitaxy. These devices were passivated with CdTe and doped with indium and arsenic as
n- and p-type dopants, respectively. Current-voltage characteristic of these devices exhibit thermally generated dark currents
at small and modest reverse bias. We have observed that RoA values of these long wavelength infrared P-on-n heterostructure photodiodes at 77K correlate with room temperature RdA values. Diode arrays with high room temperature RdA values at one volt reverse bias also have high RoA values at 77K. Similarly, low RdA values at room temperature indicate poor performance at 77K where deviation from diffusion current occurs at reverse bias
of 0.2 to 1 volt at room temperature. The results presented here, for a small samples of devices, demonstrate that room temperature
measurements of current-voltage characteristics to evaluate Hg1-xCdxTe (0.22< x <0.28) diode performance and array uniformity at lower temperatures can be used. This provides an acceptable criteria
for further study at lower temperatures. 相似文献
8.
A highly sensitive method for infrared radiation detection based on thermal resonance in an active bolometer is set forth. An active bolometer is a self-oscillating system consisting of an IR-sensitive cell in a feedback circuit of an adjustable proportional controller. The analysis of an active bolometer autonomous (dark) dynamics reveals that with a generalized gain factor A variation the system evolves from relaxation type towards oscillating and self-oscillating type. When A=Ac, where Ac is a critical value of the generalized gain factor A, the steady state loses stability through self-excited thermal oscillations. The resonance in a system weakly perturbed by IR radiation modulated at self-oscillation frequency q0[1+exp(iωct)] is considered. It is shown that in a small precritical vicinity =(A−Ac)/Ac of the gain factor the amplitude of forced thermal oscillations is proportional to q0/Ac. The D* calculation reveals that the detection power of a passive (A=0) bolometer increases with feedback introduction by a factor of 1/||. The detection powers of feasible versions of an active bolometer are compared. 相似文献
9.
10.
双波段成象及融合技术研究 总被引:7,自引:4,他引:3
概括地分析了双波段成象技术的发展概况,分析了成象技术的基本原理,提出了红外双波段基本方案和涉及的关键技术,分析和计算了系统的基本性能。最后,讨论了双波段及融合技术,认为在双波段实现融合应以自主式结构为主。 相似文献