Characterization of a Redox-responsive Molecular Switch Based on Dibenzo[1,2]dithiine Using DFT

Structural and electronic properties of a bistable redox-responsive molecular switch based on dibenzo[1,2]dithiine (PSBH) were studied using the DFT-B3LYP/6-31G* method. The results confirmed that the electrical conductivity of the closed form of considered molecular switch is higher than that of the open form. NBO electric charges on heavy atoms of biphenyl unit revealed that the positive charge on sulfur atoms reinforced, which caused the collapse of disulfide bond.     

Far-field properties and beam quality of vectorial Hermite–Laguerre–Gaussian beams beyond the paraxial approximation

The far-field properties and beam quality of vectorial nonparaxial Hermite–Laguerre–Gaussian (HLG) beams are studied in detail, where, instead of the second-order-moments-based M² factor, the extended power in the bucket (PIB) and βparameter are used to characterize the beam quality in the far field and the intensity in the formulae is replaced by the z component of the time-averaged Poynting vector S_z. It is found that the S_z PIB and βparameter of vectorial nonparaxial HLG beams depend on the mode indices n, m, αparameter and waist-width-to-wavelength ratio w₀/λ and the PIB and βparameter are additionally dependent on the bucket's size taken.     

厄米-拉盖尔-高斯光束的传输特性

利用Collins公式,推导出厄米-拉盖尔-高斯(HLG)光束通过近轴ABCD光学系统的解析传输公式,并用来研究通过自由空间和薄透镜的传输特性.结果表明,除模指数m,n之外,对HLG光束新引入的α参数,它影响光强分布和对称性;HLG光束在传输中保持形状不变;HLG光束的焦移与模指数m,n和α参数无关,这意味着m,n和α不同的HLG光束聚焦在同一位置.并给出了HLG光束的M2因子.     

矢量非傍轴厄米-拉盖尔-高斯光束的光束质量

基于矢量Rayleigh-Sommerfeld衍射积分，推导出矢量非傍轴圆偏振厄米-拉盖尔-高斯(HLG)光束的远场解析表达式.矢量非傍轴圆偏振高斯光束可作为一般公式的特例给出.将桶中功率(PIB)概念推广到非傍轴范畴，用以描述矢量非傍轴光束的远场光束质量，其中光强用时间平均坡印廷矢量的z分量取代.数值计算和分析表明，矢量非傍轴HLG光束的PIB不仅与束腰宽度与波长之比w₀/λ有关，而且还与α参数，模指数n和m以及所取桶的尺寸有关. 关键词： 矢量非傍轴厄米-拉盖尔-高斯光束 矢量Rayleigh-Sommerfeld衍射积分 桶中功率