HDI工艺中取代涂树脂铜箔适合激光钻孔的半固化片

应用于HDI的激光钻孔半固化片的方法和其它常规材料相比具有的优缺点。     

AOI技术在激光微孔产品检查中的应用

在过去几年里,小型PCB诸如硅芯片级以及便携式移动电话的生产者和设计者们已经发现:如果要保持自己的竞争力并具备生产高密度封装板能力,就必须采用微孔技术。微孔技术的出现要求针对微孔缺陷的有效检测手段对工艺进行过程控制。本文对激光微孔的自动光学检测进行了详细介绍。     

Comparison of EI and metastable atom bombardment ionization for the identification of polyurethane thermal degradation products

Polyurethanes are widely used in the manufacture of commercial products such as foams and paints. During combustion, these polymers can generate isocyanates, which induce adverse health effects. Polymer pyrolysis (Py) hyphenated with mass spectrometry (MS) allows the investigation of polymer thermal degradation over time/temperature. A diphenylmethanediisocyanate (MDI) polyurethane foam was analyzed with electron ionization (EI) and metastable atom bombardment (MAB) ionization at a pyrolysis temperature of 400 °C. The recently introduced MAB ionization source uses discrete energy stored in metastable atoms of gases to ionize the analytes. This characteristic allows modulation of the ionization energy by simply changing the ionization gas. The extensive fragmentation of molecular ions observed using EI 70 eV is not totally eliminated with EI 10 eV. However, only molecular ions are observed with MAB using N₂ as the ionization gas. Temperature gradients were used to separate the products generated during the thermal degradation of a 1,6-hexamethylenediisocyanate (HDI) polyurethane paint. The analysis of mass spectra was facilitated owing to a selective desorption of pyrolysis products. Furthermore, changing the MAB ionization gas allows elucidation of the structure of the pyrolysis products by controlling the extent of their fragmentation. During these experiments, isocyanic acid, methyleneisocyanate, ethyleneisocyanate, propylisocyanate and butylisocyanate were detected.     

1,6-六亚甲基二异氰酸酯自聚产物的结构表征

用IR与NMR表征了用醋酸钾为催化剂时 1,6 六亚甲基二异氰酸酯 (HDI)自聚产物的结构 .结果表明 ,自聚主产物是三聚体异氰脲酸酯 ,主要含有三聚体异氰脲基、异氰酸根 ,同时含有由杂质带来的微量氨基甲酸酯、脲基甲酸酯基、取代脲基、缩二脲基 .一维核磁谱及二维化学位移相关谱分辨出 7种羰基 ,一种NCO基 ,确定了氮上 8种不同取代结构的分子链连接情况 .通过建立理论模型 ,定量地描述了自聚产物的结构 .     

刚-挠性PCB 30年

文章概述了30年来刚-挠性PCB的发展。今天,凡是在刚性多层板的技术进步,同样,在刚-挠性印制板也是能够实现的。     

HDI激光盲孔定位方法的研究

HDI(高密度互联)产品的发展已经进入了规模化的生产进程,但是HDI产品的制作工艺改进仍然是PCB业者不断讨论和极力推进的工作。作为HDI产品制作中的重要一环,激光盲孔钻孔的对位系统也是人们讨论的热点,无论是激光钻机供应商还是曝光机供应商,还有PCB制作的工程师,对此问题的探讨从来就没有停止过。本文就激光盲孔的开窗,激光钻孔靶位的选择以及实现的方法提出一些个人见解。     

Zn-Co bimetallic supported ZSM-5 catalyst for phosgene-free synthesis of hexamethylene–1,6–diisocyanate by thermal decomposition of hexamethylene–1,6–dicarbamate

A set of mono-and bimetallic(Zn-Co) supported ZSM-5 catalysts was first prepared by PEG-additive method. The physicochemical properties of the catalysts were investigated by FTIR, XPS, XRD, N_2adsorption-desorption measurements, SEM, EDS and NH3-TPD techniques. The physicochemical properties showed that the Zn Co_2O_4 spinel oxide was formed on the ZSM-5 support and provided effectual synergetic effect between Zn and Co species for the bimetallic catalyst. Furthermore, bimetallic supported ZSM-5 catalyst exhibited weak, moderate and strong acidic sites, while the monometallic supported ZSM-5 catalyst showed only weak and moderate or strong acidic sites. Their catalytic performances for thermal decomposition of hexamethylene–1,6–dicarbamate(HDC) to hexamethylene–1,6–diisocyanate(HDI) were then studied. It was found that the bimetallic supported ZSM-5 catalysts,especially Zn-2Co/ZSM-5 catalyst showed excellent catalytic performance due to the good synergetic effect between Co and Zn species, which provided a suitable contribution of acidic sites. HDC conversion of 100% with HDI selectivity of 91.2% and by-products selectivity of 1.3% could be achieved within short reaction time of 2.5 h over Zn-2Co/ZSM-5 catalyst.     

激光技术在刚挠性HDI板的应用——微导通孔形成，图形成形，外型加工

概述了采用一个激光源能够加工刚性和挠性板的一种新型激光技术,PCB制造商可能采用最小的投资和提高生产率而进入HDI市场。     

埋／盲孔多层PCB制作工艺

本文阐述了埋盲孔多层印制板的制作工艺,并对关键工序的控制作了详细说明。     

埋入无源元件集成的高密度印制板

概述了Motorola的埋入PTF电阻、CFP电容和螺旋电感等无源集成的高密度印制板和埋入无源集成技术。